Photochemical Difluoromethylation of Quinoxalin-2(1H)-ones with Difluoroacetic Anhydride and Pyridine N-Oxide.
J Org Chem
; 89(2): 1199-1208, 2024 Jan 19.
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| ID: mdl-38154054
ABSTRACT
A novel photochemical difluoromethylation of quinoxalin-2(1H)-ones under catalyst-free conditions was achieved with difluoroacetic anhydride and pyridine N-oxide. The green and mild reaction conditions as well as readily attainable difluoroacetic anhydride provide a useful protocol to prepare C3-difluoromethylated quinoxalin-2(1H)-ones.
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Bases de datos:
MEDLINE
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En
Revista:
J Org Chem
Año:
2024
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Article
País de afiliación:
China