Tetrylene-Functionalized Si7-Siliconoids.
Inorg Chem
; 2024 Mar 19.
Article
en En
| MEDLINE
| ID: mdl-38502920
ABSTRACT
The core expansion of metallic or metalloid clusters by the addition of further homo- or heteronuclear vertices is pivotal to the nucleation and growth of particles. The exohedral grafting of a low-valent functionality followed by endohedral incorporation have been identified as key steps. Following previous work on the Si6 series, we now report the synthesis and full characterization of the amidinatotetrylene-functionalized seven-vertex siliconoids Si7R5[E(NtBu)2CPh] (E = Si, Ge, Sn). In the case of the silylene derivative, the solid-state structure was determined by single crystal X-ray diffraction.
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MEDLINE
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En
Revista:
Inorg Chem
Año:
2024
Tipo del documento:
Article
País de afiliación:
Alemania