Epimerization effects on coordination behaviours of phenanthroline-based phosphine-oxide ligands with uranyl ions.
Chem Commun (Camb)
; 60(38): 5042-5045, 2024 May 07.
Article
en En
| MEDLINE
| ID: mdl-38634237
ABSTRACT
Epimers of the (1,10-phenanthroline-2,9-diyl)bis(ethyl(phenyl)phosphine oxide) (Et-Ph-BPPhen) ligand with two chiral centers (R,R/S,S and R,S) were synthesized. The configurational effects on the coordination ability and mechanism between these epimeric ligands and uranyl ions were thoroughly investigated. This work is helpful to reveal the effects of different conformations of epimeric ligands on their coordination properties.
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Bases de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
China