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Epimerization effects on coordination behaviours of phenanthroline-based phosphine-oxide ligands with uranyl ions.
Yang, Xiaofan; Fang, Dong; Wang, Shihui; Tian, Zhenjiang; Xu, Lei; Liu, Jiyong; Zhang, Anyun; Xiao, Chengliang.
Afiliación
  • Yang X; College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, China. xiaoc@zju.edu.cn.
  • Fang D; College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, China. xiaoc@zju.edu.cn.
  • Wang S; Institute of Zhejiang University-Quzhou, Quzhou 324000, China.
  • Tian Z; College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, China. xiaoc@zju.edu.cn.
  • Xu L; College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, China. xiaoc@zju.edu.cn.
  • Liu J; Institute of Nuclear-Agricultural Science, Key Laboratory of Nuclear Agricultural Sciences of Ministry of Agriculture and Zhejiang Province, Zhejiang University, Hangzhou 310058, China.
  • Zhang A; Department of Chemistry, Zhejiang University, Hangzhou 310058, China.
  • Xiao C; College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, China. xiaoc@zju.edu.cn.
Chem Commun (Camb) ; 60(38): 5042-5045, 2024 May 07.
Article en En | MEDLINE | ID: mdl-38634237
ABSTRACT
Epimers of the (1,10-phenanthroline-2,9-diyl)bis(ethyl(phenyl)phosphine oxide) (Et-Ph-BPPhen) ligand with two chiral centers (R,R/S,S and R,S) were synthesized. The configurational effects on the coordination ability and mechanism between these epimeric ligands and uranyl ions were thoroughly investigated. This work is helpful to reveal the effects of different conformations of epimeric ligands on their coordination properties.
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Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China