Molten Salt-Assisted Synthesis of Titanium Nitride.
Small Methods
; : e2400228, 2024 Jun 10.
Article
en En
| MEDLINE
| ID: mdl-38859636
ABSTRACT
Titanium nitride is an exciting plasmonic material, with optical properties similar to gold. However, synthesizing TiN nanocrystals is highly challenging and typically requires solid-state reactions at very high temperatures (800-1000°C). Here, the synthesis of TiN nanocrystals is achieved at temperatures as low as 350°C, in just 1 h. The strategy comprises molten salt, Mg as reductant and Ca3N2 as nitride source. This brings TiN from the realm of solid-state chemistry into the field of solution-based synthesis in regular, borosilicate glassware.
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MEDLINE
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Revista:
Small Methods
Año:
2024
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Article
País de afiliación:
Suiza