Temperature-dependent photoluminescence of novel Eu3+, Tb3+, and Dy3+ doped LaCa4O(BO3)3: Insights at low and room temperatures.

This study explores the structural and optical qualities of LaCa4O(BO3)3 (LACOB) phosphors doped with Eu3+, Dy3+, and Tb3+ using a microwave-assisted sol-gel technique. It uncovers oxygen-related luminescence defects in LACOB, highlighting emission peaks at 489 and 585 nm for Dy3+, a distinct sharp peak at 611 nm for Eu3+ in the red spectrum, and a notable green emission for Tb3+ due to specific transitions. The photoluminescence (PL) analysis indicates that luminescence is optimized through precise doping, leveraging dipole interactions, and localized resonant energy transfer, which are influenced by dopant concentration and spatial configuration. Temperature studies show emission intensity variations, particularly noticeable below 100 K for Tb3+ doped samples, demonstrating the nuanced balance between thermal quenching and luminescence efficiency. This temperature dependency, alongside the identified optimal doping conditions, underscores the potential of these materials for advanced photonic applications, offering insights into their thermal behavior and emission mechanisms under different conditions.

Enhanced luminescence of Eu3+ in LaAl2B4O10 via energy transfer from Dy3+ doping.

In this study, an investigation was conducted on the structural and photoluminescence (PL) characteristics of LaAl2B4O10 (LAB) phosphors initially incorporated with Dy3+ and Eu3+ ions. Subsequently, the impact of varying Eu3+ concentration while maintaining a constant Dy3+ concentration was examined. Structural characterization was performed using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and energy-dispersive X-ray spectroscopy (EDS). XRD analysis confirmed the effective embedding of both dopants into the hexagonal framework of the LAB. The PL emission spectra revealed characteristic emissions of Dy3+ (blue and yellow) and Eu3+ (red) ions. The optimized dopant concentrations of both Dy3+ and Eu3+ were observed to be 3 wt%. The dominant mechanism for concentration quenching in doped LAB phosphors was determined to be the electric dipole-dipole interaction. Co-doping with Eu3+ led to a substantial decrease in Dy3+ emission intensity (∼0.18-fold) while enhancing Eu3+ emission intensity (∼3.72-fold). The critical energy transfer distance (RC = 11.64 Å) and the analysis based on the Dexter theory confirmed that the energy transfer mechanism corresponds to dipole-dipole interaction. The color purities and correlated color temperatures (CCT) were estimated, suggesting the potential of these phosphors for warm white and red lighting applications, respectively. The observed energy transfer and luminescence properties, along with the structural and compositional characterization, highlight the promising potential of LAB:Dy3+/Eu3+ co-doped phosphors for advanced lighting and display technologies.

Novel Tb³âº-Doped LaAl2B4O10 phosphors: Structural analysis, luminescent properties, and energy transfer mechanism.

This study explores the structural and luminescent properties of terbium (Tb³âº)-doped lanthanum aluminium borate (LaAl2B4O10, abbreviated as LAB) phosphors, a novel host lattice for Tb³âº doping. LAB:Tb³âº phosphors, with varying dopant concentrations, were synthesized using a microwave-assisted combustion synthesis approach and characterized using X-ray diffraction (XRD), Rietveld refinement, and photoluminescence spectroscopy at both room and low temperatures. The structural analysis confirmed the hexagonal crystal structure of LAB and revealed successful incorporation of Tb³âº ions without altering the fundamental lattice. Luminescence studies demonstrated that the LAB:Tb³âº phosphors show strong green emission primarily attributed to the 5D4→7F5 transition of Tb³âº. The optimal doping concentration was determined to be 5 wt% Tb³âº, which provided maximum luminescence efficiency. This concentration also allowed for a critical study of energy transfer mechanisms within the phosphor, revealing dipole-dipole interactions with a critical distance of 9.80 Å between Tb³âº ions. Additionally, the CIE chromaticity coordinates of LAB:0.05 Tb³âº were precisely determined to be (0.289, 0.4460), indicating the potential for high-quality green emission suitable for solid-state lighting and display technologies. This work not only demonstrates the potential of LAB:Tb3+ as a highly efficient green luminescent material, but also sheds light on the mechanisms responsible for energy transfer and concentration quenching.

Radiation shielding ability and optical features of La2O3+TiO2+Nb2O5+WO3+X2O3 (X=B, Ga, and In) glass system containing high-entropy oxides.

Three high entropy materials (La2O3+TiO2+Nb2O5+WO3+X2O3 coded as LTNWM1, LTNWM2, and LTNWM3 for X = B, Ga, and In) produced by aerodynamic containerless processing were evaluated for optical attributes, and their gamma-radiation absorption abilities were investigated in this report. Optical related parameters such as the molar refractivity ( R m ), optical transmission ( T ), molar polarizability ( α m ), metallization criterion ( M ), reflection loss ( R L ), static ( ε s t a t i c ), and optical ( ε o p t i c a l ) dielectric constants were estimated through standard expressions, while photon attenuation parameters were estimated from data from photon transmission simulations in FLUKA code and XCOM software. The attenuation parameters were calculated for a wide energy photon spectrum (15 keV-15 MeV). LTNWM1, LTNWM2, and LTNWM3 had R m values of 18.94 cm3/mol, 21.45 cm3/mol, and 26.09 cm3/mol respectively. The α m has a value of 7.52 × 10-24 cm3 for LTNWM1, 8.51 × 10-24 cm3 for LTNWM2, and 10.35 × 10-24 cm3 for LTNWM3. The photon shielding parameters evaluated by FLUKA and XCOM are compatible. The mass attenuation coefficient for the glasses was between 0.0338 and 52.8261 cm2/g, 0.0336-58.0237 cm2/g, and 0.0344-52.1560 cm2/g for LTNWM1, LTNWM2 and LTNWM3, respectively. The effective atomic number at 1.5 MeV was 18.718, 20.857, and 22.440 for LTNWM1, LTNWM2, and LTNWM3, respectively. The shielding parameters of the HMOs compared to traditional gamma radiation absorbers are exceptional and highlight the potential of using them as optically transparent gamma-shields.

Distinct Optical and Structural (Nanoyarn and Nanomat-like Structure) Characteristics of Zinc Oxide Nanofilm Derived by Using Salvia officinalis Leaves Extract Made without and with PEO Polymer.

This paper reports the optical properties of zinc oxide nanofilm fabricated by using organic natural products from Salvia officinalis leaves (SOL) extract and discusses the effect of the nanocrystal (NC) structure (nanoyarn and nanomat-like structure) on nanofilm optical properties. The surface-active layer of the nanofilm of ZnO nanoparticles (ZnO NPs) was passivated with natural organic SOL leaves hydrothermally, then accumulated on zinc oxide nanorods (ZnO NRs). The nanofilms were fabricated (with and without PEO) on glass substrate (at 85 °C for 16 h) via chemical solution deposition (CSD). The samples were characterized by UV-vis, PL, FESEM, XRD, and TEM measurements. TEM micrographs confirmed the nucleation of ZnO NPs around 4 nm and the size distribution at 1.2 nm of ZnO QDs as an influence of the quantum confinement effect (QCE). The nanofilms fabricated with SOL surfactant (which works as a capping agent for ZnO NPs) represent distinct optoelectronic properties when compared to bulk ZnO. FESEM images of the nanofilms revealed nanoyarn and nanomat-like structures resembling morphologies. The XRD patterns of the samples exhibited the existence of ZnO nanocrystallites (ZnO NCs) with (100), (002), and (101) growth planes. The nanofilms fabricated represented a distinct optical property through absorption and broad emission, as the optical energy band gap reduced as the nanofilms annealed (at 120 ℃). Based on the obtained results, it was established that phytochemicals extracted from organic natural SOL leaves have a distinct influence on zoic oxide nanofilm fabrication, which may be useful for visible light spectrum trapping. The nanofilms can be used in photovoltaic solar cell applications.

The Impact of Co Doping and Annealing Temperature on the Electrochemical Performance and Structural Characteristics of SnO2 Nanoparticulate Photoanodes.

Obtaining H2 energy from H2O using the most abundant solar radiation is an outstanding approach to zero pollution. This work focuses on studying the effect of Co doping and calcination on the structure, morphology, and optical properties of spin-coated SnO2 films as well as their photoelectrochemical (PEC) efficiency. The structures and morphologies of the films were investigated by XRD, AFM, and Raman spectra. The results confirmed the preparation of SnO2 of the rutile phase, with crystallite sizes in the range of 18.4-29.2 nm. AFM showed the granular structure and smooth surfaces having limited roughness. UV-Vis spectroscopy showed that the absorption spectra depend on the calcination temperature and the Co content, and the films have optical bandgap (Eg) in the range of 3.67-3.93 eV. The prepared samples were applied for the PEC hydrogen generation after optimizing the sample doping ratio, using electrolyte (HCl, Na2SO4, NaOH), electrode reusability, applied temperature, and monochromatic illumination. Additionally, the electrode stability, thermodynamic parameters, conversion efficiency, number of hydrogen moles, and PEC impedance were evaluated and discussed, while the SnO2 films were used as working electrodes and platinum sheet as an auxiliary or counter electrode (2-electrode system) and both were dipped in the electrolyte. The highest photocurrent (21.25 mA/cm2), number of hydrogen moles (20.4 mmol/h.cm2), incident photon-to-current change efficiency (6.892%@307 nm and +1 V), and the absorbed photon-to-current conversion efficiency (4.61% at ~500 nm and +1 V) were recorded for the 2.5% Co-doped SnO2 photoanode that annealed at 673 K.

The Influence of Electrode Thickness on the Structure and Water Splitting Performance of Iridium Oxide Nanostructured Films.

For a safe environment, humanity should be oriented towards renewable energy technology. Water splitting (WS), utilizing a photoelectrode with suitable thickness, morphology, and conductivity, is essential for efficient hydrogen production. In this report, iridium oxide (IrOx) films of high conductivity were spin-cast on glass substrates. FE-SEM showed that the films are of nanorod morphology and different thicknesses. UV-Vis spectra indicated that the absorption and reflectance of the films depend on their thickness. The optical band gap (Eg) was increased from 2.925 eV to 3.07 eV by varying the spin speed (SS) of the substrates in a range of 1.5 × 103-4.5 × 103 rpm. It was clear from the micro-Raman spectra that the films were amorphous. The Eg vibrational mode of Ir-O stretching was red-shifted from 563 cm-1 (for the rutile IrO2 single crystal) to 553 cm-1. The IrOx films were used to develop photoelectrochemical (PEC) hydrogen production catalysts in 0.5M of sodium sulfite heptahydrate Na2SO3·7H2O (2-electrode system), which exhibits higher hydrogen evaluation (HE) reaction activity, which is proportional to the thickness and absorbance of the used IrOx photocathode, as it showed an incident photon-to-current efficiency (IPCE%) of 7.069% at 390 nm and -1 V. Photocurrent density (Jph = 2.38 mA/cm2 at -1 V vs. platinum) and PEC hydrogen generation rate (83.68 mmol/ h cm2 at 1 V) are the best characteristics of the best electrode (the thickest and most absorbent IrOx photocathode). At -1 V and 500 nm, the absorbed photon-to-current conversion efficiency (APCE%) was 7.84%. Electrode stability, thermodynamic factors, solar-to-hydrogen conversion efficiency (STH), and electrochemical impedance spectroscopies (EISs) were also studied.

Quantum Coherence and Total Phase in Semiconductor Microcavities for Multi-Photon Excitation.

We examine how the weak excitation regime of a quantum well confined in a semiconductor microcavity (SM) influences the dynamics of quantum coherence and the total phase. We analyze the impact of the physical parameters on different quantumness measures, and illustrate their numerical results. We show that the amount of the coherence and total phase in the SMs for multi-photon excitation can be improved and controlled by the strength of the field, exciton-photon coupling, cavity dissipation rate, and excitonic spontaneous emission rate. We illustrate how the fidelity varies depending on the physical parameters. These results might have far-reaching ramifications not just in quantum information processing and optics, but also in physics at large.

Fabrication of TiO2/NiO p-n Nanocomposite for Enhancement Dye Photodegradation under Solar Radiation.

A p-n nanocomposite based on TiO2 nanotubes (NTs) and NiO nanoparticles (NPs) was designed and optimized in this study to improve the photocatalytic performance of methylene blue (MB). The hydrothermal technique has been used to produce TiO2/NiO nanocomposites with different NiO NPs weight ratios; 1TiO2:1NiO, 1TiO2:2NiO, and 1TiO2:3NiO. The crystal phase, chemical composition, optical properties, and morphology of TiO2/NiO were explored by various techniques. TiO2 NTs have a monoclinic structure, while NiO NPs have a cubic structure, according to the structural study. The bandgap of TiO2 NTs was reduced from 3.54 eV to 2.69 eV after controlling the NiO NPs weight ratio. The TiO2/2NiO nanocomposite showed the best photodegradation efficiency. Within 45 min of solar light irradiation, the efficiency of MB dye degradation using TiO2/2NiO hits 99.5% versus 73% using pure TiO2 NTs. Furthermore, the catalytic photodegradation efficiency did not deteriorate significantly even after five reusability cycles, intimating the high stability of the TiO2/2NiO nanocomposite. This suggests that the loading of NiO NPs into TiO2 NTs lowers the recombination of photo-produced electron/hole pairs and enlarged solar spectral response range, which results in improved photocatalytic activity. The mechanism of charge transfer in the TiO2/NiO and kinetic models were discussed for the photodegradation of MB.

High-Performance pH Sensor Electrodes Based on a Hexagonal Pt Nanoparticle Array-Coated Nanoporous Alumina Membrane.

Porous anodic alumina membranes coated with Pt nanoparticles (PAAM/Pt) have been employed as pH sensor electrodes for H+ ion detection. The PAAM was designed using a two-step anodization process. Pt nanoparticles were then sputtered onto the membrane at different deposition times. The membrane's morphological, chemical, and optical characteristics were carefully assessed following the fabrication stage using a variety of analytical techniques. The potential of the PAAM/Pt sensor electrode was investigated by measuring the potential using a simple potentiometric method. The effects of depositing Pt nanoparticles for 3-7 min on sensor electrode sensitivity were examined. The optimal potentiometric Nernstian response slope for the PAAM/Pt sensor electrode with 5 min Pt sputter coating is 56.31 mV/decade in the pH range of 3.0 to 10 at 293 K. Additionally, the PAAM/Pt sensor electrode's stability and selectivity in various ions solutions were examined. The sensor electrode had a lifetime of more than six weeks and was kept in a normal air environment.

Green synthesis of gold nanoparticles in Gum Arabic using pulsed laser ablation for CT imaging.

Laser ablation synthesis in liquid solution (PLAL) is a green technique that allows for the physical formation of nanomaterials. This study indicates the preparation of stable gold nanoparticles (AuNPs) in Gum Arabic (GA) solution via laser ablation as a CT contrast agent. The optical properties were achieved using the absorption spectroscopic technique whereas the morphology and size distribution were investigated by TEM and ImageJ software. TEM image shows greater stability and spherical shape of GA-AuNPs with smaller size at 1.85 ± 0.99 nm compared to AuNPs without GA. The absorption spectrum of pure AuNPs has a lower absorption peak height in the visible range at λ = 521 nm, while the spectrum of GA-AuNPs has a higher plasmon peak height at λ = 514 nm with a blue shift towards lower wavelengths. The concentration of GA that dissolved in 10 mL of DI water via laser ablation is set at 20 mg. Increasing the number of pulses has only a minor effect on particle size distribution, which remains tiny in the nanometer range (less than 3 nm). For energies greater than 200 mJ, there is a blue shift toward shorter wavelengths. As the concentration of GA-AuNPs increases, the CT number is also increased indicating good image contrast. It can be concluded that there is a positive and significant influence of GA as a reducing agent for AuNPs, and a contrast agent for CT imaging which highlights its superiority in future medical applications.

Design and Characterization of Zeolite/Serpentine Nanocomposite Photocatalyst for Solar Hydrogen Generation.

In this work, a low-cost, high-yield hydrothermal treatment was used to produce nanozeolite (Zeo), nanoserpentine (Serp), and Zeo/Serp nanocomposites with weight ratios of 1:1 and 2:1. At 250 °C for six hours, the hydrothermal treatment was conducted. Various methods are used to explore the morphologies, structures, compositions, and optical characteristics of the generated nanostructures. The morphological study revealed structures made of nanofibers, nanorods, and hybrid nanofibril/nanorods. The structural study showed clinoptilolite monoclinic zeolite and antigorite monoclinic serpentine with traces of talcum mineral and carbonates. As a novel photoelectrochemical catalyst, the performance of the Zeo/Serp (2:1) composite was evaluated for solar hydrogen generation from water splitting relative to its constituents. At -1 V, the Zeo/Serp (2:1) composite produced a maximum current density of 8.44 mA/g versus 7.01, 6.74, and 6.6 mA/g for hydrothermally treated Zeo/Serp (1:1), Zeo, and Serp, respectively. The Zeo/Serp (2:1) photocatalysts had a solar-to-hydrogen conversion efficiency (STH) of 6.5% and an estimated hydrogen output rate of 14.43 mmole/h.g. Consequently, the current research paved the way for low-cost photoelectrochemical catalytic material for efficient solar hydrogen production by water splitting.

Complementary Study Based on DFT of Optical and Electronic Properties of New Copolymer PVK-F8T2.

This article is mainly a complementary study of a novel part of π-conjugated copolymers based on the poly (N-vinylcarbazole) (PVK) and poly (9,9-dioctylfluorene-co-bithiophene) (F8T2) unit based on the Density Functional Theory (DFT) and Time-Dependent Density Functional Theory (TD-DFT). This study is carried out to explore the structural and optoelectronic characteristics of a new organic material named PVK-F8T2. First, the structural, optical (absorption, photoluminescence, optical transition), electronic (molecular orbital (MO), energy-level diagram) and vibratory parameters of infrared (IR) were computed and compared with experimental studies. In addition, we calculated the level energy of the excited states and their corresponding transitions. Obviously, electronic parameters such as highest occupied and lowest unoccupied molecular orbital (HOMO and LUMO), ionization potential (IP), electronic affinity (EA) and the energy band gap (Eg) were computed in order to elucidate the intramolecular charge transport and to establish the energetic diagrams of the PVK-F8T2 copolymer for different states. The results obtained looked with precision at future optoelectronic applications. From these results, we have shown that the PVK-F8T2 has significant optoelectronic properties and seems usable as an active layer in organic light-emitting diodes (OLEDs).

Optical and Thermal Investigations of New Schiff Base/Ester Systems in Pure and Mixed States.

New mesomorphic series, 4-hexadecyloxy phenyl-imino-4'-(3-methoxyphenyl)-4″-alkoxybenzoates (An), were prepared and investigated with different thermal and mesomorphic techniques. The synthesized homologous series constitutes four members that differ from each other in the terminal length of flexible chain (n) attached to phenyl ester moiety, which varies between n = 6, 8, 10, and 12 carbons. A lateral CH3O group is attached to the central benzene ring in the meta position with respect to the ester moiety. Molecular structures of all newly prepared homologues were elucidated via FT-IR, 1H and 13C NMR spectroscopy. Mesomorphic and thermal properties were examined by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and the mesophases identified by polarized optical microscopy (POM). DSC and POM examinations revealed that all members of the present series (An) exhibit a purely enantiotropic nematic (N) phase. Comparative evaluations and binary phase diagrams were established between the present homologues and their corresponding shorter one (Bn). The examination revealed that, the length of the flexible alkoxy chain incorporated into the phenylimino moiety is highly effective on the temperature range and stability of the mesophase observed. With respect to the binary mixtures An/Bn, the exhibited N phase showed to cover the whole composition range with eutectic behavior.

Optical investigations and photoactive solar energy applications of new synthesized Schiff base liquid crystal derivatives.

New homologues series of liquid crystalline materials namely, (E)-3-methoxy-4-[(p-tolylimino)methyl]phenyl 4-alkloxybenzoates (I-n), were designed and evaluated for their mesomorphic and optical behavior. The prepared series constitutes three members that differ from each other by the terminally attached alkoxy chain group, these vary between 6 and 12 carbons. A laterally OCH3 group is incorporated into the central benzene ring in meta position with respect to the ester moiety. Mesomorphic characterizations of the prepared derivatives are conducted using differential scanning-calorimetry (DSC), polarized optical-microscopy (POM). Molecular structures were elucidated by elemental analyses and NMR spectroscopy. DSC and POM investigations revealed that all the synthesized derivatives are purely nematogenic exhibiting only nematic (N) mesophase, except for the longest chain derivative (I-12) that is dimorphic possesses smectic A and N phases. Moreover, all members of the group have a wide mesomorphic range with high thermal nematic stability. A comparative study was established between the present derivative (I-6) and their previously prepared isomer. The results indicated that the location exchange of the polar compact group (CH3) influences the N mesophase stability and range. The electrical measurements revealed that all synthesized series I-n show Ohmic behaviors with effective electric resistances in the GΩ range. Under white light illumination, the effective electric conductivity for the compound I-8 is five times that obtained in dark conditions. This derivative also showed two direct optical band gaps in the UV and visible light range. In addition, I-6 has band energy gaps of values 1.07 and 2.79 eV, which are suitable for solar energy applications.