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The present work describes the synthesis of some poly(ethylene oxide)-based nanocomposite polymer electrolyte films using various silica nanostructures as the inorganic filler by simple solution mixing technique, in which the nature of the silica nanostructures play a vital role in modulating their electrochemical performances at room temperature. The silica nanostructures are prepared by ammonical hydrolysis of tetraethyl orthosilicate following the modified St6ber method. The resulting films are characterized by X-ray diffraction and differential scanning calorimeter to study their crystallinity. Room temperature AC impedance spectroscopy is utilized to determine the Li+ ion conductivity of the resulting films. The observed conductivity values of various NCPE films depend on the nature of silica filling as well as on their surface characteristics and also on the varying PEO-Li+ ratio, which is observed to be in the order of 10(-7)-10(-6) S cm(-1).
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Nanocompostos/química , Nanopartículas/química , Polietilenoglicóis/química , Dióxido de Silício/química , Condutividade Elétrica , Lítio/química , TemperaturaRESUMO
Herein, a one-step hydrothermal reaction is developed to synthesize a Ni-doped ReS2 nanostructure with sulphur defects. The material exhibited excellent OER activity with a current density of 10 mA cm-2 at an overpotential of 270 mV, a low Tafel slope of 31 mV dec-1, and good long-term durability of 10 h in 1 M KOH. It shows high faradaic efficiency of 96%, benefiting from the rapid charge transfer caused by the concerted effect of Ni-in and S-out on the ReS2 nanostructure.
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The origin of ferroelectricity in the cubic phase of BaTi1-xHfxO3has been investigated. The presence of well-defined ferroelectric polarization versus electric field (PE) hysteresis loop in the samples with global cubic symmetry suggests the presence of 'local polar regions', induced possibly due to the huge difference in the electronegativity and also difference in the ionic radii of Hf+4and Ti+4ions, which may lead to local structural disorder. The presence of polar regions is also supported through the appearance of A1(TO) polar mode in Raman spectra which in principle should be absent in the samples with cubic symmetry. The results are discussed in terms of disorder-induced local dipoles due to the electronegativity difference between Hf and Ti ions.
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Android is a free open-source operating system (OS), which allows an in-depth understanding of its architecture. Therefore, many manufacturers are utilizing this OS to produce mobile devices (smartphones, smartwatch, and smart glasses) in different brands, including Google Pixel, Motorola, Samsung, and Sony. Notably, the employment of OS leads to a rapid increase in the number of Android users. However, unethical authors tend to develop malware in the devices for wealth, fame, or private purposes. Although practitioners conduct intrusion detection analyses, such as static analysis, there is an inadequate number of review articles discussing the research efforts on this type of analysis. Therefore, this study discusses the articles published from 2009 until 2019 and analyses the steps in the static analysis (reverse engineer, features, and classification) with taxonomy. Following that, the research issue in static analysis is also highlighted. Overall, this study serves as the guidance for novice security practitioners and expert researchers in the proposal of novel research to detect malware through static analysis.
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Background Among the dialysis population, left ventricular hypertrophy (LVH) is becoming a major cause of cardiovascular death, mainly due to myocardial infarction, heart failure, and arrhythmias. Electrocardiography (ECG) is a cheap and easily available test to detect the presence of left ventricular hypertrophy. The basic purpose of this study was to assess the frequency of left ventricular hypertrophy among the maintenance hemodialysis patients by applying different voltage criteria for the diagnosis of LVH and its relationship with various biophysical and biochemical parameters. Methods A total of 68 patients of end-stage renal disease (ESRD) were included in the study who were on maintenance hemodialysis at the dialysis center of Sughra Shafi Hospital. Baseline characteristics were recorded from the patients' data. Blood samples were drawn and electrocardiographs were taken, both before and after hemodialysis. Results Results showed variability in the detection of left ventricular hypertrophy in the pre- and post-dialysis period, as it was positive for 45%, 21%, and 17% in the pre-dialysis period versus 40%, 32%, and 25% in the post-dialysis period, when the Framingham, Sokolow-Lyon, and Cornell criteria were applied, respectively. The study showed a significant relationship between left ventricular hypertrophy with a high body mass index (BMI), hypertension, and pre- and post-dialysis hypomagnesemia (P <0.05). A significant association was also seen with low serum albumin levels over the past year. Conclusion According to this study, almost half of the dialysis patients were having left ventricle hypertrophy when Framingham criteria were applied. Good control of factors that are significantly associated with the occurrence of left ventricular hypertrophy can reduce morbidity and mortality among dialysis patients secondary to cardiovascular events. In this study, these factors included hypertension, hypomagnesemia, hypoalbuminemia, and high BMI.
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UNLABELLED: Tobacco is used worldwide, but culture shapes the specific methods and patterns of its use, with implications for uptake, continuation and cessation. The purpose of this paper is to highlight the range of tobacco use which occurs worldwide, in the context of cultural and social norms. Many of these practices are relevant to the U.K., some having been brought here by migrants, with consequences for general and oral health. CLINICAL RELEVANCE: It is important that dental professionals are aware of the range of tobacco-related practices prevalent in the variety of dental patients that they may encounter.
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Cultura , Fumar , Atitude Frente a Saúde , Relações Dentista-Paciente , Emigrantes e Imigrantes/psicologia , Etnicidade/psicologia , Feminino , Saúde Global , Nível de Saúde , Humanos , Masculino , Saúde Bucal , Fatores Sexuais , Fumar/psicologia , Meio Social , Indústria do Tabaco , Abandono do Uso de Tabaco/métodos , Abandono do Uso de Tabaco/psicologia , Tabaco sem Fumaça , Reino UnidoRESUMO
AIMS AND OBJECTIVES: As part of a student elective, this pilot study aimed at investigating attitudes and practices concerning gutka use in a town in India. It was hoped that information gained would assist in formulating an appropriate health education programme to encourage gutka cessation locally and would provide more information about a habit which is also relevant to some UK South Asian populations. DESIGN AND SETTING: 124 consecutively attending subjects (103 males and 21 females) at a charity-run dental clinic in Chitrakoot, India, were interviewed using a semi-structured questionnaire. MAIN FINDINGS: 57 (46%) of the respondents, of whom there were more males than females (103 v. 21), reported current gutka use. There were no differences between users and non-users by age or educational attainment. Users found gutka 'helpful' in relieving tension, aiding con- centration, combating bad breath and as a leisure activity. They all cited other family members who were using gutka as compared to only 40% of the gutka non-users. Cancer was mentioned as a harmful outcome of gutka use more frequently by non-users. Of the 57 gutka chewers, 36 also chewed paan with tobacco and 20 smoked cigarettes. CONCLUSIONS: Gutka chewing involved almost half of the study population and proportionately more males than females. The habit was endemic within families. Many gutka chewers also smoked, chewed paan or drank alcohol, representing a high-risk behaviour for oral cancer. Proportionately more non-chewers were aware of the link with cancer. There are clear implications for health promotion in India. General dental practitioners in the UK should also be aware of the possibility that this habit is becoming more widely adopted in South Asian communities here, involving young children as well as adults. Research into gutka use is also required in the UK.
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Areca , Conhecimentos, Atitudes e Prática em Saúde , Transtornos Relacionados ao Uso de Substâncias/psicologia , Adolescente , Adulto , Criança , Escolaridade , Feminino , Humanos , Índia , Masculino , Pessoa de Meia-Idade , Projetos Piloto , Inquéritos e QuestionáriosRESUMO
UNLABELLED: OBJECTIVE; The aim of this international study was to develop a valid and reliable psychometric measure to examine the extent to which parents' attitudes about engaging in twice-daily tooth brushing and controlling sugar snacking predict these respective behaviours in their children. A supplementary objective was to assess whether ethnic group, culture, level of deprivation or children's caries experience impact upon the relationships between oral health related behaviours, attitudes to these respective behaviours and to dental caries. CLINICAL SETTING: Nurseries, health centres and dental clinics in 17 countries. PARTICIPANTS: 2822 children aged 3 to 4 years and their parents. MAIN OUTCOME MEASURES: Dental examination of children and questionnaire to parents. RESULTS: Factor analysis identified 8 coherent attitudes towards toothbrushing, sugar snacking and childhood caries. Attitudes were significantly different in families from deprived and non-deprived backgrounds and in families of children with and without caries. Parents perception of their ability to control their children's toothbrushing and sugar snacking habits were the most significant predictor of whether or not favourable habits were reported. Some differences were found by site and ethnic group. CONCLUSIONS: This study supports the hypothesis that parental attitudes significantly impact on the establishment of habits favourable to oral health. An appreciation of the impact of cultural and ethnic diversity is important in understanding how parental attitudes to oral health vary. Further research should examine in a prospective intervention whether enhancing parenting skills is an effective route to preventing childhood caries.
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Atitude Frente a Saúde , Cultura , Etnicidade , Família , Comportamento Alimentar , Higiene Bucal , Adulto , Comportamento Infantil , Pré-Escolar , Carência Cultural , Cárie Dentária/prevenção & controle , Sacarose Alimentar/administração & dosagem , Família/etnologia , Família/psicologia , Feminino , Comportamentos Relacionados com a Saúde , Conhecimentos, Atitudes e Prática em Saúde , Humanos , Masculino , Relações Pais-Filho , Poder Familiar , Fatores Socioeconômicos , Escovação DentáriaRESUMO
OBJECTIVE: To undertake formative studies investigating how the experience of dental caries in young children living in diverse settings relates to familial and cultural perceptions and beliefs, oral health-related behaviour and oral microflora. PARTICIPANTS: The scientific consortium came from 27 sites in 17 countries, each site followed a common protocol. Each aimed to recruit 100 families with children aged 3 or 4 years, half from deprived backgrounds, and within deprived and non-deprived groups, half to be "caries-free" and half to have at least 3 decayed teeth. OUTCOME MEASURES: Parents completed a questionnaire, developed using psychological models, on their beliefs, attitudes and behaviours related to their child's oral health. 10% of children had plaque sampled. RESULTS: 2,822 children and families were recruited. In multivariate analyses, reported toothbrushing behaviours that doubled the odds of being caries-free were a combination of brushing before age 1, brushing twice a day and adult involvement in brushing. Analyses combining beliefs, attitudes and behaviours found that parents' perceived ability to implement regular toothbrushing into their child's daily routine was the most important predictor of whether children had caries and this factor persisted in children from disadvantaged communities. 90% of children with lactobacillus had caries. CONCLUSIONS: Parental beliefs and attitudes play a key role in moderating oral health related behaviour in young children and in determining whether they develop caries. Further research is indicated to determine whether supporting the development of parenting skills would reduce dental caries in children from disadvantaged communities independent of ethnic origin.