Management of tannery waste effluents towards the reclamation of clean water using an integrated membrane system: A state-of-the-art review.

Tanning and other leather processing methods utilize a large amount of freshwater, dyes, chemicals, and salts and produce toxic waste, raising questions regarding their environmental sensitivity and eco-friendly nature. Total suspended solids, total dissolved solids, chemical oxygen demand, and ions such as chromium, sulfate, and chloride turn tannery wastewater exceedingly toxic for any living species. Therefore, it is imperative to treat tannery effluent, and existing plants must be examined and upgraded to keep up with recent technological developments. Different conventional techniques to treat tannery wastewater have been reported based on their pollutant removal efficiencies, advantages, and disadvantages. Research on photo-assisted catalyst-enhanced deterioration has inferred that both homogeneous and heterogeneous catalysis can be established as green initiatives, the latter being more efficient at degrading organic pollutants. However, the scientific community experiences significant problems developing a feasible treatment technique owing to the long degradation times and low removal efficiency. Hence, there is a chance for an improved solution to the problem of treating tannery wastewater through the development of a hybrid technology that uses flocculation as the primary treatment, a unique integrated photo-catalyst in a precision-designed reactor as the secondary method, and finally, membrane-based tertiary treatment to recover the spent catalyst and reclaimable water. This review gives an understanding of the progressive advancement of a cutting-edge membrane-based system for the management of tanning industrial waste effluents towards the reclamation of clean water. Adaptable routes toward sludge disposal and the reviews on techno-economic assessments have been shown in detail, strengthening the scale-up confidence for implementing such innovative hybrid systems.

Strategic management of nitrate pollution from contaminated water using viable adsorbents: An economic assessment-based review with possible policy suggestions.

Groundwater contaminated with nitrate has prompted a flurry of research studies around the world in the recent years to address this burning environmental issue. The common presence of nitrates in groundwater, wastewater, and surface waters has thrown an enormously critical challenge to the global research communities to provide safe and clean drinking water to municipalities. As per WHO, the maximum permissible limit of nitrate in drinking water is 10 mg/L and in groundwater is 50 mg/L; exceeding the limits, several human health problems are observed. Adsorption, ion-exchange processes, membrane-based approaches, electrochemical and chemical procedures, biological methods, filtration, nanoparticles, etc. have been well investigated and reviewed to reduce nitrate levels in water samples in the recent years. Process conditions, as well as the efficacy of various approaches, were discovered to influence different techniques for nitrate mitigation. But, because of low cost, simple operation, easy handling, and high removal effectiveness, adsorption has been found to be the most suitable and efficient approach. The main objectives of this review primarily focuses on the creation of a naturally abundant, cost-effective innovative abundant material, such as activated clay particles combined with iron oxide. Oxide-clay nanocomposite materials, effectively remove nitrate with higher removal efficiency along with recovery of nitrate concentrated sludge. Such methods stand out as flexible and economic ways for capturing stabilized nitrate in solid matrices to satisfy long-term operations. A techno-economic assessment along with suitable policy suggestions have been reported to justify the viability of the brighter processes. Indeed, this kind of analytical review appears ideal for municipal community recommendations on abatement of excess nitrate to supply of clean water.

An economical strategy towards the managing of selenium pollution from contaminated water: A current state-of-the-art review.

During the last few decades, contamination of selenium (Se) in groundwater has turned out to be a major environmental concern to provide safe drinking water. The content of selenium in such contaminated water might range from 400 to 700 µg/L, where bringing it down to a safe level of 40 µg/L for municipal water supply employing appropriate methodologies is a major challenge for the global researcher communities. The current review focuses mostly on the governing selenium remediation technologies such as coagulation-flocculation, electrocoagulation, bioremediation, membrane-based approaches, adsorption, electro-kinetics, chemical precipitation, and reduction methods. This study emphasizes on the development of a variety of low-cost adsorbents and metal oxides for the selenium decontamination from groundwater as a cutting-edge technology development along with their applicability, and environmental concerns. Moreover, after the removal, the recovery methodologies using appropriate materials are analyzed which is the need of the hour for the reutilization of selenium in different processing industries for the generation of high valued products. From the literature survey, it has been found that hematite modified magnetic nanoparticles (MNP) efficiently adsorb Se (IV) (25.0 mg/g) from contaminated groundwater. MNP@hematite reduced Se (IV) concentration from 100 g/L to 10 g/L in 10 min at pH 4-9 using a dosage of 1 g/L. In 15 min, the magnetic adsorbent can be recycled and regenerated using a 10 mM NaOH solution. The adsorption and desorption efficiencies were over 97% and 82% for five consecutive cycles, respectively. To encourage the notion towards scale-up, a techno-economic evaluation with possible environmentally sensitive policy analysis has been introduced in this article to introspect the aspects of sustainability. This type of assessment is anticipated to be extremely encouraging to convey crucial recommendations to the scientific communities in order to produce high efficiency selenium elimination and further recovery from contaminated groundwater.

Optimizing methanol synthesis from CO2 using graphene-based heterogeneous photocatalyst under RSM and ANN-driven parametric optimization for achieving better suitability.

Assessment of the performance of linear and nonlinear regression-based methods for estimating in situ catalytic CO2 transformations employing TiO2/Cu coupled with hydrogen exfoliation graphene (HEG) has been investigated. The yield of methanol was thoroughly optimized and predicted using response surface methodology (RSM) and artificial neural network (ANN) model after rigorous experimentation and comparison. Amongst the different types of HEG loading from 10 to 40 wt%, the 30 wt% in the HEG-TiO2/Cu assisted photosynthetic catalyst was found to be successful in providing the highest conversion efficiency of methanol from CO2. The most influencing parameters, HEG dosing and inflow rate of CO2, were found to affect the conversion rate in the acidic reaction regime (at pH of 3). According to RSM and ANN, the optimum methanol yields were 36.3 mg g-1 of catalyst and 37.3 mg g-1 of catalyst, respectively. Through the comparison of performances using the least squared error analysis, the nonlinear regression-based ANN showed a better determination coefficient (overall R2 > 0.985) than the linear regression-based RSM model (overall R2 ∼ 0.97). Even though both models performed well, ANN, consisting of 9 neurons in the input and 1 hidden layer, could predict optimum results closer to RSM in terms of agreement with the experimental outcome.

Reutilization of ferro-arsenic waste sludge for the development of concrete blocks through solidification: conservation of natural aggregates with policy suggestion.

In the present study, arsenic sludge and iron sludge extracted from a laboratory scale water treatment plant were aimed to reutilize for the development of concrete blocks. Three different grades (M15, M20 and M25) of concrete blocks were made by blending of arsenic sludge and improved iron sludge (50% sand and 40% iron sludge) in the range of density of 425 to 535 kg/m3 at an optimum ratio of 10:90 (arsenic: iron sludge) followed by mixing of designed quantity cement, coarse aggregates, water and additives. Concrete blocks developed based on this such combination exhibited 26 MPa, 32 MPa and 41 MPa compressive strengths, and 4.68 MPa, 5.92 MPa and 7.78 MPa tensile strengths for M15, M20 and M25, respectively. In comparison with the developed concrete blocks and the blocks made with 10% arsenic sludge and 90% fresh sand, the developed ones (employing 50% sand, 40% iron sludge and 10% arsenic sludge) showed more than 200% higher strength perseverance on average. Successful Toxicity Characteristic Leaching Procedure (TCLP) and compressive strength of the sludge-fixed concrete cubes classified it as a non-hazardous and completely safe to use value-added material. This process involves stabilization of arsenic-rich sludge generated from high-volume long-run laboratory-based arsenic-iron abatement set-up from contaminated water with successful fixation in solid matrix of concrete through complete substitution of natural fine aggregates (river sand) in cement mixture. Techno-economic assessment reveals such concrete block preparation at $0.09 each which is lesser than 1/2 of the present market price of same quality concrete block in India.

Development of concrete blocks by fixation of large-volume arsenic- and iron-rich sludge.10% arsenic sludge with 40% iron sludge showed the highest strength resistance.50% replacement of fresh river-sand without deterioration in strength of concrete blocks.TCLP test confirmed no chances of recontamination through leachate formation. Safe disposal and re-utilization of contaminating wastes for value-added purposes.Developed concrete blocks are lesser than 1/2 cost of the commercially available ones.