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Carbohydr Polym ; 90(4): 1609-13, 2012 Nov 06.
Artigo em Inglês | MEDLINE | ID: mdl-22944423

RESUMO

Nanocellulose from sugarcane bagasse was isolated by high pressure homogenization in a homogeneous media. Pretreatment with an ionic liquid (1-butyl-3-methylimidazolium chloride ([Bmim]Cl)) was initially involved to dissolve the bagasse cellulose. Subsequently, the homogeneous solution was passed through a high pressure homogenizer without any clogging. The nanocellulose was obtained at 80 MPa for 30 cycles with recovery of 90% under the optimum refining condition. Nanocellulose had been characterized by Fourier transformed infrared spectra, X-ray diffraction, thermogravimetric analysis, rheological measurements and transmission electron microscopy. The results showed that nanocellulose was 10-20 nm in diameter, and presented lower thermal stability and crystallinity than the original cellulose. The developed nanocellulose would be a very versatile renewable material.


Assuntos
Celulose/isolamento & purificação , Imidazóis/química , Nanoestruturas/química , Saccharum/química , Celulose/química , Celulose/ultraestrutura , Hidrólise , Microscopia Eletrônica de Transmissão , Estrutura Molecular , Pressão , Espectroscopia de Infravermelho com Transformada de Fourier , Temperatura , Termogravimetria , Difração de Raios X
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