The interactions of site-specific factors on riparian buffer effectiveness across multiple pollutants: A review.

Following decades of riparian buffer zone (RBZ) studies there remains a need to look across individual site data for collective evidence on the site-specific pollution mitigation and river water quality. We explored primary study evidence on runoff, sediment, P, N, coliforms and pesticides using complimentary styles of metadata interpretation. A quantitative assessment of pollution retention (75 studies, 474 data rows) derived relationships for retention versus width, including significant covariates of clay particle size and buffer slope for sediment, total and dissolved P. Total N and coliforms related to texture and slope but were independent of width. Other factors across pollutants were inconsistently reported. With limitations on quantitative studies a second approach examined factor significance (formal testing versus inferred; 93 studies) across source pressure, transport/physical, vegetation and soil biogeochemical factors on pollution effectiveness. The RBZ evidence showed considerable disagreement and bias in shorter term study implications on longer-term processes. Screening for stronger evidence by study number and agreement left fifteen factors informing on at least one pollutant, whereas only rainfall intensity, preferential deposition, tree planting, soil infiltration remained addressing three or more pollutants. Key messages were that: data complexities, from short-term trapping in upper buffer edges and so-called 'negative effectiveness' associated with internal recycling and/or errors in constraining mass inputs for dissolved pollutant and subsurface transport require careful interpretation; RBZ intervention and study durations were limited compared to effect times (particularly vegetation management and changing soil conditions); factors affect pollutants with particulate and dissolved phases differently and must be understood to limit RBZ pollution swapping. Buffer functioning is highly site-specific. To understand this better attention should be given to revisiting studies of vegetation management to extend timeframes, wider study of belowground (soil biogeochemical and transport) processes and studies should document site contexts across source pressures, riparian hydrological, soil and vegetation factors.

Using a multi-dimensional approach for catchment scale herbicide pollution assessments.

Worldwide herbicide use in agriculture, whilst safeguarding yields also presents water quality issues. Controlling factors in agricultural catchments include both static and dynamic parameters. The present study investigated the occurrence of herbicides in streams and groundwater in two meso-scale catchments with contrasting flow controls and agricultural landuse (grassland and arable land). Using a multi-dimensional approach, streams were monitored from November 2018 to November 2019 using Chemcatcher® passive sampling devices and groundwater was sampled in 95 private drinking water wells. The concentrations of herbicides were larger in the stream of the Grassland catchment (8.9-472.6 ng L-1) dominated by poorly drained soils than in the Arable catchment (0.9-169.1 ng L-1) dominated by well-drained soils. Incidental losses of herbicides during time of application and low flows in summer caused concentrations of MCPA, Fluroxypyr, Trichlorpyr, Clopyralid and Mecoprop to exceeded the European Union (EU) drinking water standard due to a lack of dilution. Herbicides were present in the stream throughout the year and the total mass load was higher in winter flows, suggesting a persistence of primary chemical residues in soil and sub-surface environments and restricted degradation. Losses of herbicides to the streams were source limited and influenced by hydrological conditions. Herbicides were detected in 38% of surveyed drinking water wells. While most areas had concentrations below the EU drinking water standard some areas with well-drained soils in the Grassland catchment, had concentrations exceeding recommendations. Individual wells had concentrations of Clopyralid (619 ng L-1) and Trichlorpyr (650 ng L-1). Despite the study areas not usually associated with herbicide pollution, and annual mass loads being comparatively low, many herbicides were present in both surface and groundwater, sometimes above the recommendations for drinking water. This whole catchment assessment provides a basis to develop collaborative measures to mitigate pollution of water by herbicides.