RESUMO
Thermoelectric materials are used for the conversion of waste heat to electrical energy. The transport coefficients that determine their thermoelectric properties depend on the band structure and the relaxation time of the charge carriers. Both of these are significantly affected by electron-phonon coupling. In this work, using a combination of density functional theory and semiclassical Boltzmann transport theory, we have studied the effect of electron-phonon coupling in monolayers of ZrS2, BiI3 and PbI2. Our results show that in these ionic materials charge carriers are primarily scattered by the optical modes that strongly couple with them. From our study it is conclusively shown that neglecting the contributions of optical modes to electron-phonon coupling in these low-dimensional ionic solids, as is usually done in the computation of relaxation time from deformation theory, results in severe overestimation of the relaxation time. In particular, neglecting the scattering of the optical phonons results in about two orders of magnitude overestimation of relaxation times in these materials. Moreover, we also find that the renormalization of the band structure not only results in the reduction of band gaps but also changes the band dispersion, which strongly affect different transport properties like the electrical conductivity and Seebeck coefficient. Amongst these three materials, we observe that carrier relaxation time due to electron-phonon scattering is reduced as the ionicity of the material decreases.
RESUMO
We show the presence of universal features in the entanglement entropy of regularized boundary states for (1+1)D conformal field theories on a circle when the reduced density matrix is obtained by tracing over right- or left-moving modes. We derive a general formula for the left-right entanglement entropy in terms of the central charge and the modular S matrix of the theory. When the state is chosen to be an Ishibashi state, this measure of entanglement is shown to precisely reproduce the spatial entanglement entropy of a (2+1)D topological quantum field theory. We explicitly evaluate the left-right entanglement entropies for the Ising model, the tricritical Ising model and the su[over ^](2)_{k} Wess-Zumino-Witten model as examples.
RESUMO
Momentum space distribution of photons coming out of any light emitting material/device provides critical information about their underlying physical origin. Conventional methods of determining such properties impose specific instrumentational difficulties for probing samples kept within a low temperature cryostat. There were past studies to measure a one-dimensional coherence function, which could then be used for extracting momentum space information, as well as reports of measurements of just a two-dimensional (2D) coherence function. However, all of those are associated with additional experimental complexities. So, here we propose a simpler, modified Michelson interferometer based optical setup that is kept at room temperature and placed outside the low temperature cryostat at a distance away from it. We initially measure the 2D coherence function of emitted light, which can then be used to directly estimate the 2D in-plane momentum space distribution by calculating its fast Fourier transform. We also discuss how this experimental method can overcome instrumentational difficulties encountered in the past. Similar instrumentations can also be extended for momentum space resolved astronomical studies and telecommunications involving distant light sources.
RESUMO
An experimental technique is developed to simultaneously measure both temporal and spatial coherences of a light source by altering a standard Michelson interferometer, which has been primarily used for measuring temporal coherence only. Instead of using simple plane mirrors, two retroreflectors and their longitudinal and lateral movements are utilized to incorporate spatial coherence measurement using this modified Michelson interferometer. In general, one uses Young's double slit interferometer to measure spatial coherence. However, this modified interferometer can be used as an optical setup kept at room temperature outside a cryostat to measure the spatiotemporal coherence of a light source placed at cryogenic temperatures. This avoids the added complexities of modulation of interference fringe patterns due to single slit diffraction as well. The process of mixing of spatial and temporal parts of coherences is intrinsic to existing methods for dual measurements. We addressed these issues of spatiotemporal mixing, and we introduced a method of "temporal filtering" in spatial coherence measurements. We also developed a "curve overlap" method that is used to extend the range of the experimental setup during temporal coherence measurements without compromising the precision. Together, these methods provide major advantages over plane mirror based standard interferometric systems for dual measurements in avoiding systematic errors, which lead to inaccuracies, especially for light sources with low coherences.
RESUMO
The eigenstate thermalization hypothesis (ETH) provides a way to understand how an isolated quantum mechanical system can be approximated by a thermal density matrix. We find a class of operators in (1+1)-dimensional conformal field theories, consisting of quasiprimaries of the identity module, which satisfy the hypothesis only at the leading order in large central charge. In the context of subsystem ETH, this plays a role in the deviation of the reduced density matrices, corresponding to a finite energy density eigenstate from its hypothesized thermal approximation. The universal deviation in terms of the square of the trace-square distance goes as the eighth power of the subsystem fraction and is suppressed by powers of inverse central charge (c). Furthermore, the nonuniversal deviations from subsystem ETH are found to be proportional to the heavy-light-heavy structure constants which are typically exponentially suppressed in sqrt[h/c], where h is the conformal scaling dimension of the finite energy density state. We also examine the effects of the leading finite-size corrections.
RESUMO
We explore nanoscale hydrodynamical effects on synthesis and self-assembly of cadmium sulfide nanotubes oriented along one direction. These nanotubes are synthesized by horizontal capillary flow of two different chemical reagents from opposite directions through nanochannels of porous anodic alumina which are used primarily as nanoreactors. We show that uneven flow of different chemical precursors is responsible for directionally asymmetric growth of these nanotubes. On the basis of structural observations using scanning electron microscopy, we argue that chemohydrodynamic convective interfacial instability of multicomponent liquid-liquid reactive interface is necessary for sustained nucleation of these CdS nanotubes at the edges of these porous nanochannels over several hours. However, our estimates clearly suggest that classical hydrodynamics cannot account for the occurrence of such instabilities at these small length scales. Therefore, we present a case which necessitates further investigation and understanding of chemohydrodynamic fluid flow through nanoconfined channels in order to explain the occurrence of such interfacial instabilities at nanometer length scales.