Use of selected amendments for reducing metal mobility and ecotoxicity in contaminated bottom sediments.

The aims of the study were 1) to assess the suitability of selected amendments for reducing the mobility of metals in sediments by evaluating their effects on metal sorption capacity, and 2) to assess the ecotoxicity of sediment/amendment mixtures. Three different amendments were tested: cellulose waste, biochar, and dolomite. The efficiency of metal immobilization in mixtures was dependent on pH, which increased with concentrations of amendment. The higher negative charge observed for dolomite and cellulose waste corresponded with greater attraction of cations and enhanced metal sorption. For cellulose waste, the highest values of the Q parameter were attributed to the presence of OH groups, which corresponded with the highest immobilization of metals. Biochar reduced the negative surface charge, which highlights the importance of additional factors such as high specific surface area and volume of pores in metal immobilization. All amendments increased the SSA and VN2, indicating a higher number of sorption sites for metal immobilization. Most bioassays established a reduction of the ecotoxicity for amendments. Mixtures with dolomite (25%, 45% doses) and biochar (45% dose) were low toxic. Mixtures with cellulose waste were toxic or highly toxic. The mobility of metals from contaminated sediments can be limited by reused industry side products, which could contribute to further closing the circular economy loop.

Metal contamination in sediments of dam reservoirs: A multi-facetted generic risk assessment.

The quality of bottom sediments is a key factor for many functions of dam reservoirs, which include water supply, flood control and recreation. The aim of the study was to combine different pollution indices in a critical generic risk assessment of metal contamination of bottom sediments. Both geochemical and ecological indices reflected that sediment contamination was dominated by Zn, Pb and Cd. The ecological risk indices suggested a high riks for all three metals, whereas human health risks were high for Pb and Cd. An occasional local contamination of sediments with Cr and Ni was revealed, although at levels not expected to cause concerns about potential ecological or health risk. Sediments from the Rybnik reservoir for Cu only revealed a high potential ecological risk. EF turned to be as being the most useful, whereas TRI (∑TRI) was the most important ecological index. All multi-element indices suggested similar trends, indicating that Zn, Pb and Cd taken altogether had the greatest impact on the level of sediment contamination and posed the greatest potential ecological and health risks to organisms. The use of sequential BCR extraction and ecotoxicity analyses allowed for a multi-facetted generic risk assessment of metals in sediments of dam reservoirs.