Isotopic Ag-Cu-Pb record of silver circulation through 16th-18th century Spain.

Estimating global fluxes of precious metals is key to understanding early monetary systems. This work adds silver (Ag) to the metals (Pb and Cu) used so far to trace the provenance of coinage through variations in isotopic abundances. Silver, copper, and lead isotopes were measured in 91 coins from the East Mediterranean Antiquity and Roman world, medieval western Europe, 16th-18th century Spain, Mexico, and the Andes and show a great potential for provenance studies. Pre-1492 European silver can be distinguished from Mexican and Andean metal. European silver dominated Spanish coinage until Philip III, but had, 80 y later after the reign of Philip V, been flushed from the monetary mass and replaced by Mexican silver.

Tracing the origin of lithium in Li-ion batteries using lithium isotopes.

Rechargeable lithium-ion batteries (LIB) play a key role in the energy transition towards clean energy, powering electric vehicles, storing energy on renewable grids, and helping to cut emissions from transportation and energy sectors. Lithium (Li) demand is estimated to increase considerably in the near future, due to the growing need for clean-energy technologies. The corollary is that consumer expectations will also grow in terms of guarantees on the origin of Li and the efforts made to reduce the environmental and social impact potentially associated with its extraction. Today, the LIB-industry supply chain is very complex, making it difficult for end users to ensure that Li comes from environmentally and responsible sources. Using an innovative geochemical approach based on the analysis of Li isotopes of raw and processed materials, we show that Li isotope 'fingerprints' are a useful tool for determining the origin of lithium in LIB. This sets the stage for a new method ensuring the certification of Li in LIB.

Zinc isotope composition as a tool for tracing sources and fate of metal contaminants in rivers.

Zinc is a ubiquitous metal, acting both as an essential and a toxic element to organisms depending on its concentration and speciation in solution. Human activities mobilize and spread large quantities of zinc broadly in the environment. Discriminating the natural and various anthropogenic zinc sources in the environment and understanding zinc's fate at a catchment scale are key challenges in preserving the environment. This review presents the state of the art in zinc isotope studies applied to environmental purposes at a river-basin scale. Even though the study of zinc isotopes remains less developed than more "traditional" lead isotopes, we can assess their potential for being a relevant tracer of zinc in the environment. We present the principles of zinc isotope measurements from collecting samples to mass spectrometry analysis. To understand the fate of zinc released in the environment by anthropogenic activities, we summarize the main processes governing zinc distribution between the dissolved and solid phases, with a focus on the isotope fractionation effects that can modify the initial signature of the various zinc sources. The signatures of zinc isotopes are defined for the main natural sources of zinc in the environment: bulk silicate earth (BSE), zinc sulfide ore deposits, and coal signatures. Rivers draining natural environments define the "geological background for surface water", which is close to the BSE value. We present the main anthropogenic sources (metallurgical waste, effluents, fertilizers, etc.) with their respective isotope signatures and the main processes leading to these specific isotope characteristics. We discuss the impact of the various anthropogenic zinc emissions based on the available studies based on zinc isotopes. This literature review points out current knowledge gaps and proposes future directions to make zinc isotopes a relevant tracer of zinc (and associated trace metals) sources and fate at a catchment scale.