Enhancing ferrate(VI) oxidation process to remove blue 203 from wastewater utilizing MgO nanoparticles.

The aim of this study is to investigate the beneficial effect of utilizing MgO nanoparticles on the performance of ferrate(VI) oxidation process to remove blue-203 dye from wastewater. It was also made an attempt to assess the effects of pH, temperature, and MgO nanoparticle dosage on this oxidation process performance. Several sets of batch experiment were conducted to find out the effects of temperature ranging from 25 to 65 °C, pH ranging from 1.5 to 13, ferrate(VI) concentration ranging from 0.5 to 5.9 mg/L and MgO nanoparticles dosage ranging from 0.01 to 0.05 g in 150 mL solution on the removal efficiency. The results showed that adding MgO nanoparticles can improve the performance of ferrate(VI) oxidation removal method significantly, spec. at basic conditions. This synergistic effect can be attributed to the simultaneous adsorption of ferrate(VI) and dye molecules on the surface of nanoparticles. The results also revealed that the reaction between blue-203 dye and ferrate(VI) takes place rapidly at high mixing rate. It means that the required time to complete the removal process is controlled by mixing rate. It was finally concluded that adding MgO nanoparticles was an efficient means to enhance the performance of ferrate(VI) to oxidize blue-203 dye, esp. under basic conditions.

Comparison of Azithromycin Removal from Water Using UV Radiation, Fe (VI) Oxidation Process and ZnO Nanoparticles.

Antibiotics are resistant to biodegradation, and their removal by biological processes is difficult. The purpose of this study was to investigate the removal of azithromycin from water using ultraviolet radiation (UV), Fe (VI) oxidation process and ZnO nanoparticles. The effect of different parameters such as pH, temperature, hydraulic retention time (HRT), the concentration of Fe (VI) and ZnO nanoparticles and UV intensity on the removal of azithromycin from water was investigated. The optimal conditions for the removal of azithromycin were a pH of 2, a temperature of 25 °C, a HRT of 15 min, and a ratio of ZnO nanoparticles to the initial concentration of azithromycin (A/P) of 0.00009 which was fitted by Langmuir isotherm. In addition, the optimal conditions for the removal of azithromycin using UV radiation were a pH of 7, a temperature of 65 °C, a HRT of 60 min, and UV radiation power of 163 mW/cm2. For the Fe (VI) oxidation process, the optimal conditions were a pH of 2, a temperature of 50 °C and a HRT of 20 min. Also, the optimal ratio of Fe (VI) to the initial concentration of antibiotic was between 0.011 and 0.012. The results of this study showed that the Fe (VI) oxidation process, UV radiation, and ZnO nanoparticles were efficient methods for the removal of azithromycin from water.