Modulation of π-Electron Density in Ultrathin 2D Layers of Graphite Carbon Nitride for Efficient Photocatalytic Hydrogen Production.

The rational design and synthesis of novel semiconductor nano-/quantum materials have been ambitiously pursued in the field of photocatalysis as the technology is promising and critical for attaining future energy and environmental sustainability. Herein, the integrity of aromatic carbon into graphitic carbon nitride (CN) at the same molecular plane with a few 2D layers is achieved by using modulated precursors of CN, forming carbon regulated ultrathin CN (CUCN) with improved charge transfer kinetics and photocatalytic hydrogen production. The grafted graphite rings adjacent to carbon nitride frameworks induce a significant rearrangement and relocalization of the overall framework, and form conjugated sp2 hybridized interfaces and internal electric fields that drive the separation and directional transfer of photogenerated electrons from CN sheets towards intralayer graphite regions, where the photocatalytic hydrogen evolution reaction occurs extensively, yielding largely increased HER rate of 2231.8 µmol g-1 h-1 by 8.2 times relative to CN, as well as a remarkable apparent quantum yield of 2.93% under monochromatic light at 420 nm. The high physicochemical stability and low synthesis cost of CUCN make it a potential benchmark photocatalyst that can be readily modified via element doping, heterojunction introduction, defect engineering, and so on, to further enhance its HER performance.

Constructing mesoporous Zr-doped SiO2 onto efficient Z-scheme TiO2/g-C3N4 heterojunction for antibiotic degradation via adsorption-photocatalysis and mechanism insight.

Novel modified-TiO2/Zr-doped SiO2/g-C3N4 ternary composite is fabricated via an in-situ grow of porous Zr-SiO2 layer to TiO2/g-C3N4 heterojunction, which exhibits well adsorption-photocatalytic performance under simulated solar light irradiation. The nano-size mesoporous TiO2 are dispersed on the lamellar g-C3N4, and the Zr-SiO2 is in-situ fabricated onto the surface of g-C3N4 sheets. The adsorption occurs on the SiO2 layers, and doping Zr element to SiO2 enhances the adsorption of pollutants, while the photocatalytic reaction occurs on the valence band (VB) of TiO2 and conduction band (CB) of g-C3N4, which gives reactive oxygen species of ∙O2-, h+, and ∙OH for high efficient decomposition of antibiotics, i.e. berberine hydrochloride (98.11%), tetracycline (80.76%), and oxytetracycline (84.84%). The excellent adsorption capacity and Z-scheme photoinduced charge carrier migration behavior endowed the novel material with enhanced berberine hydrochloride (BH) removal in water, which approximately 2.5 and 3.8 folds than that of pure g-C3N4 and sole TiO2, respectively. Three degradation pathways are unraveled by LC-MS and theoretical calculations. Furthermore, the toxicity of intermediates was evaluated by the Toxicity Estimation Software Tool (T.E.S.T.), the result demonstrated a good application potential of M-TiO2/Zr-SiO2/g-C3N4 as an novel adsorptive photocatalyst.

Simultaneous determination of urinary parabens, bisphenol A, triclosan, and 8-hydroxy-2'-deoxyguanosine by liquid chromatography coupled with electrospray ionization tandem mass spectrometry.

A simple and fast method was developed for the simultaneous determination of five parabens, bisphenol A (BPA), triclosan (TCS), and 8-hydroxy-2'-deoxyguanosine (8-OHdG) in human urine using liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC-ESI-MS/MS). The solid-phase extraction (SPE) procedure, chromatographic conditions, and MS/MS parameters were optimized to achieve maximum sensitivity and accuracy for the analytes. The validation results showed that the correlation coefficients (R (2)) and recoveries ranged from 0.999 to 1 and 83.9 to 109.9 %, respectively, and the intra-day and inter-day precisions (relative standard deviation, RSD) were within the range of 1.3-8.5 % and 1.3-9.0 %, respectively. The limits of detection for the analytes ranged from 0.001 to 0.05 µg/L. The method was successfully employed to determine parabens, BPA, TCS, and 8-OHdG in urine samples from school students in Guangzhou, China. The results showed that methyl, ethyl, n-propyl parabens, BPA, TCS, and 8-OHdG were frequently detected in urine samples. n-Butyl and benzyl parabens were only detected in a part of the samples due to their low concentrations in urine.

Remediation of lead contaminated soil by biochar-supported nano-hydroxyapatite.

In this study, a high efficiency and low cost biochar-supported nano-hydroxyapatite (nHAP@BC) material was used in the remediation of lead (Pb)-contaminated soil. The remediation effect of nHAP@BC on Pb-contaminated soil was evaluated through batch experiments. The stability, bioaccessibility of Pb in the soil and the change in soil characteristics are discussed. Furthermore, the effects of the amendments on the growth of cabbage mustard seedlings and the accumulation of Pb were studied. The results showed that the immobilization rates of Pb in the soil were 71.9% and 56.8%, respectively, after a 28 day remediation using 8% nHAP and nHAP@BC materials, and the unit immobilization amount of nHAP@BC was 5.6 times that of nHAP, indicating that nHAP@BC can greatly reduce the cost of remediation of Pb in soil. After the nHAP@BC remediation, the residual fraction Pb increased by 61.4%, which greatly reduced the bioaccessibility of Pb in the soil. Moreover, nHAP@BC could effectively reduce the accumulation of Pb in plants by 31.4%. Overall, nHAP@BC can effectively remediate Pb-contaminated soil and accelerate the recovery of soil fertility.

In situ remediation and phytotoxicity assessment of lead-contaminated soil by biochar-supported nHAP.

In this study, a kind of biochar-supported nano-hydroxyapatite (nHAP@BC) material was used in in-situ remediation of lead-contaminated soil. Column experiments were performed to compare the mobility of nHAP@BC and Bare-nHAP. The immobilization, accumulation and toxic effects of Pb in the after-amended soil were assessed by the in vitro toxicity tests and pot experiments. The column experiments showed a significant improvement in the mobility of nHAP@BC. The immobilization rate of Pb in the soil was 74.8% after nHAP@BC remediation. Sequential extraction procedures revealed that the residual fraction of Pb increased by 66.6% after nHAP@BC remediation, which greatly reduced the bioavailability of Pb in the soil. In addition, pot experiments indicated that nHAP@BC could effectively reduce the upward translocation capacity of Pb in a soil-plant system. The concentration of Pb in the aerial part of the cabbage mustard was 0.1 mg/kg, which is lower than the tolerance limit (0.3 mg/kg). nHAP@BC can remediate Pb-contaminated soil effectively, which can restore soil quality for planting.

Synthesis of BiOI-TiO2 composite nanoparticles by microemulsion method and study on their photocatalytic activities.

This study was conducted to synthesize a series of nanosized BiOI-TiO2 catalysts to photodegrade Bisphenol A solution. The BiOI-TiO2 nanoparticles were synthesized in the reverse microemulsions, consisting of cyclohexane, Triton X-100, n-hexanol, and aqueous salt solutions. The synthesized particles were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) surface analyzer, Fourier transform-infrared spectroscopy (FT-IR), ultraviolet-visible light (UV-Vis) absorption spectra and transmission electron microscope (TEM). The photodegradation of Bisphenol A (BPA) in aqueous suspension under visible light irradiation was investigated to explore the feasibility of using the photocatalytic method to treat BPA wastewater. The effects of different molar ratios of BiOI to TiO2 on the photocatalytic activity were discussed. The experimental results revealed that the photocatalytic effect of the BiOI-TiO2 particles was superior to the commercial P25 TiO2. The BPA degradation could be approached by a pseudo-first-order rate expression. The observed reaction rate constant (kobs) was related to nanoparticles dosage and initial solution pH.

Anatase quantum dots decorated silica/carbon lamellas for removal of antipsychotic drugs via adsorption-photocatalysis and toxicity evaluation.

In this work, discrete quantum dots of crystallized anatase TiO2 are successfully anchored on carbon nanosheets containing amorphous SiO2 via templated self-assembly and pyrolysis routes. The novel hybrid photocatalyst of TiO2/C/SiO2 exhibits well coupled adsorption and visible light photocatalysis on chlorpromazine (CPZ) and the rate constants are 0.0223 and 0.0198 min-1, respectively. The direct photocatalytic degradation of CPZ under static conditions reaches 91.1% within 3 h while a removal rate of 31.4% for CPZ could be retained under dynamic flow conditions, and the improved performance could be attributed to enhanced adsorption via SiO2/C and highly exposure of TiO2 QDs surface. Based on the trapping experiments, ESR, LC-MS, and toxicity evaluation, O2- free radicals are identified as main reactive species for CPZ degradation along three possible pathways, with reduced toxicities for its intermediates. The cell viability tests of photocatalytic-degraded solutions and the catalyst exhibit negligible toxicities for both intermediates and the material, suggesting the novel composite of TiO2/C/SiO2 as an environmental friendly photocatalyst for pharmaceutical wastewater treatment.

Cysteine chemical modification for surface regulation of biochar and its application for polymetallic adsorption from aqueous solutions.

Biochar (BC) has been widely used to remove heavy metals from wastewater. However, due to the hydrophobicity of BC and the lack of its surface functional groups, the effect of metal ions adsorption onto BC is limited. In order to improve the adsorption efficiency, L-cysteine was used to modify biochar derived from pomelo peel (PP) to regulate surface structure. The characteristics of BC and cysteine/biochar composite (cys/BC) were analyzed by various characterization methods. Results showed that the hydrophilicity of biochar was enhanced, and the number of surface functional groups was increased, resulting to strong adsorption ability of Ag(I) (618.9 mg/g), Pb(II) (274.5 mg/g), and As(V) (34.7 mg/g) for cys/BC, which increased approximately by 15%, 35%, and 29% compared with that of BC, respectively. The adsorption process of Pb(II) onto cys/BC was fitted better by the Freundlich isotherm model and for Ag(I) and As(V) by the Langmuir isotherm model. Moreover, the adsorption kinetics followed pseudo-second-order equation and the adsorption process was controlled by the intraparticle diffusion for Ag(I), Pb(II), and As(V) adsorption onto cys/BC. In addition, the adsorption capacities of cys/BC for Ag(I), Pb(II), and As(V) decreased slightly after five adsorption/desorption cycles. Finally, the multiple adsorption mechanisms including functional groups, pore adsorption, surface complexation, and cations-π were analyzed. The paper demonstrated that the cys/BC composite could be reused as effective adsorbents for removing contaminants in the environment.

Iron-nitrogen co-doped carbon nanotubes decorated with Cu2O possess enhanced electronic properties for effective peroxymonosulfate activation.

Exploiting the full potential of copper-based nanoparticles in the activation of peroxymonopersulfate (PMS) is a great challenge due to their insufficient dispersity and electronic properties. We report here a novel iron­nitrogen co-doped carbon nanotube (FNC) modified with a Cu2O nanocomposite (Cu2O/FNC) that exhibits ultrahigh catalytic performance in the activation of PMS to degrade fluconazole (~95%). Catalytic performance evaluation illustrated that Cu2O/FNC also has wide pH applicability (3.0-11.0), long-term stability and excellent adaptability. In addition, luminescent bacteria toxicity tests confirm that Cu2O/FNC/PMS significantly reduced the acute biotoxicity of various recalcitrant pollutants (reduced by 45-83%). By identifying the reactive oxygen species (ROS) and catalytic performance for various pollutants, we propose that pollutants that interact weekly with activators are mostly destroyed by sulfate radicals and hydroxyl radicals, whilst both radical and non-radical routes were involved in the degradation of pollutants that were easily adsorbed. By modifying Cu2O with FNC, several crucial properties such as the specific surface area, surface defects, active sites and the charge transfer rate were significantly improved, leading to excellent catalytic performance for pollutant removal. Finally, a reasonable reaction mechanism is advanced for the fluconazole degradation pathway. This study not only develops a novel PMS oxidation system for fluconazole degradation, but also provides a new strategy to improve the reactivity and applicability of PMS activators by combining radical and non-radical activation pathways.

Comparison of adsorption behaviors and mechanisms of methylene blue, Cd2+, and phenanthrene by modified biochars derived from pomelo peel.

Although biochar (BC) has been widely used to adsorb pollutants in environment due to its natural and green characteristics, the structural defects of BC limit the ability to remove various environmental pollutants in aqueous solution. In this study, oxidized biochar (OBC) and sulfhydryl biochar (SBC) derived from pomelo peel (PP) were prepared through an oxidation and esterification reaction. BC and modified BC were used for the removal of methylene blue (MB), Cd2+, and phenanthrene (PHE) in aqueous solution. The adsorption behavior and efficiency toward different types of pollutants were studied by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), Raman, X-ray photoelectron spectroscopy (XPS), kinetics, and isotherm model fitting. The results showed that the change of pH had great effect on MB and Cd2+ adsorption, but not on PHE. SBC not only possessed the newly formed sp2-hybridized domains with easy access to aromatic pollutants but also had multiple functional groups (-COOH, -OH, -SH, -NH2) that provided adsorption sites for positively charged pollutants. SBC was more flexible and efficient in purifying pollutants compared to BC and OBC, with the saturated adsorption capacities of MB (209.16 mg/g), Cd2+ (786.19 mg/g), and PHE (521.58 mg/g). Moreover, the adsorption kinetic and isotherms fitting showed that the adsorption mechanisms were closely related to the structure of biochar and the properties of pollutants, including π-π interaction, surface charge, electrostatic interaction, surface functional groups, and Van der Waals force. In addition, the analysis of structure-function relationship demonstrated the enhanced hydrophilicity and the easy exposure of the binding sites on OBC and SBC. Hence, it was significantly effective to regulate microstructure and interfacial properties to promote its adsorption behaviors of biochar.

Adsorption-photocatalysis synergistic removal of contaminants under antibiotic and Cr(VI) coexistence environment using non-metal g-C3N4 based nanomaterial obtained by supramolecular self-assembly method.

Due to the rapid development of modern industry, the coexistence of antibiotics and inorganic heavy metals pollutants in wastewater has become a universal phenomenon. Therefore, developing efficient and eco-friendly photocatalyst for mixed pollutants degradation is significant. In this work, a well-designed phosphorus and sulfur co-doped g-C3N4 with feeble N vacancies catalyst (P/S-g-C3Nx) was fabricated by supramolecular self-assembly method, and was applied to remove berberine hydrochloride (BH) and Cr(VI) simultaneously with the synergy of adsorption-photocatalysis. A series of experiments was conducted to unveil the synergistic mechanism. The kinetic models indicated that the adsorption of P/S-g-C3Nx improved the BH removal process by accelerating the photo-degradation, because the adsorption rate > surface degradation rate > bulk degradation rate. Besides, the photo-degradation process improved the BH removal rate by regenerating the adsorption sites of P/S-g-C3Nx. Moreover, from the experiments in BH-Cr(VI) mixed solution system, the existence of BH also enhanced the surface adsorption of Cr(VI) in P/S-g-C3Nx sample, and the reduction rate of Cr(VI) was also promoted with the existence of BH. Overall, the results of this investigation suggest that the adsorption-photocatalysis synergy method is an efficient way to eliminate organic pollutant and Cr(VI) simultaneously.

Synergistic adsorption-photocatalytic degradation of different antibiotics in seawater by a porous g-C3N4/calcined-LDH and its application in synthetic mariculture wastewater.

In this work, a modified g-C3N4/MgZnAl-calcined layered double hydroxide composite (M-CN/cLDH) was successfully fabricated via a template method. The composite material is a hierarchical porous flower-like nanostructure self-assembled from stacked hybrid flakes. The 3D M-CN/cLDH architectures exhibit a synergistic effect of adsorption and photocatalysis for eliminating typical tetracycline antibiotics in seawater, i.e., oxytetracycline (OTC), tetracycline (TC), chlortetracycline (CTC), and doxycycline (DXC). The synergistic removal rate of OTC in seawater of M-CN/cLDH is 2.73 times higher than that of g-C3N4 after 120 min of visible-light illumination, and M-CN/cLDH also performs better adsorption-photocatalytic degradation on OTC in the continuous flow reaction process. The superior adsorption capability of the M-CN/cLDH is attributed to the open porous structures of cLDH, and its excellent photocatalytic degradation activity is ascribed to the closely bonded heterojunctions between g-C3N4 (CN) and cLDH double layers. The mass spectra reveals the degradation pathways of OTC, and its byproducts are less toxic after degradation for 120 min. The exploration of the M-CN/cLDH in synthetic mariculture wastewater suggested a huge potential for its practical application. With the assistance of magnesium ammonium phosphate (MAP) precipitation pretreatment, the material can effectively retain the high OTC removal rate in the synthetic mariculture wastewater circumstance.

Anionic polyacrylamide-assisted construction of thin 2D-2D WO3/g-C3N4 Step-scheme heterojunction for enhanced tetracycline degradation under visible light irradiation.

Thin 2D/2D WO3/g-C3N4 Step-scheme (S-scheme) heterojunction with carbon doping and bridge (C-W/N) was constructed with anionic polyacrylamide (APAM), in which APAM functioned as an assistant templet and a carbon source. APAM and WO3 were inserted into g-C3N4 nanosheet. The carbon, thin planar structure and WO3 with oxygen vacancies result in fast charge transfer, high quantum efficiency and strong driving force for photocatalytic reaction. Consequently, as-prepared C-W/N ternary composite photocatalyst exhibited significantly enhanced photocatalytic performance for tetracycline (TC) degradation under visible light compared to pure g-C3N4, WO3 and other binary composites. Moreover, the material showed high stability and reusability in cyclic TC degradation. The principal intermediate products over C-W/N photocatalyst were revealed by HPLC-MS analysis. Corresponding degradation pathway of TC was also presented in this work. According to the trapping experiments, analysis of electron spin resource (ESR) and band gap, possible charge transfer pathways of C-W/N are proposed and discussed in detail. Based on the results, carbon derived from APAM works not only as electron mediator but also as acceptor for photocatalytic degradation reaction. It is a promising way to further modulate heterojunction for varies applications.

Magnetic biochar for environmental remediation: A review.

The difficulty of separating the powdered biochar from the environmental medium may lead to secondary pollution and hinder the large-scale application of biochar as an adsorbent. An effective strategy to solve this bottleneck is to introduce transition metals and their oxides into the biochar matrix, creating easily separable magnetic biochar. Magnetic biochar is also effective for the removal of pollutants from aqueous solution. This review comprises a systematic analysis of 109 papers published in recent years (From 2011 to June 2019), and summarises the synthetic methods and raw materials required for magnetic biochar preparation. The basic physicochemical properties of magnetic biochar are expounded, together with findings from relevant studies, and the application of magnetic biochar as an adsorbent or catalyst in environmental remediation are summarised. Other applications of magnetic biochar are also discussed. Finally, some constructive suggestions are given for the future direction of magnetic biochar research.

Supramolecular self-assembly synthesis of noble-metal-free (C, Ce) co-doped g-C3N4 with porous structure for highly efficient photocatalytic degradation of organic pollutants.

Developing inexpensive and stable photocatalysts without noble metals, yet remarkably enhancing the photocatalytic activities, is highly needed. Here, a novel carbon and cerium co-doped porous g-C3N4 (C/Ce-CN) has been successfully prepared through thermal polymerization of the supramolecular aggregation. The morphologies, chemical structures, optical and photoelectrochemical properties of the synthesized photocatalysts were analyzed via a series of characterization measurements. Experimental results indicated that C/Ce-CN showed remarkably enhanced photocatalytic activity of TC and RhB degradation, which is about 2.6 and 2.4 times higher than that of pristine CN, and it also exhibited a good stability. Compared with bare CN, the enhanced performance of C/Ce-CN is mainly attributed to the stronger utilization rate of visible light, the rapider charge transfer rate, the longer lifetime of carriers and the larger surface specific area. The main intermediates in degradation process of antibiotics were tested by the HPLC-MS. Finally, the possible photocatalytic degradation pathways and mechanisms were proposed.

Efficient visible-light-driven hydrogen evolution and Cr(VI) reduction over porous P and Mo co-doped g-C3N4 with feeble N vacancies photocatalyst.

Developing highly efficient and inexpensive photocatalysts without noble metals, yet remarkably enhancing hydrogen production and Cr(VI) reduction activity, is highly needed. Here, the effective photocatalytic H2 evolution under visible light from an Eosin Y (EY)-sensitized (P, Mo)-g-C3Nx system by avoiding any noble metal co-catalyst is reported by the first time. Meanwhile, the optimized sample also displays the excellent performance in photocatalytic hexavalent chromium (Cr(VI)) reduction. In addition, this composite exhibits delectable stability for photocatalytic activities, no significant decay of activity is being observed after 16h reaction for photocatalytic H2 evolution (8h for Cr(VI) reduction). It is believed that this work will open up a new route for fabricating high-performance and inexpensive photocatalysts for hydrogen production and Cr(VI) reduction.

Urinary bisphenol analogues and triclosan in children from south China and implications for human exposure.

Bisphenols and triclosan (TCS) are widely used in consumer products. However, knowledge on human exposure to these anthropogenic chemicals has remained limited in China, especially for children. In this study, concentrations of seven bisphenols and TCS were determined in 283 urine samples collected from South China children aged between 3 and 11 years old. Bisphenol A (BPA), bisphenol S (BPS) and TCS were frequently detected in urine samples, with a detection rate of 93%, 89%, and 95%, respectively. Urinary concentrations of Σ7BPs (the sum concentrations of the seven bisphenols) ranged from 0.43 to 31.5 µg/L, with a median value of 0.91 µg/L, while TCS concentrations ranged from < limit of quantification to 21.9 µg/L (median: 0.21 µg/L). BPA was the predominant analogue (median: 0.35 µg/L), accounting for 49.8% of Σ7BPs. The urinary BPA concentrations in children from Guangzhou were significantly greater than those from Shenzhen. Correlation analysis suggested that multiple exposure sources to South China children likely existed for BPA, BPS, and TCS. Age, but not gender, was negatively associated with urinary residues of BPA and BPS (p < 0.05) and positively with TCS concentrations (p < 0.05). The estimated daily intake of Σ7BPs (23.9 ng/kg bw/day) or TCS (5.63 ng/kg bw/day) was below the tolerant reference dose of BPA, indicating no considerable health hazard to South China children.

Urinary metabolites of organophosphate esters in children in South China: Concentrations, profiles and estimated daily intake.

Organophosphate esters (OPEs) are widely used in household products as flame retardants or plasticizers and have become ubiquitous pollutants in environmental media. However, little is known about OPE metabolites in humans, especially in children. In this study, eight OPE metabolites were measured in 411 urine samples collected from 6 to 14-year-old children in South China. Bis(2-chloroethyl) phosphate (BCEP), bis(1-chloro-2-propyl) phosphate (BCIPP) and diphenyl phosphate (DPHP) were the dominant OPE metabolites, and their median concentrations were 1.04, 0.15 and 0.28 µg/L, respectively. The levels of urinary OPE metabolites in the present study were much lower than those in participants from other countries, with the exception of BCEP, suggesting widespread exposure to tris(2-chlorethyl) phosphate (TCEP, the parent chemical of BCEP) in South China. No significant difference in the concentrations of any of the OPE metabolites was observed between males and females (p > .05). Significant negative correlations were observed between age and BCEP, BCIPP, bis(1,3-dichloro-2-propyl) phosphate (BDCIPP), di-o-cresyl phosphate (DoCP) and di-p-cresyl phosphate (DpCP) (DCP), or DPHP (p < .05). Pearson correlation coefficients between urinary OPE metabolites indicated multiple sources and OPE exposure pathways in children. The estimated daily intake suggested that children in South China have a relatively high exposure level to TCEP. To the best of our knowledge, this is the first study to report the urinary levels of OPE metabolites in Chinese children.

Stabilisation of nanoscale zero-valent iron with biochar for enhanced transport and in-situ remediation of hexavalent chromium in soil.

In this study, a biochar-supported nanoscale zero-valent iron (nZVI@BC) material was used for in situ remediation of hexavalent chromium-contaminated soil. Sedimentation tests and column experiments were used to compare the stability and mobility of nZVI@BC and bare-nZVI. The immobilisation efficiency of chromium, toxic effect of chromium and the content of iron were assessed through leaching tests and pot experiments. Sedimentation tests and transport experiments indicated that nZVI@BC with nZVI to BC mass ratio of 1:1 exhibited better stability and mobility than that of bare-nZVI. The immobilisation efficiency of Cr(VI) and Crtotal was 100% and 92.9%, respectively, when the soil was treated with 8 g/kg of nZVI@BC for 15 days. Moreover, such remediation effectively reduced the leachability of Fe caused by bare-nZVI. In addition, pot experiments showed that such remediation reduced the phytotoxicity of Cr and the leachable Fe and was favourable for plant growth.

Remediation of hexavalent chromium contaminated soil by biochar-supported zero-valent iron nanoparticles.

In this study, a kind of high-efficiency and low-cost biochar-supported zero-valent iron nanoparticles (nZVI@BC) was synthesised and used in the remediation of Cr(VI)-contaminated soil. The remediation tests indicated that the immobilisation efficiency of Cr(VI) and Crtotal was 100% and 91.94%, respectively, by 8g nZVI@BC per kg soil for 15 d of remediation. Further investigations showed that exchangeable Cr was almost completely converted to Fe-Mn oxides and organic matter. Moreover, nZVI@BC could effectively improve soil fertility and reduce the leachability of Fe caused by nZVI. At the same time, the cabbage mustard growth experiments indicated that the phytotoxicity of Cr(VI) and Fe in the seedlings was effectively decreased by nZVI@BC treatment, and that the cabbage mustard growth was enhanced.