RESUMO
The oil and gas industry plays a vital role in the global economy. The production process has several critical conditions and can expose metals to corrosion. Surfactants like the quaternary ammonium salt Benzyldimethyldodecylammonium Bromide (BDAC) are currently used to prevent corrosions; classical methods for determining these surfactants have problems in saline samples and usually present high costs. In this context, spectroscopic techniques become an excellent alternative for quaternary ammonium salts detection. Here, a SERS (surface-enhanced Raman scattering) sensor based on gold nanoparticles (AuNPs) synthesized through chemical reduction was used as an alternative method for BDAC detection. We detected BDAC at low concentrations in water solutions: at 5 to 30 ppm (1.47 × 10-5 mol L-1 to 8.82 × 10-5 mol L-1); and had the vibration attempt attribute analyzed. A new study of quaternary ammonium compounds using AuNPs and SERS with a different, easy, and repeatable approach to spectra acquisition is presented and shows to be a promising method applied in quaternary ammonium salt compounds detection for the oil and gas industry.
RESUMO
BACKGROUND: To assess whether glass-ceramic shade, thickness and translucency affect degree of conversion (DC) and Knoop microhardness (KHN) of resin cements photoactivated using light-emitting diode (LED) or quartz-tungsten-halogen (QTH) units. MATERIAL AND METHODS: Glass-ceramic blocks were cut (2, 3 and 4mm) and sintered. For DC FT Raman spectroscopy (n=3), film specimens of cements (RelyX ARC, U200, Veneer, C&B) were obtained. For KHN test (n=3), cements were inserted in cylindrical matrix and covered by polyester strip. Specimens were photoactivated (30s) using LED or QTH according to each group: direct photoactivation (DP), interposing ceramic specimens or no photoactivation (NP). Data were analysed by ANOVA and Tukey's test, Kruskal-Wallis and Dunn's tests (p<0.05). RESULTS: Ceramic features had significant effect on DC of RelyX ARC, U200 and Veneer (p<0.0017). Light source had no effect (p=0.9512). C&B and Veneer had higher DC, followed by dual cements. NP dual cements showed the lowest DC. For KHN, ceramic shade (p=0.1717) and light source (p=0.1421) were not significant, but ceramic translucency, thickness and resin cement were significant (p=0.0001). KHN was higher for U200 followed by ARC, and lowest for Veneer. CONCLUSIONS: DC was affected by ceramic shade, translucency and thickness. KHN was dependent on ceramic translucency and thickness. Higher DC and KHN were achieved for dual-cured cements photoactivated through 2mm-thick low translucent or 3mm-thick high translucent glass-ceramic. Key words:Cementation, composite resin cements, dental curing lights, glass ceramics.