Sapphire advanced mitigation process: wet etch to expose sub-surface damage and increase laser damage resistance and mechanical strength.

A novel, to the best of our knowledge, method of wet chemical etching of sapphire workpieces (such as optics, wafers, windows, and cones), called the sapphire advanced mitigation process (or sapphire AMP), has been developed that exposes sub-surface mechanical damage created during the optical fabrication process and significantly enhances the surface laser damage resistance ($ \gt {2{\times}}$>2×) and mechanical strength (up to $\sim{2.6{\times}}$∼2.6×). Sapphire AMP involves first treating the workpiece with a mixture of sulfuric and phosphoric acid $([{\rm H_{2}{\rm SO_{4}}}]:[{\rm H_{3}{\rm PO_{4}}}]=1:3)$([H2SO4]:[H3PO4]=1:3) at 220°C, followed with phosphoric acid at 160°C, then with sodium hydroxide base (NaOH) and surfactant at 40°C, and finally with a high-pressure deionized water spray rinse. Sapphire AMP has been demonstrated on both A- and C-plane sapphire workpieces. The mechanism of this etch process involves the reaction of the sapphire $({\rm Al_{2}}{\rm O_{3}})$(Al2O3) surface with sulfuric acid $({\rm H_{2}}{\rm SO_{4}})$(H2SO4) forming aluminum sulfate $[{{\rm Al}_2}{({{\rm SO}_4})_3}]$[Al2(SO4)3], which has low solubility. The high phosphoric acid content in the first and second steps of sapphire AMP results in the efficient conversion of ${{\rm Al}_2}{({{\rm SO}_4})_3}$Al2(SO4)3 to aluminum phosphate $({\rm AlPO_{4}})$(AlPO4), which is very soluble, greatly reducing reaction product redeposition on the workpiece surface. Sapphire AMP is shown to expose sub-surface mechanical damage on the sapphire surface created during the grinding and polishing processes, whose etched morphology has either isotropic or anisotropic evolution depending on the nature of the initial surface damage. Sapphire AMP was also designed to remove the key known surface, laser absorbing precursors (namely, foreign chemical impurities, the fracture surface layer of preexisting sub-surface damage, and reaction product or foreign species redeposition or precipitation). Static and sliding indention induced surface microfractures on sapphire are shown after sapphire AMP to have a significant decrease in the fast photoluminescence intensity (a known metric for measuring the degree of laser damaging absorbing precursors). In addition, the onset of laser damage (at 351 nm 3 ns) on sapphire AMP treated workpieces was shown to increase in fluence from $\sim{4}$∼4 to $ \gt {9}.{5}\;{{\rm J/cm}^2}$>9.5J/cm2. Finally, biaxial ball-on-ring mechanical tests on sapphire disks showed an increase in the failure stress from 340 MPa (with pre-existing 28 µm flaws) to $\sim{900}\;{\rm MPa}$∼900MPa after sapphire AMP, which is attributed to the blunting of the surface microfractures.

Using behavior change to reduce child lead exposure in resource-poor settings: a formative study.

The objective of this formative research was to explore the acceptability and feasibility of changing housekeeping behaviors as a low-cost approach that may reduce childhood lead exposure in Johannesburg, South Africa. Using the Trials of Improved Practices (TIPs) methodology, modified housekeeping behaviors were negotiated with participants who chose the behaviors they wanted to try and then performed them in their homes over 4 weeks. Researchers interviewed them at the end of the month to understand their experience of trying out the behaviors. The modified behaviors offered to each participant were as follows: cleaning window sills with detergent and water, cleaning window sills more frequently, mopping floors with two buckets (one with soapy water for washing and one with clean water for rinsing), mopping floors more frequently, dusting surfaces with detergent and water and dusting surfaces more frequently. Participants found cleaning window sills with soap and water and cleaning them more often the most acceptable and feasible of behavior modifications. Environmental samples showed a significant reduction in lead dust on window sills. These findings can assist in the development of acceptable and feasible medium-term interventions to reduce childhood lead exposure in resource-poor settings until more robust health policies are implemented.

Dynamics of transient absorption in bulk DKDP crystals following laser energy deposition.

The transient changes in the optical properties of bulk DKDP material arising from its exposure to high temperatures and pressures associated with localized laser energy deposition are investigated. Two methods for initiation of laser-induced breakdown are used, intrinsic, involving relatively large energy deposition brought about by focusing of the laser beam to high intensities, and extrinsic, arising from more localized deposition due to the presence of pre-existing absorbing damage initiating defects. Each method leads to a very different volume of material being affected, which provides for different material thermal relaxation times to help better understand the processes involved.

Dynamics of material modifications following laser-breakdown in bulk fused silica.

We report on the material response during the cooling phase in bulk fused silica following localized energy deposition via laser-induced breakdown.We use a time-resolved microscope system to acquire images of the region of energy deposition at delay times covering the entire timeline of events. In addition, this system is configured to perform pump-and-probe damage testing measurements to investigate the evolution of the transient absorption of the modified material. The main features of a damage site are established at approximately 30 ns after the pump pulse, i.e. cracks reach their final size within this time frame. The results reveal that the cracks and melted core exhibit a transient absorption up until about 300 ns and 200 micros delay times, respectively, and suggest that the melted region returns to solid phase at approximately 70 ms delay.

Fracture-induced subbandgap absorption as a precursor to optical damage on fused silica surfaces.

The optical damage threshold of indentation-induced flaws on fused silica surfaces was explored. Mechanical flaws were characterized by laser damage testing, as well as by optical, secondary electron, and photoluminescence microscopy. Localized polishing, chemical leaching, and the control of indentation morphology were used to isolate the structural features that limit optical damage. A thin defect layer on fracture surfaces, including those smaller than the wavelength of visible light, was found to be the dominant source of laser damage initiation during illumination with 355 nm, 3 ns laser pulses. Little evidence was found that either displaced or densified material or fluence intensification plays a significant role in optical damage at fluences >35 J/cm(2). Elimination of the defect layer was shown to increase the overall damage performance of fused silica optics.

Blockade of RAGE suppresses periodontitis-associated bone loss in diabetic mice.

Diabetes is associated with increased prevalence, severity, and progression of periodontal disease. To test the hypothesis that activation of RAGE (Receptor for Advanced Glycation End products) contributes to the pathogenesis of diabetes-associated periodontitis, we treated diabetic mice, infected with the human periodontal pathogen Porphyromonas gingivalis, with soluble RAGE (sRAGE). sRAGE is the extracellular domain of the receptor, which binds ligand and blocks interaction with, and activation of, cell-surface RAGE. Blockade of RAGE diminished alveolar bone loss in a dose-dependent manner. Moreover, we noted decreased generation of the proinflammatory cytokines TNF-alpha and IL-6 in gingival tissue, as well as decreased levels of matrix metalloproteinases. Gingival AGEs were also reduced in mice treated with sRAGE, paralleling the observed suppression in alveolar bone loss. These findings link RAGE and exaggerated inflammatory responses to the pathogenesis of destructive periodontal disease in diabetes.

Densification of fused silica due to shock waves and its implications for 351 nm laser induced damage.

High-power 351 nm (3 ) laser pulses can produce damaged areas in high quality fused silica optics. Recent experiments have shown the presence of a densified layer at the bottom of damage initiation craters. We have studied the propagation of shock waves through fused silica using large-scale atomistic simulations since such shocks are expected to accompany laser energy deposition. These simulations show that the shocks induce structural transformations in the material that persist long after the shock has dissipated. Values of densification and thickness of densified layer agree with experimental observations. Moreover, our simulations give an atomistic description of the structural changes in the material due to shock waves and their relation to Raman spectra measurements.

Influence of pulse duration on ultrashort laser pulse ablation of biological tissues.

Ablation characteristics of ultrashort laser pulses were investigated for pulse durations in the range of 130 fs-10 ps. Tissue samples used in the study were dental hard tissue (dentin) and water. We observed differences in ablation crater morphology for craters generated with pulse durations in the 130 fs-1 ps and the 5 ps-10 ps range. For the water experiment, the surface ablation and subsequent propagation of stress waves were monitored using Mach-Zehnder interferometry. For 130 fs-1 ps, energy is deposited on the surface while for longer pulses the beam penetrates into the sample. Both studies indicate that a transition occurs between 1 and 5 ps.

Screening of substance abuse in public welfare and child protective service clients: a comparative study of rapid assessment instruments vs. the SASSI.

In light of new welfare reforms, it is essential that public welfare workers move individuals from welfare to work in an expedient fashion. Client alcohol and/or drug use/abuse is one barrier that may inhibit this process. The following study (N = 93) administered both the Hudson Index of Alcohol Involvement, the Hudson Index of Drug Involvement (rapid assessment instruments) and the Miller Substance Abuse Subtly Screening Inventory (SASSI) to public welfare and Child Protection system clients. Results indicated that the two rapid assessment measures strongly correlated with the advanced, commonly used SASSI measure. It is suggested that public welfare workers should institute these rapid assessment instruments at intake to screen clients for alcohol and drug use/abuse. When indicated, the client could then be referred to the appropriate agency for further assessment and treatment, to better prepare them for employment as mandated by new welfare reforms. The rapid assessment instruments were found to be shorter than the SASSI, easily administered, and able to detect alcohol and/or drug use/abuse effectively and efficiently in these populations.

Radiation produced by femtosecond laser-plasma interaction during dielectric breakdown.

Optical breakdown by femtosecond and nanosecond laser pulses in transparent dielectrics produces an ionized region of dense plasma confined within the bulk of the material. This ionized region is responsible for broadband radiation that accompanies the breakdown process. Spectroscopic measurements of the accompanying light have been used to show that, depending on the laser parameters, the spectra may originate from plasma-induced second-harmonic generation, supercontinuum generation, or thermal emission by the plasma. By monitoring the emission from the ionized region, one can ascertain the predominant breakdown mechanism and the morphology of the damage region.

Minimal dispersion refractive index profiles.

The analogy between optics and quantum mechanics is exploited by considering a 2-D quantum system whose Schroedinger equation is closely related to the wave equation for light propagation in an optical fiber. From this viewpoint, Marcatili's condition for minimal-dispersion-refractive-index profiles, and the Olshansky- Keck formula for rms pulse spreading in an alpha-profile fiber may be derived without recourse to the WKB approximation. Besides affording physical insight into these results, the present approach points out a possible limitation in their application to real fibers.

Exposure of adolescent girls to cigar images in women's magazines, 1992-1998.

OBJECTIVES: This study assessed the exposure of adolescent girls to cigar images in women's magazines from 1992 to 1998. METHODS: Data were obtained from the 5 women's magazines with the highest readership of adolescent girls. RESULTS: We found a significant upward trend in cigar images portrayed in women's magazines and a significant increase in the portrayal of women cigar smokers over the period observed. Cigar images were less likely than cigarette images to promote tobacco or nontobacco products. Among advertisements, nearly all those that featured cigars promoted nontobacco products; advertisements featuring cigarettes overwhelmingly promoted tobacco products. CONCLUSIONS: Between 1992 and 1998, adolescent readers of women's magazines were increasingly exposed to images of cigars.

Spatial coherence of laboratory soft-x-ray lasers.

Employing a time-dependent model with counterpropagating beams and saturable gain, we calculate the degree of coherence for a range of x-ray lasers. From these results we infer a scaling law that can be used to estimate the degree of coherence of a general class of x-ray lasers.

High-power narrow-band pulses with wavelengths tunable about 1.053 µm from a synchronously pumped optical parametric oscillator.

We have constructed an optical parametric oscillator to generate 75-ps near-transform-limited pulses with wavelengths tunable about 1.053 µm for use in pump-probe studies of self-focusing. The singly resonant oscillator uses a Brewster-cut LiB(3)O(5) crystal that is oriented for type-II phase matching and synchronously pumped by the amplified and frequency-tripled pulse trains from a mode-locked and Q-switched Nd:YLP laser. An intracavity Pockels cell is used to switch out single 0.5-MW pulses at rates of 1 to 10 Hz. The design, construction, and performance of the oscillator are discussed. Measured performance is compared with design predictions and with detailed numerical simulations.

Computation of mode properties in optical fiber waveguides by a propagating beam method.

Propagating beam solutions for optical waveguides can be made to generate such mode-related properties as propagation constants, relative mode powers, and group delays with high precision and considerable flexibility. These quantities are needed in the analysis of optical fiber dispersion. The technique requires the generation of correlation functions from the numerical solutions of a wave equation. These correlation functions are in turn Fourier-transformed with respect to axial distance z. The resulting spectra display sharp resonances corresponding to mode groups, and the positions and heights of these resonances determine the previously mentioned mode properties. The spectral analysis is made highly accurate by the use of line-shape fitting techniques. With this method, mode group delays can be determined to a precision of +/-0.12 psec/km using a computation covering a 5-cm propagation path.

Computation of mode eigenfunctions in graded-index optical fibers by the propagating beam method.

The propagating beam method utilizes discrete Fourier transforms for generating configuration-space solutions to optical waveguide problems without reference to modes. The propagating beam method can also give a complete description of the field in terms of modes by a Fourier analysis with respect to axial distance of the computed fields. Earlier work dealt with the accurate determination of mode propagation constants and group delays. In this paper the method is extended to the computation of mode eigenfunctions. The method is efficient, allowing generation of a large number of eigenfunctions from a single propagation run. Computations for parabolic-index profiles show excellent agreement between analytic and numerically generated eigenfunctions.

Mode properties and dispersion for two optical fiber-index profiles by the propagating beam method.

The propagating beam method generates solutions for the electric field in a graded-index optical fiber that emphasize beam characteristics rather than modal properties. Through Fourier analysis with respect to axial distance z, these solutions can be made to yield such mode properties as the propagation constants beta(n), the mode group delays partial differentialbeta(n)/ partial differentialomega, and the mode eigenfunctions. The propagating beam method has been applied to a detailed study of two index profiles with finite thickness cladding: an axisymmetric power-law (alpha = 1.85) profile both without and with an on-axis dip. In nine successive computer runs, eighty-five and eighty-four bound or guided modes were excited and characterized for the two respective profiles. The mode group delays near cutoff for both profiles show large deviation from those derived with the WKB method. In addition, sets of almost degenerate modes near cutoff show large differences in group delay. Modes with low azimuthal quantum number are strongly perturbed by the central dip. It is found that rms pulse dispersion is quite sensitive to the inclusion or exclusion of modes near cutoff, but that frequency response bandwidth is not. This leads to the conclusion that fiber bandwidth cannot be accurately inferred from rms pulse dispersion and may explain why broadband multimode fibers exist dispite strong perturbation of the modes near cutoff.

Spectral approach to optical resonator theory.

A new computational method for unloaded optical resonators is developed based on the discrete Fourier analysis of information generated by repeated iterations of the optical field corresponding to transits between reflectors. The method is a straightforward extension of the propagating beam method developed earlier for optical fibers for extracting modal properties from numerical solutions to the paraxial scalar wave equation. The method requires computation of a field correlation function, whose Fourier transform reveals the eigenmodes as resonant peaks. Analysis of the location and breadth of these peaks determines the resonator eigenvalues. When the eigenvalues are known, additional discrete Fourier transforms of the field are used to generate the mode eigenfunctions. This new method makes possible the unambiguous identification and accurate characterization of the entire spectrum of transverse resonator modes.

Mode properties of optical fibers with lossy components by the propagating beam method.

The theory of optical fibers has been concerned mainly with propagation in lossless waveguides. Although real fibers are composed of core materials with extremely small absorption coefficients, they may have claddings and jackets with substantially higher losses. These components can in turn selectively attenuate certain higher-order guided modes. The propagating beam method utilizes configuration space solutions to a scalar wave equation to generate the mode propagation constants and eigenfunctions for a general class of weakly guiding fibers. This method has now been generalized to treat fibers with absorbing components such as claddings and jackets. It is now possible to compute with this generalized method both the mode attenuation coefficients and mode eigenfunctions for such fibers. Results are given for planar and circularly symmetric waveguides with lossy claddings and jackets.

Calculation of dispersion in graded-index multimode fibers by a propagating-beam method.

Methods are developed for extracting from a numerical propagating-beam solution of a scalar wave equation the information necessary to compute the impulse-response function and the pulse dispersion for a multimode graded-index fiber. It is shown that the scalar Helmholtz equation and the parabolic wave equation have the same set of eigenfunctions in common and that the eigenvalues for the two equations are simply related. Thus one can work exclusively with the simpler parabolic equation. Both the mode eigenvalues (propagation constants) and mode weights, which are necessary for determining the impulse response, can be obtained with high accuracy from a numerical Fourier transform of the complex field-correlation function by the use of digital-filtering techniques. It is shown how a solution obtained in the absence of profile dispersion can be simply corrected for the presence of profile dispersion. In an illustrative example a gradedindex fiber with a central dip in its profile is considered.