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As a promising alternative to the mainstream CoFeB/MgO system with interfacial perpendicular magnetic anisotropy (PMA), L10-FePd and its synthetic antiferromagnet (SAF) structure with large crystalline PMA can support spintronic devices with sufficient thermal stability at sub-5 nm sizes. However, the compatibility requirement of preparing L10-FePd thin films on Si/SiO2 wafers is still unmet. In this paper, we prepare high-quality L10-FePd and its SAF on Si/SiO2 wafers by coating the amorphous SiO2 surface with an MgO(001) seed layer. The prepared L10-FePd single layer and SAF stack are highly (001)-textured, showing strong PMA, low damping, and sizeable interlayer exchange coupling, respectively. Systematic characterizations, including advanced X-ray diffraction measurement and atomic resolution-scanning transmission electron microscopy, are conducted to explain the outstanding performance of L10-FePd layers. A fully-epitaxial growth that starts from MgO seed layer, induces the (001) texture of L10-FePd, and extends through the SAF spacer is observed. This study makes the vision of scalable spintronics more practical.
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Field-effect experiments on cuprates using ionic liquids have enabled the exploration of their rich phase diagrams [Leng X, et al. (2011) Phys Rev Lett 107(2):027001]. Conventional understanding of the electrostatic doping is in terms of modifications of the charge density to screen the electric field generated at the double layer. However, it has been recently reported that the suppression of the metal to insulator transition induced in VO2 by ionic liquid gating is due to oxygen vacancy formation rather than to electrostatic doping [Jeong J, et al. (2013) Science 339(6126):1402-1405]. These results underscore the debate on the true nature, electrostatic vs. electrochemical, of the doping of cuprates with ionic liquids. Here, we address the doping mechanism of the high-temperature superconductor YBa2Cu3O7-X (YBCO) by simultaneous ionic liquid gating and X-ray absorption experiments. Pronounced spectral changes are observed at the Cu K-edge concomitant with the superconductor-to-insulator transition, evidencing modification of the Cu coordination resulting from the deoxygenation of the CuO chains, as confirmed by first-principles density functional theory (DFT) simulations. Beyond providing evidence of the importance of chemical doping in electric double-layer (EDL) gating experiments with superconducting cuprates, our work shows that interfacing correlated oxides with ionic liquids enables a delicate control of oxygen content, paving the way to novel electrochemical concepts in future oxide electronics.
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We recently demonstrated that the superconductor-to-insulator transition induced by ionic liquid gating of the high temperature superconductor YBa2Cu3O7 (YBCO) is accompanied by a deoxygenation of the sample [A. M. Perez-Munoz et al., Proc. Natl. Acad. Sci. U. S. A. 114, 215 (2017)]. Density functional theory calculations helped establish that the pronounced changes in the spectral features of the Cu K-edge absorption spectra measured in situ during the gating experiment arise from a decrease of the Cu coordination within the CuO chains. In this work, we provide a detailed analysis of the electronic structure origin of the changes in the spectra resulting from three different types of doping: (i) the formation of oxygen vacancies within the CuO chains, (ii) the formation of oxygen vacancies within the CuO2 planes, and (iii) the electrostatic doping. For each case, three stoichiometries are studied and compared to the stoichiometric YBa2Cu3O7, i.e., YBa2Cu3O6.75, YBa2Cu3O6.50, and YBa2Cu3O6.25. Computed vacancy formation energies further support the chain-vacancy mechanism. In the case of doping by vacancies within the chains, we study the effect of oxygen ordering on the spectral features and we clarify the connection between the polarization of the x-rays and this doping mechanism. Finally, the inclusion of the Hubbard U correction on the computed spectra for antiferromagnetic YBa2Cu3O6.25 is discussed.
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In this work we study the interfaces between the Mott insulator LaMnO3 (LMO) and the band insulator SrTiO3 (STO) in epitaxially grown superlattices with different thickness ratios and different transport and magnetic behaviors. Using atomic resolution electron energy-loss spectral imaging, we analyze simultaneously the structural and chemical properties of these interfaces. We find changes in the oxygen octahedral tilts within the LaMnO3 layers when the thickness ratio between the manganite and the titanate layers is varied. Superlattices with thick LMO and ultrathin STO layers present unexpected octahedral tilts in the STO, along with a small amount of oxygen vacancies. On the other hand, thick STO layers exhibit undistorted octahedra while the LMO layers present reduced O octahedral distortions near the interfaces. These findings are discussed in view of the transport and magnetic differences found in previous studies.
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Despite their highly anisotropic complex-oxidic nature, certain delafossite compounds (e.g., PdCoO2, PtCoO2) are the most conductive oxides known, for reasons that remain poorly understood. Their room-temperature conductivity can exceed that of Au, while their low-temperature electronic mean-free-paths reach an astonishing 20 µm. It is widely accepted that these materials must be ultrapure to achieve this, although the methods for their growth (which produce only small crystals) are not typically capable of such. Here, we report a different approach to PdCoO2 crystal growth, using chemical vapor transport methods to achieve order-of-magnitude gains in size, the highest structural qualities yet reported, and record residual resistivity ratios ( > 440). Nevertheless, detailed mass spectrometry measurements on these materials reveal that they are not ultrapure in a general sense, typically harboring 100s-of-parts-per-million impurity levels. Through quantitative crystal-chemical analyses, we resolve this apparent dichotomy, showing that the vast majority of impurities are forced to reside in the Co-O octahedral layers, leaving the conductive Pd sheets highly pure (â¼1 ppm impurity concentrations). These purities are shown to be in quantitative agreement with measured residual resistivities. We thus conclude that a sublattice purification mechanism is essential to the ultrahigh low-temperature conductivity and mean-free-path of metallic delafossites.
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We successfully tuned an underdoped ultrathin YBa2Cu3O(7-x) film into the overdoped regime by means of electrostatic doping using an ionic liquid as a dielectric material. This process proved to be reversible. Transport measurements showed a series of anomalous features compared to chemically doped bulk samples and a different two-step doping mechanism for electrostatic doping was revealed. The normal resistance increased with carrier concentration on the overdoped side and the high temperature (180 K) Hall number peaked at a doping level of pâ¼0.15. These anomalous behaviors suggest that there is an electronic phase transition in the Fermi surface around the optimal doping level.
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The electrical transport properties of ultrathin YBa2Cu3O(7-x) films have been modified using an electric double layer transistor configuration employing an ionic liquid. A clear evolution from superconductor to insulator was observed in nominally 7 unit-cell-thick films. Using a finite size scaling analysis, curves of resistance versus temperature, R(T), over the temperature range from 6 to 22 K were found to collapse onto a single scaling function, which suggests the presence of a quantum critical point. However, the scaling fails at the lowest temperatures indicating the possible presence of an additional phase between the superconducting and insulating regimes.
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Understanding the impact of strain on organic semiconductors is important for the development of electronic devices and sensors that are subject to environmental changes and mechanical stimuli; it is also important for understanding the fundamental mechanisms of charge trapping. Following our previous study on the strain effects in rubrene, we present here only the second example of the strain-work function relationship in an organic semiconductor; in this case, the benchmark material tetracene. Thin, platelike single crystals of tetracene with large (001) facets were laminated onto silicon and rubber substrates having significantly different coefficients of thermal expansion; mechanical strain in tetracene was subsequently induced by varying the temperature of the assembly. Tensile and compressive strains parallel to the (001) major facet were measured by grazing incidence X-ray diffraction, and the corresponding shifts in the electronic work functions were recorded via scanning Kelvin probe microscopy (SKPM). The work function of the tetracene (001) crystal surface directly correlated with the net mechanical strain and increased by â¼100 meV for in-plane tensile strains of 0.1% and decreased by approximately the same amount for in-plane compressive strains of -0.1%. This work provides evidence of the general and important impact of strain on the electrical properties of van der Waals bonded crystalline organic semiconductors and thereby supports the hypothesis that heterogeneous strains, for example in thin films, can be a major source of static electronic disorder.
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Reducing the operation temperature of solid oxide fuel cells is a major challenge towards their widespread use for power generation. This has triggered an intense materials research effort involving the search for novel electrolytes with higher ionic conductivity near room temperature. Two main directions are being currently followed: the use of doping strategies for the synthesis of new bulk materials and the implementation of nanotechnology routes for the fabrication of artificial nanostructures with improved properties. In this paper, we review our recent work on solid oxide fuel cell electrolyte materials in these two directions, with special emphasis on the importance of disorder and reduced dimensionality in determining ion conductivity. Substitution of Ti for Zr in the A(2)Zr(2-) (y)Ti(y)O(7) (A = Y, Dy, and Gd) series, directly related to yttria stabilized zirconia (a common fuel cell electrolyte), allows controlling ion mobility over wide ranges. In the second scenario we describe the strong enhancement of the conductivity occurring at the interfaces of superlattices made by alternating strontium titanate and yttria stabilized zirconia ultrathin films. We conclude that cooperative effects in oxygen dynamics play a primary role in determining ion mobility of bulk and artificially nanolayered materials and should be considered in the design of new electrolytes with enhanced conductivity.
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The manufacture of oral dosage form may induce changes in the physical form of an active pharmaceutical ingredient. One such example includes formation of hydrate during granulation followed by the reverse transition to the anhydrous form during drying. We used naproxen sodium dihydrate (DH) as the model compound and studied its dehydration at elevated temperature under different processing conditions, (i) in ambient air, (ii) in flow of inert gas (iii) under low pressure environment, and (iv) under 'high' pressure in closed environments. In situ variable temperature X-ray diffraction was used to monitor kinetics of phase transformation under these processing conditions. The DH dehydration was fastest under the flow of inert gas and slowest in closed environment. Polyvinyl pyrrolidone (PVP) and microcrystalline cellulose (MCC), commonly used hygroscopic solids, were used as the model excipients to monitor influence of excipients in modulating DH dehydration behavior under different processing conditions. Both the excipients altered the kinetics as well as the extent of DH dehydration, with PVP delaying and MCC facilitating the transformation under all processing conditions studied. The results indicate that the physical form of API, such as hydrate or anhydrous in the present case, in the formulation may be modulated by rational excipient selection.
Assuntos
Anti-Inflamatórios não Esteroides/química , Celulose/química , Excipientes/química , Naproxeno/química , Povidona/química , Química Farmacêutica , Dessecação , CinéticaRESUMO
Development of novel magnetic materials is of interest for fundamental studies and applications such as spintronics, permanent magnetics, and sensors. We report on the first experimental realization of single element ferromagnetism, since Fe, Co, and Ni, in metastable tetragonal Ru, which has been predicted. Body-centered tetragonal Ru phase is realized by use of strain via seed layer engineering. X-ray diffraction and electron microscopy confirm the epitaxial mechanism to obtain tetragonal phase Ru. We observed a saturation magnetization of 148 and 160 emu cm-3 at room temperature and 10 K, respectively. Control samples ensure the ferromagnetism we report on is from tetragonal Ru and not from magnetic contamination. The effect of thickness on the magnetic properties is also studied, and it is observed that increasing thickness results in strain relaxation, and thus diluting the magnetization. Anomalous Hall measurements are used to confirm its ferromagnetic behavior.
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The magnetoresistance of La0.7Sr0.3MnO3/SrTiO3 superlattices with magnetic field rotating out-of-plane shows unexpected peaks for in-plane fields. Resistivity calculations with spin-orbit coupling reveal that orbital reconstruction at the manganite interface leads to a 2D ferromagnetic electron gas coupled antiparallel to the manganite "bulk". These orbital and magnetic reconstructions are supported by X-ray linear dichroism and ab initio calculations.
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Using X-ray absorption spectroscopy and electron energy loss spectroscopy with atomic-scale spatial resolution, experimental evidence for charge transfer at the interface between the Mott insulators Sm2 CuO4 and LaFeO3 is obtained. As a consequence of the charge transfer, the Sm2 CuO4 is doped with electrons and thus epitaxial Sm2 CuO4 /LaFeO3 heterostructures become metallic.