RESUMO
The performance of nonfullerene-acceptor-(NFA)-based organic solar cells is rapidly approaching the efficiency of inorganic cells. The chemical versatility of NFAs extends the light-harvesting range to the infrared, while preserving a considerably high open-circuit-voltage, crucial to achieve power-conversion efficiencies >17%. Such low voltage losses in the charge separation process have been attributed to a low-driving-force and efficient exciton dissociation. Here, we address the nature of the subpicosecond dynamics of electron/hole transfer in PM6/Y6 solar cells. While previous reports focused on active layers only, we developed a photocurrent-detected two-dimensional spectroscopy to follow the charge transfer in fully operating devices. Our measurements reveal an efficient hole-transfer from the Y6-acceptor to the PM6-donor on the subpicosecond time scale. On the contrary, at the same time scale, no electron-transfer is seen from the donor to the acceptor. These findings, putting ultrafast spectroscopy in action on operating optoelectronic devices, provide insight for further enhancing NFA solar cell performance.
RESUMO
Extracting the light trapped in a waveguide, or the opposite effect of trapping light in a thin region and guiding it perpendicular to its incident propagation direction, is essential for optimal energetic performance in illumination, display or light harvesting devices. Here we demonstrate that the paradoxical goal of letting as much light in or out while maintaining the wave effectively trapped can be achieved with a periodic array of interpenetrated fibers forming a photonic fiber plate. Photons entering perpendicular to that plate may be trapped in an intermittent chaotic trajectory, leading to an optically ergodic system. We fabricated such a photonic fiber plate and showed that for a solar cell incorporated on one of the plate surfaces, light absorption is greatly enhanced. Confirming this, we found the unexpected result that a more chaotic photon trajectory reduces the production of photon scattering entropy.