Making Nanofiber Membrane Stand on End to Construct Vertically Interfacial Evaporators for Efficient Solar Evaporation, Omnidirectional Solar Absorption, and Ultrahigh-Salinity Brine Desalination.

Solar-driven interfacial desalination is widely considered to be a promising technology to address the global water crisis. This study proposes a novel electrospun nanofiber-based all-in-one vertically interfacial solar evaporator endowed with a high steam generation rate, steady omnidirectional evaporation, and enduring ultrahigh-salinity brine desalination. In particular, the electrospun nanofiber is collected into the tubular structure, followed by spraying with a dense crosslinked poly(vinyl alcohol) film, which renders them sufficiently strong for the preparation of a vertically array evaporator. The integrated evaporator made an individual capillary as a unit to form multiple thermal localization interfaces and steam dissipation channels, realizing zone heating of water. Thus a high steam generation rate exceeding 4.0 kg m-2 h-1 in pure water is demonstrated even under omnidirectional sunlight, and outperforms existing evaporators. Moreover, salt ions in the photothermal layer can be effectively transported to the water in capillaries and subsequently exchanged with the bulk water due to the strong action of capillary force, which ensures an ultrahigh desalination rate (≈12.5 kg m-2 h-1 under 3 sun) in 25 wt% concentration brine over 300 min. As such, this work provides a meaningful roadmap for the development of state-of-the-art solar-driven interfacial desalination.

Gradient-Charged Hydrogels for Highly Efficient Solar Steam Generation and Desalination.

Solar-driven interface desalination (SDID) is a promising and sustainable technology that produces freshwater from brine. Ionic hydrogels are effective evaporators, providing enhanced interaction with water and ions due to the charged groups on hydrophilic polymer networks. In this study, we developed a hydrogel-based solar steam generator with a gradient-charged (GC) structure for desalination. The gradient-charged groups' distribution on the hydrogels creates gradients of free water and osmotic pressure, realizing rapid water supplement as well as desalination of concentrated brine. Consequently, the GC hydrogel demonstrated an exceptional water evaporation rate, achieving a value as high as 2.61 kg m-2 h-1 in pure water and 1.72 kg m-2 h-1 on treating with 20 wt % NaCl solution under one sun illumination. Following the substantial solar-driven evaporation, impurities, including salt and other pollutants, were removed, thereby ensuring the purity of the condensed water. Overall, the GC hydrogel-based evaporator is a promising solution for SDID to achieve effective and sustainable water desalination.

Sandwich-structured composite fibrous membranes with tunable porous structure for waterproof, breathable, and oil-water separation applications.

HYPOTHESIS: In general, microporous membranes with waterproofness, breathability, and oil-water separation performance are prepared from hydrophobic raw materials and demonstrated to exhibit an interconnected porous structure. Hence, constructing porous and gradient-structured composite membranes by integrating robust hydrophobic/lipophilic polyvinylidene fluoride (PVDF) and breathable polyurethane (PU) microporous membranes could help realize a selective separation process. EXPERIMENT: Here, novel polyvinylidene fluoride-carbon nanotube/polyurethane/polyvinylidene fluoride-carbon nanotube (PVDF-CNT/PU/PVDF-CNT) sandwich-structured microporous membranes were fabricated by sequential electrospinning. The influence of the thickness ratios of PVDF/PU/PVDF and carbon nanotube (CNT) content on the fibrous construction, porous structure, and wettability of the composite membranes was systematically studied by scanning electron microscopy (SEM), pore size, porosity and contact angle. Significantly, the effect of the fibrous construction, porous structure, and wettability on the waterproofness, breathability, and oil-water separation ability of the composite membranes was investigated. FINDINGS: The novel separation system proved the 'complementary effect' between the PVDF and PU membranes. Further, because of the elaborate gradient construction, superior porous structure, and robust hydrophobicity-oleophilicity, the resultant membranes exhibited moderate waterproofness (38 kPa) and excellent breathability (8.63 kg m-2 d-1), and oil-water separation, confirming that they could be promising alternatives for numerous practical applications, such as protective clothing, treatment of oil-contaminated water, and membrane distillation.