Electron spin resonance study on the 4fhoneycomb quantum magnet YbCl3.

The local magnetic properties of Yb3+in the layered honeycomb material YbCl3were investigated by electron spin resonance on single crystals. For in-plane and out-of-plane field orientations theg-factor shows a clear anisotropy (g∥=2.97(8)andg⊥=1.53(4)), whereas the low temperature exchange coupling and the spin relaxation display a rather isotropic character. At elevated temperatures the contribution of the first excited crystal field level (21±2meV) dominates the spin relaxation.