RESUMO
Through quantitatively adjust soil electric field, we investigated the effect of soil electric field on aggregate stability and soil erosion in black soil region of Northeast China with the experiments of wet sieving and rainfall simulation. Results showed that: 1) Soil surface potential absolute value and electric field strength increased with the decreases of electrolyte concentration in bulk solution. Soil electric field strength could reach to 108 V·m-1. 2) With the increase of soil electric field strength, the degree of fragmentation of soil aggregates increased and the mean weight diameter (MWD) decreased sharply first and then kept constant. 3) With decreasing electrolyte concentration and increasing surface potential, the amount of soil loss increased. As the electrolyte concentration was <0.01 mol·L-1, the corresponding soil surface potential was > 210 and 209 mV for Bin-xian and Keshan, respectively, the cumulative amounts of soil loss with rainfall time almost overlapped, suggesting that the electrolyte concentration of 0.01 mol·L-1 was the threshold for soil erosion. 4) There was a linear relationship between soil cumulative loss and MWD. Our results indicated that soil electric field strength increased as the rain enters into the soil, which could induce soil aggregate breakdown and release amounts of fine soil particles. Finally, soil erosion occurred under the driving of flowing water. Our results provided insights into the mechanism underlying soil erosion in the black soil region of Northeast China.
Assuntos
Solo , Água , China , Chuva , Movimentos da ÁguaRESUMO
Intensive application of biochar requires better understanding of their environmental behaviors such as stability, fate, and mobility. The release of bulk biochar into biochar nanoparticles (NPs) may bring risks because of their potential flowing into downstream water bodies with nutrients/containments attached. Low-temperature pyrolyzed biochars, namely fruit tree branch biochar of 350/450/550 °C (FB350, FB450 and FB550), corn straw biochar of 350 °C (CB350) and peanut straw biochar of 350 °C (PB350), were produced, and their NPs were extracted. The yield, elemental composition, mineral composition, surface functional groups and zeta potential of biochar NPs were characterized. Subsequently their suspension stability was evaluated in NaCl and CaCl2 solutions by dynamic light scattering technique. The Hamaker constants and particle interaction energy of the biochar NPs were calculated by adopting Derjaguin-Landau-Verwey-Overbeek theory. For biochar NPs of same feedstock, the stability of FB350/450/550-NPs could be predicted well by their zeta potential values. The types of their surface functional groups were the same while their adsorption intensity differed. The scenarios for biochar NPs of different feedstock sources were different, that is, inconsistent variation was observed between their zeta potential and suspension stability, which were rooted in the variable type and quantity of surface functional groups. In conclusion, feedstock was the most significant factor that influenced the suspension stability of biochar NPs, followed by the pyrolysis temperature and solution chemistry, which were highly dependent on surface potential. The findings provide references for the environmental risk evaluation of biochar NPs and reasonable application of biochar in field.