Nanostructured Metallic Glass in a Highly Upgraded Energy State Contributing to Efficient Catalytic Performance.

Metallic glasses (MGs), with high density of low coordination sites and high Gibbs free energy state, are novel promising and competitive candidates in the family of electrochemical catalysts. However, it remains a grand challenge to modify the properties of MGs by control of the disordered atomic structure. Recently, nanostructured metallic glasses (NGs), consisting of amorphous nanometer-sized grains connected by amorphous interfaces, have been reported to exhibit tunable properties compared to the MGs with identical chemical composition. Here, it is demonstrated that electrodeposited Ni-P NG is characterized by an extremely high energy state due to its heterogeneous structure, which significantly promotes the catalytic performance. Moreover, the Ni-P NG with a heterogeneous structure is a perfect precursor for the fabrication of unique honey-like nanoporous structure, which displays superior catalytic performance in the urea oxidation reaction (UOR). Specifically, modified Ni-P NG requires a potential of mere 1.36 V at 10 mA cm-2 , with a Tafel slope of 13 mV dec-1 , which is the best UOR performance in Ni-based alloys. The present work demonstrates that the nanostructurization of MGs provides a universal and effective pathway to upgrade the energy state of MGs for the design of high-performance catalysts in energy conversion.

Space-confined and substrate-directed synthesis of transition-metal dichalcogenide nanostructures with tunable dimensionality.

Atomically thin transition-metal dichalcogenide (TMDC) nanostructures are predicted to exhibit novel physical properties that make them attractive candidates for the fabrication of electronic and optoelectronic devices. However, TMDCs tend to grow in the form of two-dimensional nanoplates (NPs) rather than one-dimensional nanoribbons (NRs) due to their native layered structure. Herein, we have developed a space-confined and substrate-directed chemical vapor deposition strategy for the controllable synthesis of WS2, WSe2, MoSe2, MoS2, WS2(1-x)Se2x NPs and NRs. TMDC NRs with lengths ranging from several micrometers to 100 µm have been obtained and the widths of TMDC NRs can be effectively tuned. Moreover, we found that TMDC NRs show different growth behaviors on van der Waals (vdW) and non-vdW substrates. The micro-nano structures, optical and electronic properties of synthesized TMDC NRs have been systematically investigated. This approach provides a general strategy for controllable synthesis of TMDC NRs, which makes these materials easily accessible as functional building blocks for novel optoelectronic devices.