RESUMO
The number of published literature on the effect of ultrasonic cavitation and advanced oxidation pretreatment on the dewatering performance of anaerobically digested sludge is very limited. This study aims at determining the optimum operating conditions of large-scale filtering centrifuges in wastewater treatment plants. The optimum dose of hydrogen peroxide, ultrasonic power, ultrasonic duration, ultrasonic pulse and particle size distribution for improved dewatering performance were determined in this study. In addition, shear stress-shear rate and viscosity-shear rate rheograms were developed to show the rheological flow properties for varying ultrasonic power and treatment duration. Optimum sonication power, time, pulse and amplitude were determined to be 14 W, 1 min, 55/5 and 20%, respectively. At a pH of 6.8, the optimum concentration of hydrogen peroxide was found to be 43.5 g/L. The optimum hydrogen peroxide dose in the combined conditioning experiments was determined to be 500 mg/L at a pH of 3. Under these optimum conditions, capillary suction time was reduced significantly by 71.1%. This study helps to reduce polymer consumption and provides the optimum pretreatment and dewatering operating conditions, and better monitoring and control in the dewatering unit has significant impact in the overall economy of wastewater treatment plants.
Assuntos
Peróxido de Hidrogênio , Oxirredução , Esgotos , Eliminação de Resíduos Líquidos , Esgotos/química , Peróxido de Hidrogênio/química , Eliminação de Resíduos Líquidos/métodos , Ultrassom/métodos , Concentração de Íons de HidrogênioRESUMO
The green and cost-effective nature of the microbial desalination cell (MDC) make it a promising alternative for future sustainable desalination. However, MDC suffers from a low desalination rate that inhibits it being commercialized. External resistance (Rext) is one of the factors that significantly affect the desalination rate in MDCs, which is still under debate. This research, for the first time, investigated the impact of Rext on MDCs with different internal resistance (Rint) of the system to discover the optimal range of Rext for efficient MDC performance. The results showed that the effect of Rext on desalination rate (2.52 mg/h) was quite low when the Rint of MDC was high (200 Ω). However, operating the MDC with a low Rint (67 Ω) significantly improved the desalination rate (9.85 mg/h) and current generation. When MDC was operated with a low Rint the effect of variable Rext on desalination and current generation was noticeable. Therefore, low Rint (67 Ω) MDC was used to select the optimum Rext when the optimal range was found to be Rext ⪠Rint, Rext < Rint, Rext ≈ Rint (ranging from 1-69 Ω) to achieve the highest desalination rates (10.41-8.59 mg/h). The results showed the superior effect of Rint on desalination rate before selecting the optimal range of Rext in the outer circuit.
Assuntos
Fontes de Energia Bioelétrica , Purificação da ÁguaRESUMO
Developing cost-effective technology for treatment of sewage and nitrogen-containing groundwater is one of the crucial challenges of global water industries. Microbial fuel cells (MFCs) oxidize organics from sewage by exoelectrogens on anode to produce electricity while denitrifiers on cathode utilize the generated electricity to reduce nitrogen from contaminated groundwater. As the exoelectrogens are incapable of oxidizing insoluble, polymeric, and complex organics, a novel integration of an anaerobic sequencing batch reactor (ASBR) prior to the MFC simultaneously achieve hydrolytic-acidogenic conversion of complex organics, boost power recovery, and remove Carbon/Nitrogen (C/N) from the sewage and groundwater. The results obtained revealed increases in the fractions of soluble organics and volatile fatty acids in pretreated sewage by 52 ± 19% and 120 ± 40%, respectively. The optimum power and current generation with the pretreated sewage were 7.1 W m-3 and 45.88 A m-3, respectively, corresponding to 8% and 10% improvements compared to untreated sewage. Moreover, the integration of the ASBR with the biocathode MFC led to 217% higher carbon and 136% higher nitrogen removal efficiencies compared to the similar system without ASBR. The outcomes of the present study represent the promising prospects of using ASBR pretreatment and successive utilization of solubilized organics in denitrifying biocathode MFCs for simultaneous energy recovery and C/N removal from both sewage and nitrate nitrogen-contaminated groundwater.