Simulation Study on Molecular Adsorption of Coal in Chicheng Coal Mine.

To study the importance of the adsorption mechanism of methane (CH4) and carbon dioxide (CO2) in coal for coalbed methane development, we aimed to reveal the influence mechanism of adsorption pressure, temperature, gas properties, water content, and other factors on gas molecular adsorption behavior from the molecular level. In this study, we selected the nonsticky coal in Chicheng Coal Mine as the research object. Based on the coal macromolecular model, we used the molecular dynamics (MD) and Monte Carlo (GCMC) methods to simulate and analyze the conditions of different pressure, temperature, and water content. The change rule and microscopic mechanism of the adsorption amount, equal adsorption heat, and interaction energy of CO2 and CH4 gas molecules in the coal macromolecular structure model establish a theoretical foundation for revealing the adsorption characteristics of coalbed methane in coal and provide technical support for further improving coalbed methane extraction.

Molecular Simulation of Coal Molecular Diffusion Properties in Chicheng Coal Mine.

In order to study the importance of the diffusion mechanism of CH4 and CO2 in coal for the development of coalbed methane, the aim of this paper is to reveal the influence mechanism of pressure, temperature, water content and other factors on the molecular diffusion behavior of gas at the molecular level. In this paper, non-sticky coal in Chicheng Coal Mine is taken as the research object. Based on the molecular dynamics method (MD) and Monte Carlo (GCMC) method, the diffusion characteristics and microscopic mechanism of CH4 and CO2 in coal under different pressures (100 kPa-10 MPa), temperatures (293.15-313.15 K) and water contents (1-5%) were analyzed in order to lay a theoretical foundation for revealing the diffusion characteristics of CBM in coal, and provide technical support for further improving CBM extraction. The results show that high temperature is conducive to gas diffusion, while high pressure and water are not conducive to gas diffusion in the coal macromolecular model.

Development of a Graded Early Warning Index System and Identification of Critical Temperatures for Coal Spontaneous Combustion Using Composite Gas Characteristics.

Conventional single gas alarm method and coal spontaneous combustion three-stage alarm method have become increasingly inadequate to meet complex underground conditions. To address this issue, this study focuses on the coal in the goaf of the Z109 working face in the Donggucheng Mine as the research object. Through program-controlled heating experiments, the production of carbon monoxide and hydrocarbon gases during the coal oxidation process was determined, and the variation characteristics of gas ratios with temperature were further analyzed. The coal spontaneous combustion process was subdivided into seven small stages, and a quantitative composite parameter coal spontaneous combustion grading warning system was formulated. Based on its characteristics, measures to be taken under different warning levels were proposed, and it was determined that 120, 140, and 160 °C are the key temperatures for coal spontaneous combustion prevention and control in the Z109 working face of Donggucheng Mine. By using numerical simulation, the optimal nitrogen injection position for the working face was determined and the on-site fire prevention and extinguishing measures were optimized, providing insights into the establishment of a coal mine spontaneous combustion warning system.

Distribution of H2S in the 10103 excavation working face of the Baozigou coal mine.

Based on the production conditions of the 10103 excavation working face of the Baozigou coal mine, this paper analyzes the potential sources of H2S and the expected emission concentrations of H2S in the working face. Considering the previous engineering practice for controlling H2S disasters in coal mine working faces, numerical simulations were conducted to investigate air flow and H2S migration and diffusion in the tunnel in the excavation working face. The migration and distribution of H2S in the coal seam mining face were studied, and the effects of outlet wind speed, duct location, and duct diameter on the H2S concentration distribution were explored. The higher the outlet wind speed, the more conducive to the emission of H2S gas, but too high a wind speed will be detrimental to the concentrated extraction and purification absorption of H2S; the closer the outlet position of the air duct is to the end of the working surface, the lower the H2S concentration in the vortex area at the corner; the air duct If the diameter is too small, the harmful gases released from hard-to-break coal cannot be entrained and taken away. When the diameter of the air duct is too large, the entrainment volume during the jet process will be expanded. To verify the field distribution of H2S concentration at the bottom, middle, and top of the boring machine, a CD4-type portable H2S instrument was used to analyze the distribution of H2S near the excavation working face.

Experimental Study on the Dielectric Properties of Coal In Situ with Variable Temperatures.

The aim of this study was to explore the mapping relationship between the temperature and the dielectric parameters of coal and rock under variable temperatures as well as to determine the characteristics of a dielectric anomaly response. Experiments were performed using lignite, nonstick coal, gas coal, coking coal, and anthracite. The evolution of pyrolysis characteristics, microcrystal structure, and dielectric properties with changing temperature was investigated, and the changes in the dielectric parameters of coal and rock were comprehensively analyzed. As such, the cause of the dielectric anomaly with changing temperatures of coal and rock was revealed. The results show that the dielectric properties of coal at different pyrolysis temperatures are closely related to the degree of intermolecular thermal motion, the evolution of microcrystal structure, and the mechanism of polarization response. In the low-temperature stage, the thermal motion of coal molecules is weak and exhibits electronic polarization, and the dielectric parameters change slightly with temperature while being dependent on the moisture content. In the high-temperature pyrolysis stage, the intense molecular thermal motion leads to the breaking of chemical bonds and the release of volatiles; moreover, the distance between aromatic layers of coal decreases, the order of aromatic structure increases, the dipole turning polarization is the main polarization type, and the dielectric response is obvious. When the pyrolysis reaction is basically complete, the dielectric constants of the five coal samples reach the maximum. As the temperature increases continuously, the coal structure is destroyed by the weakening of the thermal motion of the coal molecules and the accumulation of thermal stress; meanwhile, the dielectric constant decreases gradually, while the dielectric loss and tangent of dielectric loss increase rapidly. At the same temperature, the dielectric constant decreases with an increase in test frequency. These results lay a foundation for the inversion of dielectric data in fire areas of coal mines.

Research on the dust-control technology of a double-wall attached-ring air curtain on an excavation face.

On the basis of the jet theory of airflow fields and the gas-solid two-phase flow theory, we studied the law of dust migration in a simulated dusting space. We used the control variable method and numerical simulation software to explore the airflow field and dust concentration distribution on the working surface of the dusting under different inlet wind speeds and different attached blades of the double-walled annular air curtain. We determined the speed of the inlet of the annular air curtain to be 30 m/s. When the angle of the attached blade was 30°, the dust concentration of the driver and other workers was controlled below 100 mg/m3, which produced the best dust control effect is the best. Using real data, we built a similar test platform to test the airflow field and dust concentration. Through data measurement and analysis, we proved that a dust control system with a double-wall attached-ring air curtain formed a circulating airflow field that could shield dust and effectively reduce dust concentration in the simulated space. The dust removal efficiency of total dust and exhaled dust reached 98.5% and 97.5%, respectively. We compared the test data and simulation results and concluded that the double-wall attached-ring air curtain could effectively ensure the safety of mine production and provide a better underground working environment for operators.

Research on CO Migration Patterns in Shallowly Buried Coal Seam Composite Goafs.

To address the issue of CO exceedance in the close-range composite goaf, this paper focuses on the composite goaf of the Shaping Mine as the research subject and investigated the migration dynamics of CO within shallowly buried composite goaf areas. Sulfur hexafluoride gas (SF6) tracer experiments were conducted at the 13103 working face in Shaping Mine to assess surface fissures and air leakage, yielding insights into the distribution patterns of air leakage channels and facilitating the identification of critical areas for channel sealing. Programmed heating and oxidation experiments were conducted on coal seams 8# and 13# to determine the CO generation patterns during coal oxidation. The results show that higher concentrations of O2 corresponded to elevated CO production at equivalent temperatures. Subsequent data analysis unveiled exponential relationships between the O2 consumption rate and CO production rate within the goaf area, offering a theoretical framework for understanding CO migration patterns. Through numerical simulations, the study analyzed the CO migration patterns in the composite goaf area, observing downward diffusion of CO emanating from coal oxidation in the overlying goaf areas followed by dispersion toward the working face and roadways. Driven by airflow dynamics, CO accrued in the return air corner of the working face. Building upon these insights, comprehensive CO management strategies were implemented, resulting in sustained reductions of temperatures and CO concentrations to safe levels within the original high-temperature, high-concentration CO zones. Notably, CO concentrations at the return air corner of the working face continued to decline over the management period, reaching below 24 ppm within 10 to 15 days, highlighting the effectiveness of the management measures in ensuring safe underground production.

Experimental Study on the Effect of CO2 Injection Pressure on the Migration Characteristics and Extraction Effects of Replacement CH4.

To study the effect of CO2 injection pressure on gas migration characteristics and coalbed methane (CBM) extraction, a platform for the experimental replacement of CH4 with CO2 was used to conduct experiments on the replacement of CH4 under different CO2 injection pressures and analyze the gas transport characteristics and CH4 extraction during the experiment. The results reveal that the rate of gas migration out of the coal seam accelerates with increasing gas injection pressure, as determined by comparisons of the migration rates between adjacent monitoring points. The change trend of the CH4 desorption rate under different gas injection pressures is divided into slow decline, sharp decline, and stability stages, and the maximum value of the effective diffusion coefficient increases from 2.3 × 10-5 to 3.4 × 10-5 and 4.6 × 10-5 cm2/s as the gas injection pressure increases from 0.6 to 0.8 and 1.0 MPa. Similarly, the change pattern of coal seam permeability can be divided into slow decline, sharp decline, and stability stages. After the gas injection pressure was increased from 0.6 to 0.8 and 1.0 MPa, the CH4 desorption volume increased from 90.2 to 94.1 and 97.8 L, whereas the coal seam CO2 sequestration volume increased from 269.2 to 274.2 and 322.8 L, respectively. In contrast, the CH4 extraction efficiency increased from 76.9 to 80.2 and 82.9%, respectively. The research results have important reference value and practical significance for optimizing the CO2 injection pressure and improving the CBM extraction.

Novel PFA-Based Inorganic Three-Phase Foam for Inhibiting Coal Spontaneous Combustion.

Fire accidents caused by coal spontaneous combustion usually lead to a large loss of coal resources and casualties. Not only that, the greenhouse effect is polluted while the environment is polluted. At present, the commonly used fire-extinguishing materials such as water, inhibitors, and organic foams have the disadvantages of poor stability and short fire-extinguishing cycles. It is difficult to effectively suppress coal spontaneous combustion and quickly extinguish the fire for a long time. To suppress the spontaneous combustion of coal, the research team proposed an inorganic three-phase foam with a high foam expansion rate, good cohesiveness, and excellent stability. In the formulation, pulverized fly ash (PFA) is used as the matrix, sodium dodecyl benzene sulfonate (SDBS) and α-olefin sulfonate (AOS) are used as foaming agents, curdlan is used as the foam stabilizer, and sodium silicate is the binder. The compound foaming agent with the best performance is optimized, through the two-group compounding test. The composite foaming agent's optimal compound ratio is SDBS/AOS (3:2). The optimal ratio of inorganic three-phase foam (ITPF) components was obtained through the control variable method experiment. The water-cement ratio is 5:1, the composite foaming agent is 0.2%, the curdlan is 0.5%, and the sodium silicate is 1.6%. In addition, it has been determined by experiments that ITPF has the strongest foaming ability when the pH value is 9 and the temperature is 60 °C. The fire-extinguishing performance of the new material ITPF was investigated by thermogravimetry and coal spontaneous combustion tendency test. It has been observed that the new material has the effect of cooling down and isolating coal from contact with oxygen. The results show that the new material ITPF has the potential to prevent coal spontaneous combustion.

Study on Spontaneous Combustion Characteristics and Oxidation Kinetic Parameters of Lignite at Different Oxygen Concentrations.

The spontaneous combustion parameters of lignite at different oxygen concentrations and temperatures were studied by temperature-programmed oxidation experiments. The characteristic parameters, tendency, oxygen consumption rate, kinetic parameters of oxidation reaction, and heat release intensity of coal's spontaneous combustion were studied. The results show that the variation of export oxygen volume fraction of coal samples under different oxygen concentrations is similar. It has a general s-shaped downward trend. The change trend of the CO concentration of the coal sample export is basically the same at different oxygen concentrations. The CO concentration at the outlet of the coal sample increases with the increase in coal temperature. The CO concentration at 0-200 °C increased exponentially with the coal temperature. The distribution pattern of CO/CO2 ranging from 0 to 320 °C was similar at different oxygen concentrations. With the increase of coal temperature, CO/CO2 first increases and then decreases after reaching the extreme point. The change curve of CH4 with coal temperature under different oxygen concentrations meets the exponential change rule. At different oxygen concentrations, the concentration of ethylene at 0-300 °C changes exponentially, but at 300-400 °C there is no rule. When the oxygen concentration is 20.9%, according to the comprehensive judgment index method and cross temperature method, the comprehensive determination of the spontaneous combustion trend of coal samples is grade II. Under different oxygen concentrations, the oxygen consumption rate of coal increases with the increase of temperature; the oxygen consumption rate increases with the increase of oxygen concentration at the same temperature. The activation energy of coal samples increases with the decrease of oxygen supply concentration or the increase of temperature. The thermal strength of the coal sample is consistent with the change trend of the oxygen consumption rate. The heat release intensity of coal samples conforms to an exponential function and polynomial function in the early and late stages, respectively.

Risk identification of coal spontaneous combustion based on COWA modified G1 combination weighting cloud model.

To realize the scientific judgment of spontaneous combustion risk in the coal mine, the spontaneous combustion influence factors were analyzed from the three aspects of coal spontaneous combustion tendency, air leakage, and oxygen supply, heat storage and heat dissipation. And the basis for the evaluation of t spontaneous combustion grade was constructed. Combination ordered weighted averaging (COWA) calculation was introduced to optimizes G1 subjective weighting, and a COWA modified G1 combined weighting cloud model was proposed to identify the spontaneous combustion risk in the coal mine. Finally, the rationality of the model was verified with actual cases. The research results show that the spontaneous combustion risk level in the Lingquan coal mine is relatively safe, which is consistent with the actual situation. And the spontaneous combustion tendency of coal is the leading factor affecting spontaneous combustion risk.

Study on Spontaneous Combustion "Three Zones" of the Distribution Law and Integrated Fire Prevention Technology in Mined-Out Area of Lingquan Mine.

To determine the risk range of remaining coal in the goaf of the higher slice on the seventh mining and fifth face of Lingquan Mine, the beam tube monitoring system was adopted to supervise the temperature and gas content changes in the goaf during the normal mining period of the working face. As per the principle of dividing spontaneous combustion "three zones" (SCTZ), numerical simulation of the distribution of SCTZ in the goaf of the work face was performed. The O2 content and index gas in the goaf were measured and analyzed, and combined with the in-situ measurement outcomes, the distribution of SCTZ in the goaf was determined through the FLUENT numerical modeling program. The outcomes show that the distribution pattern of SCTZ in the goaf of fully mechanized mining face is: the heat dissipation zone is 0-41 m, the oxidation zone is 41-97 m, the suffocation zone is more than 97 m away from the work face, and the increment of temperature is 0.7/°C. Based on the judgement result of SCTZ, the minimum recovery rate of work face is above 3.7 m/d. The use of new polymer materials validly solves the problem of excessive CO in the return air corner of the goaf and prevents self-ignition accidents in the goaf.

Dynamic prediction model of spontaneous combustion risk in goaf based on improved CRITIC-G2-TOPSIS method and its application.

Due to the problems related to the numerous factors affecting the spontaneous combustion of goaf coal, such as sudden, uncertain, and dynamic changes, and the fact that the weight of the indexes in the prediction model of the spontaneous combustion risk is difficult to determine, an improved Criteria Importance Through Inter-criteria Correlation (CRITIC) modified Technique for Order of Preference by Similarity to Ideal Solution G2-(TOPSIS) dynamic prediction model of goaf spontaneous combustion was developed. An optimal decision-making model was established by introducing the Euclidean distance function, and the function-driven type G2 weighting method was modified using the differential-driven type weighting method of the CRITIC. In addition, the comprehensive weights of each index were obtained. An update factor was introduced to obtain the dynamic weight, and the primary-secondary relationship of the risk factors affecting the spontaneous combustion of goaf was evaluated. Based on the G2 weighting method, which approximates the driving function principle of the ideal solution ranking method (TOPSIS), a G2-TOPSIS goaf spontaneous combustion risk assessment model was established. The degree of closeness was analyzed and the risk grade of the goaf spontaneous combustion was finally predicted. The sub-model was applied to the goaf of working face 1303 in the Jinniu Coal Mine. It was concluded that the air leakage duration was the dominant factor inducing the risk of the spontaneous combustion of the goaf. The risk grade of spontaneous combustion of the goaf is Class III, and the predicted results are consistent with the actual situation. The improved CRITIC-G2-TOPSIS dynamic model was demonstrated to be scientific in predicting the goaf spontaneous combustion risk, and these research results have important popularization and application value.

[Estimated cosmic radiation doses for flight personnel].

Objective. To calculate individual annual cosmic radiation effective dose for monitored flight personnel. Method. With the help of aircraft flight information from flight performance manual, software CARI-6 developed by U.S. Federal Aviation Administration was used to calculate the effective dose of galactic cosmic radiation along the air lines, and to calculate the effective dose rate on the ground in Urumuqi, then individual annual cosmic radiation dose on flight personnel was estimated from the data calculated by CARI-6. Result. The annual cosmic radiation dose on the ground at Urumuqi was 0.420 mSv a-1. The average effective dose rate of all flights of Xinjiang Airlines from 1997 to 1999 was 2.381 microSv h -1(0.33-3. 64 microSv h-1). Average annual cosmic radiation dose on flight personnel was 2.193 mSv a-1 (0.887-4.419 mSv a-1). Conclusion. Annual individual doses of all monitored flight personnel are well below the limit 20 mSv a-1 recommended by International Commission on Radiological Protection (ICRP).