Application of zeolite based nanocomposites for wastewater remediation: Evaluating newer and environmentally benign approaches.

The presence of heavy metal ions and emerging pollutants in water poses a great risk to various biological ecosystems as a result of their high toxicity. Consequently, devising efficient and environmentally friendly methods to decontaminate these waters is of high interest to many researchers around the world. Among the varied water treatment and desalination means, adsorption and photocatalysis have been widely employed. However, the discussion and analysis of the use of zeolite-based composites as adsorbents are somehow minimal. The porous aluminosilicates (zeolites) are excellent candidates in wastewater treatment owing to various mechanisms of pollutants removal that they possess. The purpose of this review is thus to provide a synopsis of the current developments in the fabrication and application of nanocomposites based on zeolite as adsorbents and photocatalysts for the extraction of heavy metals, dyes and emerging pollutants from wastewaters. The review goes on to look into the effect of weight ratio on photocatalyst, photodegradation pathways, and various factors that influence photocatalysis and adsorption.

Characterization and utilization of water treatment sludge for coagulation of raw water.

One of the critical steps in the treatment of raw water for human consumption is clarification. It encompasses coagulation and flocculation to reduce the concentration of suspended solids in turn producing a semi-solid slurry called water treatment sludge (WTS). It is necessary to characterize and find economic and sustainable ways to utilize the WTS. The WTS used in this work was characterized and contained aluminum (Al) (20.3% Al2O3) and iron (Fe) (5.28% Fe2O3) making it suitable for the development of a coagulant. A less energy-intensive way, through atmospheric acid leaching of WTS, was developed to extract Al and Fe for use as a coagulant. The sulphuric acid concentration and solid loading that gave the highest Al concentration were determined to be 3N and 5 g/100 mL, respectively. Turbidity reduction achieved with the developed coagulant ranged from 91 to 99% and was higher than that obtained in related studies due to the higher concentrations of Al and Fe in the WTS used in this study. Since the coagulant was very acidic, it was co-dosed with calcium oxide at 10 g/L of water to adjust the pH of the final water to allowable pH values for potable water (6.5-9.5).

Enhanced covalent p-phenylenediamine crosslinked graphene oxide membranes: Towards superior contaminant removal from wastewaters and improved membrane reusability.

The increasing depletion of freshwater necessitates the re-use and purification of wastewaters. Among the existing separation membrane materials, graphene oxide (GO) is a promising candidate, owing to its tunable physicochemical properties. However, the widening of GO membranes pore gap in aqueous environments is a major limitation. Crosslinking agents can be incorporated to alleviate this problem. This study describes a comparative analysis of uncrosslinked and p-Phenylenediamine (PPD) crosslinked GO membranes' water purification performance. Dip-coating and dip-assisted layer-by-layer methods were used to fabricate the uncrosslinked and crosslinked membranes respectively. The covalent interaction between GO and PPD was confirmed by Fourier Transform Infra-Red and X-ray Photoelectron Spectroscopy. The excellent membrane topographical continuity and intactness was assessed by means of Scanning Electron Microscopy, while water contact angle measurements were undertaken to evaluate and confirm membrane hydrophilicity. The improvement impact of the crosslinker was manifested on the enhancement of the stability and performance of the membranes during nanofiltration tests of aqueous solutions of methylene blue in a homemade nanofiltration cell operated at 1 bar.