Integrating life cycle assessment and characterisation techniques: A case study of biodiesel production utilising waste Prunus Armeniaca seeds (PAS) and a novel catalyst.

Prunus Armeniaca seed (PAS) oil was utilised as a waste biomass feedstock for biodiesel production via a novel catalytic system (SrO-La2O3) based on different stoichiometric ratios. The catalysts have been characterised and followed by a parametric analysis to optimise catalyst results. The catalyst with a stoichiometric ratio of Sr: La-8 (Sr-La-C) using parametric analysis showed an optimum yield of methyl esters is 97.28% at 65 °C, reaction time 75 min, catalyst loading 3 wt% and methanol to oil molar ratio of 9. The optimum catalyst was tested using various oil feedstocks such as waste cooking oil, sunflower oil, PAS oil, date seed oil and animal fat. The life cycle assessment was performed to evaluate the environmental impacts of biodiesel production utilising waste PAS, considering 1000 kg of biodiesel produced as 1 functional unit. The recorded results showed the cumulative abiotic depletion of fossil resources over the entire biodiesel production process as 22,920 MJ, global warming potential as 1150 kg CO2 equivalent, acidification potential as 4.89 kg SO2 equivalent and eutrophication potential as 0.2 kg PO43- equivalent for 1 tonne (1000 kg) of biodiesel produced. Furthermore, the energy ratio (measured as output energy divided by input energy) for the entire production process was 1.97. These results demonstrated that biodiesel obtained from the valorisation of waste PAS provides a suitable alternative to fossil fuels.

Nanomaterial grafted polymorphous activated carbon cloth surface for antibacterial, capacitive deionization and oil spill cleaning applications.

This work reports the development of multifunctional or polymorphous surfaces using zinc oxide (ZnO) nanorods, silica (SiO2), and fluoropolymer functionalization in a sequential process. Firstly, zinc oxide nanorods were grown on activated carbon cloth (ACC) using a simple low-temperature synthesis process. ZnO nanorods-coated ACC substrate was applied to investigate the antimicrobial properties, and the results showed inhibition of 50% for Escherichia coli (E.coli) and 55% for Bacillus subtilis (B.subtilis) over 48 h of incubation time. Subsequent in-situ modification of silica nanoparticles like layer on ZnO nanorods-coated ACC surface was developed and used as an electrode for brackish water desalination in a capacitive deionization system. ZnO-SiO2 modified ACC surface enhanced the desalination efficiency by 1.6 times, the salt removal rate (SRR) by threefold, and the durability (fouling prevention) for long-term usage compared to pristine ACC. Further modification of the ZnO-SiO2-ACC surface using fluoropolymer rendered the surface superhydrophobic and oleophilic. Vegetable (1.4 g/g) and crude oil (1.6 g/g) adsorption capacities were achieved for modified surface which was 70% enhancement compared with pristine ACC. The dynamic oil spill adsorption test exhibited the complete removal of oil spills on water surfaces within a few seconds, suggesting a potential application in oil spill cleaning.

Development of portable sensor for the detection of bacteria: effect of gold nanoparticle size, effective surface area, and interparticle spacing upon sensing interface.

In this study, systematic development of a portable sensor for the rapid detection of Escherichia coli (E. coli) and Exiguobacterium aurantiacum (E. aurantiacum) was reported. A conductive glass was utilized as a substrate and developed the electrode patterns on it. Trisodium citrate (TSC) and chitosan-stabilized gold nanoparticles (AuNPs) (CHI-AuNP-TSC) and chitosan-stabilized AuNPs (CHI-AuNP) were synthesized and utilized as a sensing interface. The morphology, crystallinity, optical properties, chemical structures, and surface properties of immobilized AuNPs on the sensing electrodes were investigated. The sensing performance of the fabricated sensor was evaluated by using an electrochemical method to observe the current changes in cyclic voltammetric responses. The CHI-AuNP-TSC electrode has higher sensitivity toward E. coli than CHI-AuNP with a limit of detection (LOD) of 1.07 CFU/mL. TSC in the AuNPs synthesis process played a vital role in the particle size, the interparticle spacing, the sensor's effective surface area, and the presence of CHI around AuNPs, thus enhancing the sensing performance. Moreover, post-analysis of the fabricated sensor surface exhibited the sensor stability and the interaction between bacteria and the sensor surface. The sensing results showed a promising potential for rapid detection using a portable sensor for various water and food-borne pathogenic diseases.

Autopsy of Used Reverse Osmosis Membranes from the Largest Seawater Desalination Plant in Oman.

The Barka desalination plant, commissioned in 2018, is the largest desalination plant in Oman. It has a capacity of 281 MLD with a reverse osmosis (RO) first-pass recovery rate of 46%. As part of the standard operator practice, a membrane autopsy was conducted to determine the cause of reductions in membrane performance. This study investigated fouled membranes (model No. SW30HRLE-440) from two different locations in the membrane rack. Various analytical methods were used to conduct the membrane autopsy. Field-emission scanning electron microscopy/energy-dispersive X-ray (FESEM/EDS) analyses of membrane samples showed major components of inorganic foulants. Moreover, black and salt-like crystals deposited on the membrane surface revealed significant carbon (C) components and oxygen (O), with a small amount of magnesium (Mg), chloride (Cl), sodium (Na), aluminium (Al), and calcium (Ca), respectively. A Fourier transform infrared (FTIR) analysis revealed the presence of long-chain hydrocarbons, carboxylic acids/esters, carbohydrates/polysaccharides, and inorganic foulants. Thermogravimetric analyses (TGA) of the membranes showed a high initial weight loss due to organic and inorganic fouling. X-ray photoelectron (XPS) analyses further confirmed the presence of inorganic and organic foulants on the membrane surfaces. Bacteria identification results showed the presence of Bacillus cereus and Bacillus marisflavi. This paper offers a detailed analysis of the foulants present on the reverse osmosis membrane surface and sub-surface before and after a cleaning process.

Some Distinct Attributes of ZnO Nanorods Arrays: Effects of Varying Hydrothermal Growth Time.

This study investigates the growth time effect on the structural, morphological, optical, and photoelectrochemical characteristics of highly oriented ZnO nanorod arrays (ZNRAs). The nanorod arrays were grown on ITO substrates using the unified sol-gel spin coating and hydrothermal techniques. ZnO nanoparticles (ZNPs) were synthesized using the sol-gel spin coating method. In contrast, the hydrothermal method was used to grow the ZnO nanorods. The hydrothermal growth time investigated was between 4 and 12 h. The synthesized ZNRAs were used as the photoanode electrodes to investigate their photoelectrochemical (PEC) electrode potency. The as-prepared ZNRAs were characterized using various analytical tools to determine their structures, morphologies, optical, and photoelectrochemical traits. EDX spectra showed the presence of uncontaminated ZnO chemical composition, and FTIR spectra displayed the various functional groups in the samples. A rod-shaped ZnO nanocrystallite with mean lengths and diameters of 300-500 nm and 40-90 nm, respectively, is depicted. HRTEM images indicated the nucleation and growth of ZNRAs with a lattice fringe spacing of 0.26 nm and a growth lattice planer orientation of [002]. The optimum ZNRAs (grown at 8 h) as photoelectrode achieved a photoconversion efficiency of 0.46% and photocurrent density of 0.63 mA/cm2, that was 17 times higher than the one shown by ZNPs with Ag/AgCl as the reference electrode. Both values were higher than those reported in the literature, indicating the prospect of these ZNRAs for photoelectrode applications.

Removal of heavy metal ions by capacitive deionization: Effect of surface modification on ions adsorption.

Activated carbon cloth (ACC) coated with zinc oxide (ZnO) nanoparticles (NPs) have been used as electrodes in flow-by capacitive deionization (CDI) system. Aqueous solution of individual Pb2+ and Cd2+ ions and mixed Pb2+ and Cd2+ ions were used as test contaminant in CDI system to study the effect of surface modification upon ions removal efficiency. Due to the aggregated structure of ZnO NPs on ACC surface, the modified ACC electrodes develop the additional surface area as well as dielectric barrier therefore resulting in higher specific capacitance. In addition, coating with ZnO NPs effectively reduced physical adsorption whereby enhanced the ions adsorption rate and capacity during electrosorption process. Upon incorporating with ZnO NPs, the electrosorption efficiency was enhanced from 17% to 33% for Pb2+, from 21% to 29% for Cd2+ and from 21% to 35% for mixed Pb2+ and Cd2+ ions. The power consumption of individual ions and mixed ions removal process for ACC and ZnO NPs modified ACC were also discussed. Furthermore, used ACC electrodes surfaces were examined using photoelectron spectroscopy (XPS) and results were also conferred. The CDI ACC electrodes with ZnO NPs showed a promising and an effective way for heavy metal removal applications.

ZnO nanorod-chitosan composite coatings with enhanced antifouling properties.

The current study describes the fabrication of chitosan­zinc oxide nanorods composite (CHT/ZnO) on fiberglass panels (support substrate). ZnO nanorods (NRs) with size ranging from 20 to 100 nm and some microrods with an approximate size of 0.5-1 µm were grown on fiberglass panels. CHT 1%/ZnO composite had ZnO NRs incorporated into chitosan (CHT) coating while ZnO NRs were not visible in the CHT 2%/ZnO NRs composite. XRD and FTIR results showed the presence of the ZnO and chitosan. The water contact angle decreased from 80° ± 2° (control) to 65° ± 2° for CHT 1%/ZnO NRs and 42 ± 2° for CHT 2%/ZnO NRs composite coatings. The antimicrobial activities of the coated fiberglass panels were investigated using biofilm-forming bacteria Bacillus subtilis and Escherichia coli under both light and dark conditions. CHT/ZnO composite coated fiberglass panels showed the strongest antimicrobial activity compared to chitosan, ZnO NRs coatings, and Zn-based antifouling paint in the experiments with B. subtilis and E. coli under light conditions. The highest antifouling activity was observed for CHT 2%/ZnO composites. CHT/ZnO composites can be good alternatives to the toxic antifouling paints.

Anticorrosion Coated Stainless Steel as Durable Support for C-N-TiO2 Photo Catalyst Layer.

The development of durable photocatalytic supports resistant in harsh environment has become challenging in advanced oxidation processes (AOPs) focusing on water and wastewater remediation. In this study, stainless steel (SS), SS/Ti (N,O) and SS/Cr-N/Cr (N,O) anticorrosion layers on SS meshes were dip-coated with sol gel synthesised C-N-TiO2 photo catalysts pyrolysed at 350 °C for 105 min, using a heating rate of 50 °C/min under N2 gas. The supported C-N-TiO2 films were characterised by scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and Raman spectroscopy. The results showed that C-N-TiO2 was successfully deposited on anticorrosion coated SS supports and had different morphologies. The amorphous C and TiO2 were predominant in C-N-TiO2 over anatase and rutile phases on the surface of SS and anticorrosion supports. The C-N-TiO2 coated films showed enhanced photocatalytic activity for the decolouration of O.II dye under both solar and UV radiation. The fabricated C-N-TiO2 films showed significant antibacterial activities in the dark as well as in visible light. Herein, we demonstrate that SS/Ti(N,O) and SS/Cr-N/Cr(N,O) anticorrosion coatings are adequate photocatalytic and corrosion resistant supports. The C-N-TiO2 photo catalytic coatings can be used for water and wastewater decontamination of pollutants and microbes.