Batch Experimental Studies and Statistical Modeling for the Effective Removal of Tetracycline from Wastewater Using Bimetallic Zn-Cu-Metal-Organic Framework@Hydrogel Composite Beads.

Antimicrobial resistance (AMR) is on an upsurge as more and more broad-spectrum antibiotics are being used haphazardly, resulting in imbalances in the ecosystem and disrupting common/systematic clinical protocols. To combat this issue, metal-organic framework embedded zinc-copper-benzenedicarboxylate@calcium alginate composite beads (Zn-Cu-BDC@CA CBs) were synthesized and utilized for the adsorption of tetracycline (TC) from water. The surface morphology, presence of functional groups, surface area, and thermal stability of Zn-Cu-BDC@CA CBs were evaluated by field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET), and thermal gravimetric analysis (TGA), respectively. Batch adsorption experiments were also carried out to optimize the adsorption performance of Zn-Cu-BDC@CA CBs for TC by adjusting the key parameters, including pH of the solution, contact time, adsorbent dosage, temperature, and initial concentration of TC. From the RSM model, 96.8% removal of TC takes place under the optimum conditions (pH = 7.3, mass = 17.2 mg, concentration = 21.3 ppm, time = 3.4 h, and temperature = 31.8 °C), which aligns closely with the experimental batch study, where the addition of 20 mg of adsorbent to a 20 mL TC solution (20 mg/L) at a pH of 7 and a temperature of 27 °C yielded an impressive TC removal efficiency of 96.55% within 180 min. Zn-Cu-BDC@CA CBs possess homogeneous adsorption surfaces, and TC is adsorbed via monolayer chemisorption, according to the results derived from the Langmuir isotherm model and pseudo-second-order kinetic model. The thermodynamic analysis indicated that the adsorption process is both endothermic and spontaneous. In their entirety, the synthesized Zn-Cu-BDC@CA CBs exhibit certain operational advantages, such as simple separation, satisfactory adsorption performance, and decent recyclability, indicating their viability for industrial application of elimination of TC residues from aquatic environments.

Waste to value transformation: Converting Carica papaya seeds into green fluorescent carbon dots for simultaneous selective detection and degradation of tetracycline hydrochloride in water.

Rampant use of antibiotics has resulted in their seepage into groundwater and ultimately ending up in the food chain, causing antimicrobial resistance. To address this issue, it is imperative to not only quantitatively detect but eliminate them from water. An eco-friendly, one-step microwave-induced pyrolysis of waste papaya seeds (PS) with ethylenediamine (EDA) for just 5min gave green fluorescent nitrogen-doped carbon dots (PS-CDs), which are capable of detecting and photocatalytically degrading TC. The fluorescence properties of PS-CDs displayed that it has high sensitivity and selectivity towards sensing of TC with a detection limit as low as 120 nM. Also, the method gave satisfactory recovery results when extrapolated to determine TC in spiked milk, orange juice, tap water, and honey samples. On the other hand, PS-CDs alone potentially function as an efficient photocatalyst for the degradation of TC. PS-CDs' dual functionality provides an effectual method for the simultaneous detection and degradation of TC by a single nanoprobe.

Circular economical approach of extracting nanocarbons from waste pea peel for sensing of p-nitrophenol and its conversion into paracetamol.

An important paradigm shift towards the circular economy is to prioritize waste prevention, reuse, recycling, and recovery before disposal is necessary. In this context, a sustainable protocol of converting waste pea peel (wPP) into low-cost carbon nanomaterials for sensing and conversion of p-nitrophenol (p-NP) into value-added paracetamol is being reported. Two fractions of the carbonaceous nanomaterials were obtained after the hydrothermal treatment (HT) of wPP, firstly an aqueous portion containing water-soluble carbon dots (wPP-CDs) and a solid residue, which was converted into carbonized biochar (wPP-BC). Blue-colored fluorescent wPP-CDs displayed excitation-dependent and pH-independent properties with a quantum yield (QY) of 8.82 %, which were exploited for the fluorescence sensing of p-NP with 4.20 µM limit of detection. Pyrolyzed biochar acting as an efficient catalyst effectively reduces p-NP to p-aminophenol (p-AP) in just 16 min with a 0.237 min-1 rate of conversion. Furthermore, the produced p-AP was converted into paracetamol, an analgesic and antipyretic drug, to achieve zero waste theory. Thus, this study provides the execution of sustainable approaches based on the integral valorization of biowaste that can be further recycled and reused, offering an effective way to attain a profitable circular economy.

Non-toxic and biodegradable κ-carrageenan/ZnO hydrogel for adsorptive removal of norfloxacin: Optimization using response surface methodology.

Antibiotic resistance is increasing globally due to increased prescription and easy dispensing of antibiotic drugs universally. Hence, to mitigate this effect, efficient, biodegradable, and non-toxic adsorbents are required to be developed. Carrageenan (CG), a natural polymer, having multiple functional groups, provides a backbone for crosslinking with borax and incorporation of ZnO nanoparticles that formed borax-cross-linked κ-carrageenan (CG/Bx/ZnO) hydrogel which is used for efficient adsorption of norfloxacin from water. Surface morphology of as-synthesized hydrogel revealed the rough surface, which was determined by FESEM. Surface area of CG/Bx/ZnO hydrogel was found to be 22.90 m2/g with 3.41 nm pore radius. Systematic batch adsorption studies revealed that 99.4 % removal efficiency could be achieved at a dosage level of 20 mg/L of norfloxacin with 10 mg of hydrogel at pH of 4 in 8 h at room temperature. Experimentally optimized key parameters affecting the overall efficiency of adsorption matched well with the results assessed from ANOVA using Box-Behnken composite design model. The adsorption process was well fitted with the pseudo-second-order model and Langmuir isotherm with 1282.05 mg/g adsorption capacity. Thermodynamic study results show that adsorption is spontaneous and endothermic. The CG/Bx/ZnO hydrogel demonstrated excellent repeatability with minimal loss in norfloxacin adsorption for seven cycles.

Quick and hassle-free smartphone's RGB-based color to photocatalytic degradation rate assessment of malachite green dye in water by fluorescent Zr-N-S co-doped carbon dots.

Sunlight active blue emissive zirconium, nitrogen, and sulfur co-doped carbon dots (Zr-N-S-CDs) have been synthesized by microwave-induced pyrolysis for achieving efficient photocatalytic degradation of pollutant malachite green dye (MG) in water. Surface morphology studies using high-resolution transmission electron microscopy confirmed the formation of spherical-shaped CDs with an absorbance peak at 350 nm and emission peak at 437 nm in UV-vis and fluorescence spectroscopy, respectively. Surface functional groups, elemental composition, and metal/non-metal co-doping were confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. To understand the photocatalytic performance of Zr-N-S-CDs, various parameters, such as the source of energy, concentration of dye, catalyst dosage, and change in pH, were investigated. MG dye (20 ppm) at a pH 7 with 0.5 mg/mL of Zr-N-S-CDs could be photodegraded efficiently in 90 min under sunlight (99%) compared to dark and artificial light conditions. Moreover, real-time analysis of degradation rate could be conveniently calculated by integrating the colorimetric responses of MG dye with RGB values obtained by the "Color Picker" app of a smartphone. The degradation rate obtained using a smartphone (97.89%) was found to be in agreement with the UV-vis spectroscopy (99%), thus, providing a new, handy, and instrument-free route for speedy and quantitative estimation of the degradation of hazardous MG dye by Zr-N-S-CDs.