RESUMO
Organic self-assembled molecules (OSAMs) based hole-transporting materials play a pivotal role in achieving highly efficient and stable inverted perovskite solar cells (IPSCs). However, the reported carbazol-based OSAMs have serious drawbacks, such as poor wettability for perovskite solution spreading due to the nonpolar surface, worse matched energy arrangement with perovskite, and limited molecular species, which greatly limit the device performance. To address above problems, a novel OSAM [4-(3,6-glycol monomethyl ether-9H-carbazol-9-yl) butyl]phosphonic acid (GM-4PACz) was synthesized as hole-transporting material by introducing glycol monomethyl ether (GM) side chains at carbazolyl unit. GM groups enhance the surface energy of Indium Tin Oxide (ITO)/SAM substrate to facilitate the nucleation and growth of up perovskite film, suppress cation defects, release the residual stress at SAM/perovskite interface, and evaluate energy level for matching with perovskite. Consequently, the GM-4PACz based IPSC achieves a champion PCE of 25.52 %, a respectable open-circuit voltage (VOC) of 1.21â V, a high stability, possessing 93.29 % and 91.75 % of their initial efficiency after aging in air for 2000â h or tracking at maximum power point for 1000â h, respectively.
RESUMO
Processing additive plays an important role in the standard operation procedures for fabricating top performing polymer solar cells (PSCs) through efficient interactions with key photovoltaic materials. However, improving interaction study of acceptor materials to high performance halogenated aromatic additives such as diiodobenzene (DIB) is a widely neglected route for molecular engineering toward more efficient device performances. In this work, two novel Y-type acceptor molecules of BTP-TT and BTP-TTS with different aromatic side chains on the outer positions are designed and synthesized. The resulting aromatic side chains significantly enhanced the interactions between the acceptor molecules and DIB through an arene/halogenated arene interaction, which improved the crystallinity of the acceptor molecules and induced a polymorph with better photovoltaic performances. Thus, high power conversion efficiencies (PCEs) of 18.04% and 19.22% are achieved in binary and ternary blend devices using BTP-TTS as acceptor and DIB as additive. Aromatic side chain engineering for improving additive interactions is proved to be an effective strategy for achieving much higher performance photovoltaic materials and devices.
RESUMO
Side-chain engineering with heteroatoms is not only effective in tuning frontier molecular orbitals, but also possible for forming secondary bonds which can be utilized to planarize the molecular backbone, hence, improving the photon absorption as well as charge-transport abilities of polymer solar-cell (PSC) materials. Herein, two types of unconventional side chains, namely carboxylate and carbamate, containing various heteroatoms are introduced to the thiophene bridges in high performance benzodithiophene (BDT) based donor polymers to from the novel polymers PTzTz-C and PTzTz-N, respectively. In these polymers, non-covalent Oâ â â S and Nâ â â H interactions induce a high tendency to aggregation. In a ternary-blend PSC with PTzTz-N added to the high-performance D18 : BTP-eC9 blend, complimentary absorption and improved thin-film morphology were observed with a top power conversion efficiency of 18.76 %, which is an improvement of almost 5 % over the D18 : BTP-eC9 binary blends.
RESUMO
A robust hole transporting layer (HTL), using the cost-effective Cobalt(II) acetate tetrahydrate (Co(OAc)2 â 4 H2 O) as the precursor, was simply processed from its aqueous solution followed by thermal annealing (TA) and UV-ozone (UVO) treatments. The TA treatment induced the loss of crystal water followed by oxidization of Co(OAc)2 â 4 H2 O precursor, which increased the work function. However, TA treatment differently realize a high work function and ideal morphology for charge extraction. The resulting problems could be circumvented easily by additional UVO treatment, which also enhanced the conductivity and lowered the resistance for charge transport. The optimal condition was found to be a low temperature TA (150 °C) followed by simple UVO, where the crystal water in Co(OAc)2 â 4 H2 O was removed fully and the HTL surface was anchored by substantial hydroxy groups. Using PM6 as the polymer donor and L8-BO as the electron acceptor, a record high PCE of 18.77 % of the binary blend OSCs was achieved, higher than the common PEDOT:PSS-based solar cell devices (18.02 %).
RESUMO
The limited selection pool of high-performance wide bandgap (WBG) polymer donors is a bottleneck problem of the nonfullerene acceptor (NFA) based organic solar cells (OSCs) that impedes the further improvement of their photovoltaic performances. Herein, a series of new WBG polymers, namely PH-BTz, PS-BTz, PF-BTz, and PCl-BTz, are developed by using the bicyclic difluoro-benzo[d]thiazole (BTz) as the acceptor block and benzo[1,2-b:4,5-b']dithiophene (BDT) derivatives as the donor units. By introducing S, F, and Cl atoms to the alkylthienyl sidechains on BDT, the resulting polymers exhibit lowered energy levels and enhanced aggregation properties. The fluorinated PBTz-F not only exhibits a low-lying HOMO level, but also has stronger face-on packing order and results in more uniform fibril-like interpenetrating networks in the related PF-BTz:L8-BO blend. A high-power conversion efficiency (PCE) of 18.57% is achieved. Moreover, PBTz-F also exhibits a good batch-to-batch reproducibility and general applicability. In addition, ternary blend OSCs based on the host PBTz-F:L8-BO blend and PM6 guest donor exhibits a further enhanced PCE of 19.54%, which is among the highest values of OSCs.
RESUMO
The morphology plays a key role in determining the charge generation and collection process, thus impacting the performances of organic solar cells (OSCs). The limited selection pool of additives to optimize the morphology of OSCs, especially for the emerging layer-by-layer (LbL) OSCs, impeding the improvements of photovoltaic performances. Herein, a new method of using conjugated polymers as the additives to optimize the morphology for improving the photovoltaic performances of LbL-OSCs is reported. Four polymers of PH, PS, PF, and PCl are developed with different side chains. These polymers exhibit poor performances as donor materials and additives in the BHJ devices, due to the unsuitable energy level alignment and unfavorable molecular interactions. By contrast, they can be served as efficient additives to optimize the PM6 fibril matrix for facilitating the penetration of BTP-eC9 and forming an intertwined D/A bicontinuous network with a vertical segregation. Such morphology is optimized by side chain engineering, which enables the progressive improvement of the charge separation and collection. As a result, adding a small amount of PCl as the additive, the optimized morphology contributes to a champion PCE of 19.10% with a high FF of 80.5%.
RESUMO
Suppressing the photon energy loss (Eloss ), especially the non-radiative loss, is of importance to further improve the device performance of organic solar cells (OSCs). However, typical π-conjugated semiconductors possess a large singlet-triplet energy gap (ΔEST ), leading to a lower triplet state than charge transfer state and contributing to a non-radiative loss channel of the photocurrent by the triplet state. Herein, a series of triplet polymer donors are developed by introducing a BNIDT block into the PM6 polymer backbone. The high electron affinity of BNIDT and the opposite resonance effect of the BN bond in BNIDT results in a lowered highest occupied molecular orbital (HOMO) and a largely reduced ΔEST . Moreover, the morphology of the active blends is also optimized by fine-tuning the BNIDT content. Therefore, non-radiative recombination via the terminal triplet loss channels and morphology traps is effectively suppressed. The PNB-3 (with 3% BNIDT):L8-BO device exhibits both small ΔEST and optimized morphology, favoring more efficient charge transfer and transport. Finally, the simultaneously enhanced Voc of 0.907 V, Jsc of 26.59 mA cm-2 , and FF of 78.86% contribute to a champion PCE of 19.02%. Therefore, introducing BN bonds into benchmark polymers is a possible avenue toward higher-performance of OSCs.
RESUMO
Despite remarkable breakthrough made by virtue of "polymerized small-molecule acceptor (PSMA)" strategy recently, the limited selection pool of high-performance polymer acceptors and long-standing challenge in morphology control impede their further developments. Herein, three PSMAs of PYDT-2F, PYDT-3F, and PYDT-4F are developed by introducing different fluorine atoms on the end groups and/or bithiophene spacers to fine-tune their optoelectronic properties for high-performance PSMAs. The PSMAs exhibit narrow bandgap and energy levels that match well with PM6 donor. The fluorination promotes the crystallization of the polymer chain for enhanced electron mobility, which is further improved by following n-doping with benzyl viologen additive. Moreover, the miscibility is also improved by introducing more fluorine atoms, which promotes the intermixing with PM6 donor. Among them, PYDT-3F exhibits well-balanced high crystallinity and miscibility with PM6 donor; thus, the layer-by-layer processed PM6/PYDT-3F film obtains an optimal nanofibril morphology with submicron length and ≈23 nm width of fibrils, facilitating the charge separation and transport. The resulting PM6/PYDT-3F devices realizes a record high power conversion efficiency (PCE) of 17.41% and fill factor of 77.01%, higher than the PM6/PYDT-2F (PCE = 16.25%) and PM6/PYDT-4F (PCE = 16.77%) devices.