Locking Effect in Metal@MOF with Superior Stability for Highly Chemoselective Catalysis.

Ultrasmall metal nanoparticles (NPs) show high catalytic activity in heterogeneous catalysis but are prone to reunion and loss during the catalytic process, resulting in low chemoselectivity and poor efficiency. Herein, a locking effect strategy is proposed to synthesize high-loading and ultrafine metal NPs in metal-organic frameworks (MOFs) for efficient chemoselective catalysis with high stability. Briefly, the MOF ZIF-90 with aldehyde groups cooperating with diamine chains via aldimine condensation was interlocked, which was employed to confine in situ formation of Au NPs, denoted as Au@L-ZIF-90. The optimized Au@La-ZIF-90 has highly dispersed Au NPs (2.60 ± 0.81 nm) with a loading amount around 22 wt % and shows a great performance toward 3-aminophenylacetylene (3-APA) from the selective hydrogenation of 3-nitrophenylacetylene (3-NPA) with a high yield (99%) and excellent durability (over 20 cycles), far superior to contrast catalysts without chains locking and other reported catalysts. In addition, experimental characterization and systematic density functional theory calculations further demonstrate that the locked MOF modulates the charge of Au nanoparticles, making them highly specific for nitro group hydrogenation to obtain 3-APA with high selectivity (99%). Furthermore, this locking effect strategy is also applicable to other metal nanoparticles confined in a variety of MOFs, and all of these catalysts locked with chains show great selectivity (≥90%) of 3-APA. The proposed strategy in this work provides a novel and universal method for precise control of the inherent activity of accessible metal nanoparticles with a programmable MOF microenvironment toward highly specific catalysis.

Low-threshold random lasers based on the DCM-DEG gain system with graphene nanosheets.

In this article, low-threshold random lasers based on DCM-DEG (DD) gain system with graphene nanosheets are studied. The experiment results show that the threshold of random lasers reduces rapidly when an appropriate amount of graphene nanosheets is added in DD solution. Meanwhile, the quantity and quality of random lasing modes raise significantly. We discussed the potential reasons why the graphene nanosheets can strengthen the sample's random lasing. And, the influence of the graphene nanosheet concentration on the radiation characteristics of random lasers is further studied. When the concentration of graphene nanosheets is 0.088wt%, the lasing threshold of DD samples with graphene nanosheets (GDD) is only about 31.8% of the lasing threshold of DD samples, and the quality of random lasing modes is five times higher than that of the DD sample. To further reduce the lasing threshold, the gold (Au) nanoparticles are added in the mixed solution to form the GDD solution with Au nanoparticles (GGDD). The results show that the lasing threshold of the GGDD sample is about 7.73 µJ/pulse, which is 5.2% of the lasing threshold of the DD sample. This experiment provides a new method to study low-threshold and high-quality random lasers based on graphene.

Self-healing properties of Hermite-Gaussian correlated Schell-model beams.

We study theoretically and experimentally the influence of the obstacle position separation from the source on the self-healing capacity of partially coherent beams using Hermite-Gaussian correlated Schell-model beams as a case in point. We establish that the shorter the distance between the obstacle and the source plane and the longer the distance between the obstacle and the observation (receiver) plane, the better the self-healing capacity of the beams. In addition, a similarity degree between the reconstructed and original beams is introduced to quantify the self-healing capacity of partially coherent beams. The derived interesting results may find applications in optical information processing, image transmission, and recovery.

Statistical properties of a partially coherent radially polarized vortex beam propagating in a uniaxial crystal.

Free-space propagation and experimental generation of a partially coherent radially polarized (PCRP) vortex beam were studied recently [Opt. Express24, 13714 (2016)OPEXFF1094-408710.1364/OE.24.013714]. In this work, we explore the statistical properties of such a PCRP vortex beam propagating in a uniaxial crystal. We show that the anisotropy of the refractive index of the uniaxial crystal induces the asymmetrical distribution of the intensity, the degree and the state of polarization, as well as the degree of coherence of the beam during propagation. Further, by comparing the asymmetrical distribution of the statistical properties of the PRCP vortex beam with those of a PRCP beam without a vortex phase, we find that the asymmetrical features can be used for determining whether a PCRP beam carries the vortex phase. Further, we show that from the far-field distribution of the degree of coherence, we could quantify the topological charge and distinguish the handedness of the vortex phase. Our findings provide a novel approach for measuring the phase information of the partially coherent vortex beams.

Spiral spectrum of a Laguerre-Gaussian beam propagating in anisotropic non-Kolmogorov turbulent atmosphere along horizontal path.

Close to the ground, it is generally known that atmospheric turbulence exhibits strong anisotropy, which affects the performance of applications such as free-space optical (FSO) communication. In this paper, we establish a theoretical model for calculating the spiral spectrum, also called the orbital angular momentum (OAM) spectrum, of a Laguerre-Gaussian (LG) beam after propagation through anisotropic turbulence along a horizontal link. This model isolates the effects of anisotropy from other parameters of the turbulence. On the basis of this model, the effects of the anisotropy on the probability density of the OAM spectrum and its corresponding modal crosstalk are studied through numerical examples. Our simulation results show that the width of the OAM spectrum will increase or slightly decrease depending on the specific nature of the anisotropy. In addition, it is demonstrated that the inner scale is more likely to cause modal crosstalk than the outer scale. Some strategies to reduce modal crosstalk in anisotropic turbulence are also discussed. Our results may be useful in OAM-based FSO communication at ground level.

Scintillation properties of a partially coherent vector beam with vortex phase in turbulent atmosphere.

We undertake a computational and experimental study of an advanced class of structured beams, partially coherent radially polarized vortex (PCRPV) beams, on propagation through atmospheric turbulence. A computational propagation model is established to simulate this class of beams, and it is used to calculate the average intensity and on-axis scintillation index of PCRPV beams. On comparison with other classes of structured beams, such as partially coherent vortex beams and partially coherent radially polarized beams, it is found that the PCRPV beams, which structure phase, coherence and polarization simultaneously, show marked improvements in atmospheric propagation. The simulation results agree reasonably well with the experimental results. These beams will be useful in free-space optical communications and remote sensing.

Fraunhofer diffraction and the state of polarization of partially coherent electromagnetic beams.

We generalize the concept of Fraunhofer diffraction to partially coherent electromagnetic beams and show how the state of polarization is affected by a circular aperture. It is illustrated that the far-zone properties of a random beam can be tuned by varying the aperture radius. We find that even an incident beam that is completely unpolarized can sometimes produce a field that is highly polarized.

Partially coherent fractional vortex beam.

We introduce a new kind of partially coherent vortex (PCV) beam with fractional topological charge named partially coherent fractional vortex (PCFV) beam and derive the propagation formula for such beam passing through a stigmatic ABCD optical system with the help of the convolution method. We calculate numerically the propagation properties of a PCFV beam focused by a thin lens, and we find that the PCFV beam exhibits unique propagation properties. The opening gap of the intensity pattern and the rotation of the beam spot disappear gradually and the cross-spectral density (CSD) distribution becomes more symmetric and more recognizable with the decrease of the spatial coherence width, being qualitatively different from those of the PCV beam with integral topological charge. Furthermore, we carry out experimental generation of a PCFV beam with controllable spatial coherence, and measure its focusing properties. Our experimental results are consistent with the theoretical predictions.

Complex degree of coherence measurement for classical statistical fields.

We propose a new method for measuring real and imaginary parts of the complex degree of coherence of a classical field obeying Gaussian statistics. Our method is based on mixing incoherently a coherent Gaussian beam, a local oscillator, and the statistical field. We stress that our approach is especially beneficial for revealing the complex degree of coherence of inhomogeneous two-dimensional fields. As an illustration, we report the complex degree of the coherence measurement of a complex Gaussian-correlated beam. Our method can find applications in image transmission and recovery.

Vortex phase-induced changes of the statistical properties of a partially coherent radially polarized beam.

Partially coherent radially polarized (PCRP) beam was introduced and generated in recent years. In this paper, we investigate the statistical properties of a PCRP beam embedded with a vortex phase (i.e., PCRP vortex beam). We derive the analytical formula for the cross-spectral density matrix of a PCRP vortex beam propagating through a paraxial ABCD optical system and analyze the statistical properties of a PCRP vortex beam focused by a thin lens. It is found that the statistical properties of a PCRP vortex beam on propagation are much different from those of a PCRP beam. The vortex phase induces not only the rotation of the beam spot, but also the changes of the beam shape, the degree of polarization and the state of polarization. We also find that the vortex phase plays a role of resisting the coherence-induced degradation of the intensity distribution and the coherence-induced depolarization. Furthermore, we report experimental generation of a PCRP vortex beam for the first time. Our results will be useful for trapping and rotating particles, free-space optical communications and detection of phase object.

Self-reconstruction of partially coherent light beams scattered by opaque obstacles.

Self-reconstruction refers to an ability of certain fully coherent optical beams to recover their spatial profiles after scattering by obstacles. In this communication, we extend the self-reconstruction concept to partially coherent beams. We show theoretically and verify experimentally that any partially coherent beam can self-reconstruct its intensity profile and state of polarization upon scattering from an opaque obstacle provided the beam coherence area is reduced well below the obstacle area. We stress that our self-reconstruction technique is independent of the obstacle shape and it is scalable to the case of multiple obstacles or even of inhomogeneous media as long as a characteristic obstacle area or a medium inhomogeneity scale is well in excess of the beam coherence area or length, respectively. We anticipate the technique to be instrumental in applications ranging from beam shaping to image transfer and trapped particle manipulation in turbid media.

Propagation of optical coherence lattices in the turbulent atmosphere.

We explore the propagation of recently introduced optical coherence lattices (OCLs) in the turbulent atmosphere. We show that the lattice intensity profile and the spatial degree of coherence will display periodicity reciprocity over long propagation distances even though the lattices are affected by the turbulence. The lattice periodicity reciprocity has been previously conjectured to be advantageous for free-space information transfer and optical communications. We then show how one can increase the distance over which the lattice periodicity reciprocity is preserved in the turbulent atmosphere by engineering input lattice beam parameters. We also show that the OCLs have scintillation indices lower than those of Gaussian beams.

Splitting and combining properties of an elegant Hermite-Gaussian correlated Schell-model beam in Kolmogorov and non-Kolmogorov turbulence.

Elegant Hermite-Gaussian correlated Schell-model (EHGCSM) beam was introduced in theory and generated in experiment just recently [Phys. Rev. A 91, 013823 (2015)]. In this paper, we study the propagation properties of an EHGCSM beam in turbulent atmosphere with the help of the extended Huygens-Fresnel integral. Analytical expressions for the cross-spectral density and the propagation factors of an EHGCSM beam propagating in turbulent atmosphere are derived. The statistical properties, such as the spectral intensity, the spectral degree of coherence and the propagation factors, of an EHGCSM beam in Kolmogorov and non-Kolmogorov turbulence are illustrated numerically. It is found that an EHGCSM beam exhibits splitting and combing properties in turbulent atmosphere, and an EHGCSM beam with large mode orders is less affected by turbulence than an EHGCSM beam with small mode orders or a Gaussian Schell-model beam or a Gaussian beam, which will be useful in free-space optical communications.

Generation and propagation of an electromagnetic Gaussian Schell-model vortex beam.

We outline the propagation of an electromagnetic Gaussian Schell-model (EGSM) vortex beam through a paraxial ABCD optical system and analyze the vortex phase-induced changes of the statistical properties, such as average intensity, state of polarization, and degree of polarization (DOP), of a focused EGSM beam. It is found that one can shape the beam profile of an EGSM vortex beam in the focal plane through varying its initial topological charge, DOP, and coherence widths. Furthermore, we first report experimental generation of an EGSM vortex beam and measure its focusing properties in experiments. Our experimental results are consistent with the numerical results and may be useful in material thermal processing and particle trapping.

Experimental demonstration of ghost imaging with an electromagnetic Gaussian Schell-model beam.

Recently, there has been a controversy about the dependence of the visibility of the ghost image on the degree of polarization (DOP) of a stochastic electromagnetic beam because of different definitions of the visibility. In this paper, we revisit ghost imaging with an electromagnetic Gaussian Schell-model (EGSM) beam. Through numerical examples based on the conventional definition of the visibility, we find that the visibility of the ghost image indeed increases or decreases with the increase of the DOP the beam source under certain conditions. We solve the controversy between literatures and the present paper through analyzing the r.m.s. widths of auto-correlation functions of the x component of the field and of the y component of the field. Furthermore, we carry out experimental demonstration of ghost imaging with an EGSM beam. Our experimental results verify the theoretical predictions.

Experimental study of turbulence-induced beam wander and deformation of a partially coherent beam.

We carry out an experimental study of the effect of spatial coherence on the beam wander and the deformation of a Gaussian Schell-model (GSM) beam propagating through thermally induced turbulence. It is demonstrated that a GSM beam with lower coherence indeed experiences smaller beam wander and deformation than that with higher coherence. Our experimental results are explained by the beam wander theory of partially coherent beam reasonably, and will be useful in free-space optical communications.

Experimental generation of cosine-Gaussian-correlated Schell-model beams with rectangular symmetry.

Cosine-Gaussian-correlated Schell-model sources whose degree of coherence (DOC) is of circular symmetry have been introduced just recently [Opt. Lett. 38, 2578 (2013)]. In this Letter, we propose a model for a source whose DOC is the superposition of two 1D cosine-Gaussian-correlated Schell-model sources, i.e., possesses rectangular symmetry. The novel model sources and beams they generate are termed rectangular cosine-Gaussian Schell-model (RCGSM). The RCGSM beam exhibits unique features on propagation, e.g., its intensity in the far field (or in the focal plane) displays a four-beamlet array profile, being qualitatively different from the ring-shaped profile of the CGSM beam whose DOC is of circular symmetry. Furthermore, we have carried out experimental generation of the proposed beam and measured its focusing properties. Our experimental results are consistent with the theoretical predictions.

Experimental generation of partially coherent beams with different complex degrees of coherence.

We established an experimental setup for generating partially coherent beams with different complex degrees of coherence, and we report experimental generation of an elliptical Gaussian Schell-model (GSM) beam and a Laguerre-GSM beam for the first time. It has been demonstrated experimentally that an elliptical GSM beam and a Laguerre-GSM beam produce an elliptical beam spot and a dark hollow beam spot in the focal plane (or in the far field), respectively, which agrees with theoretical predictions. Our results are useful for beam shaping and particle trapping.

Experimental demonstration of vortex phase-induced reduction in scintillation of a partially coherent beam.

We carry out experimental measurement of the scintillation index of a partially coherent beam-carrying vortex phase (i.e., Gaussian-Schell model vortex beam) propagating through thermally induced turbulence. It is demonstrated that a Gaussian-Schell model vortex beam has appreciably smaller scintillation than a Gaussian-Schell model beam, which will be useful in free-space optical communication.

Establishment and Application of a Patient-Ventilator Asynchrony Remote Network Platform for ICU Mechanical Ventilation: A Retrospective Study.

BACKGROUND: In the process of mechanical ventilation, the problem of patient-ventilator asynchrony (PVA) is faced. This study proposes a self-developed remote mechanical ventilation visualization network system to solve the PVA problem. METHOD: The algorithm model proposed in this study builds a remote network platform and achieves good results in the identification of ineffective triggering and double triggering abnormalities in mechanical ventilation. RESULT: The algorithm has a sensitivity recognition rate of 79.89% and a specificity of 94.37%. The sensitivity recognition rate of the trigger anomaly algorithm was as high as 67.17%, and the specificity was 99.92%. CONCLUSIONS: The asynchrony index was defined to monitor the patient's PVA. The system analyzes real-time transmission of respiratory data, identifies double triggering, ineffective triggering, and other anomalies through the constructed algorithm model, and outputs abnormal alarms, data analysis reports, and data visualizations to assist or guide physicians in handling abnormalities, which is expected to improve patients' breathing conditions and prognosis.