Industrial pilot scale slow pyrolysis reduces the content of organic contaminants in sewage sludge.

Pyrolysis has been gaining global interest as a viable option for reducing organic contaminant levels in waste materials such as sewage sludge (SS) for their subsequent use as a soil amendment. However, publicly available knowledge on the capacity of pyrolysis to reduce the levels in SSs is mostly based on laboratory or bench scale studies. The aim of this study was to examine the effects of industrial pilot scale slow pyrolysis at two temperatures and retention times (450 °C, 1 h and 500 °C, 1.5 h) on a wide range of organic and inorganic contaminants in SSs. Pyrolysis at 500 °C decreased the concentrations of the detected per- and polyfluoroalkyl substances (PFASs, by 30-93 %), brominated diphenyl ethers (BDEs; by 97-98 %) and most endocrine disrupting compounds (EDCs, by 82-96 %) more efficiently than pyrolysis at 450 °C. Estrone and pharmaceuticals, with the exception of paracetamol, were removed to below quantification limits. Non-volatile inorganic contaminants concentrated to the chars (22-46 % increase). These results confirm that slow pyrolysis has the capacity to significantly reduce organic contaminant levels in SSs at an industrial scale, while content of inorganic contaminants depends mainly on the feedstock properties. Pyrolysis temperature of over 500 °C is advised to secure efficient removal of organic contaminants. However, it is anticipated that reactor design with good heat transfer and volatile removal could further improve the removal of organic contaminants from SSs. The results are especially valuable for sludge management operators planning to procure a pyrolysis plant.

Biostimulation proved to be the most efficient method in the comparison of in situ soil remediation treatments after a simulated oil spill accident.

The use of in situ techniques in soil remediation is still rare in Finland and most other European countries due to the uncertainty of the effectiveness of the techniques especially in cold regions and also due to their potential side effects on the environment. In this study, we compared the biostimulation, chemical oxidation, and natural attenuation treatments in natural conditions and pilot scale during a 16-month experiment. A real fuel spill accident was used as a model for experiment setup and soil contamination. We found that biostimulation significantly decreased the contaminant leachate into the water, including also the non-aqueous phase liquid (NAPL). The total NAPL leachate was 19 % lower in the biostimulation treatment that in the untreated soil and 34 % lower in the biostimulation than oxidation treatment. Soil bacterial growth and community changes were first observed due to the increased carbon content via oil amendment and later due to the enhanced nutrient content via biostimulation. Overall, the most effective treatment for fresh contaminated soil was biostimulation, which enhanced the biodegradation of easily available oil in the mobile phase and consequently reduced contaminant leakage through the soil. The chemical oxidation did not enhance soil cleanup and resulted in the mobilization of contaminants. Our results suggest that biostimulation can decrease or even prevent oil migration in recently contaminated areas and can thus be considered as a potentially safe in situ treatment also in groundwater areas.

NAPL migration and ecotoxicity of conventional and renewable fuels in accidental spill scenarios.

Fuels derived from non-petroleum renewable resources have raised interest due to their potential in replacing petroleum-based fuels, but information on their fate and effects in the terrestrial and aquatic environments in accidental spill scenario is limited. In this study, migration of four fuels (conventional diesel, conventional gasoline, renewable diesel NExBTL, and ethanol-blended gasoline RE85 containing maximum 85% ethanol) as non-aqueous phase liquids (NAPL) in soil was demonstrated in a laboratory-scale experiment. Ecotoxicity data was produced for the same fuels. There was no significant difference in migration of conventional and renewable diesel, but gasoline migrated 1.5 times deeper and 7-9 times faster in sand than diesel. RE85 spread horizontally wider but not as deep (p < 0.05) as conventional gasoline. Conventional gasoline was the most toxic (lethal concentration [LC50] 20 mg/kg total hydrocarbon content [THC]) among the studied fuels in soil toxicity test with earthworm Eisenia fetida followed by ethanol-blended gasoline (LC50 1,643 mg/kg THC) and conventional diesel (LC50 2,432 mg/kg THC), although gasoline evaporated fast from soil. For comparison, the toxicity of the water-accommodated fractions (WAF) of the fuels was tested with water flea Daphnia magna and Vibrio fischeri, also demonstrating groundwater toxicity. The WAF of conventional gasoline and RE85 showed almost similar toxicity to both the aquatic test species. EC50 values of 1:10 (by volume) WAF were 9.9 %WAF (gasoline) and 9.3 %WAF (RE85) to D. magna and 9.3 %WAF (gasoline) and 12.3 %WAF (RE85) to V. fischeri. Low solubility decreased toxicity potential of conventional diesel in aquatic environment, but direct physical effects of oil phase pose a threat to organisms in nature. Renewable diesel NExBTL did not show clear toxicity to any test species.