Excellent Mercury Removal in High Sulfur Atmosphere Using a Novel CuS-BDC-2D Derived by Metal-Organic Frame.

To effectively remove high concentrations of mercury in a high sulfur atmosphere of nonferrous smelting flue gas, a novel two-dimensional CuS-MOF (CuS-BDC-2D) material is synthesized by anchoring S to Cu sites in the Cu-BDC MOF. The highly dispersed CuS active sites and MOF framework structural properties in CuS-BDC-2D enable efficiently collaborate in capturing mercury. CuS-BDC-2D exhibits a layered floral structure with high specific surface area and thermal stability, with poor crystallinity. Compared to CuS and the three-dimensional CuS-MOF (CuS-BDC-3D) structure, CuS-BDC-2D demonstrates significantly higher mercury capture capacity due to the high exposure of active sites and defects sites in the two-dimensional material. Moreover, CuS-BDC-2D exhibits excellent resistance to sulfur, maintaining its high efficiency in removing Hg0 even at high levels of sulfur dioxide (SO2), such as 5000-20,000 ppm. The superior performance of CuS-BDC-2D makes it suitable for controlling mercury emissions in actual nonferrous smelting flue gas. This discovery also paves the way for the development of new mercury adsorbents, which can guide future advancements in this field.

Efficient ozone decomposition in high humidity environments using novel iron-doped OMS-2-loaded activated carbon material.

This study effectively addresses the rapid deactivation of manganese-based catalysts in humid environments during ozone decomposition by introducing iron-doped manganese oxide octahedral molecular sieve (Fe-OMS-2) catalysts supported on activated carbon (AC). By optimizing the doping ratio of Fe-OMS-2, the Fe-OMS-20.5/AC catalyst achieves nearly 100% ozone decomposition efficiency across a wide range of relative humidity levels (0 to 60%), even at elevated air flow rates of 800 L·g-1·h-1, outperforming standalone AC, Fe-OMS-2, or a simple mixture of OMS-2 and AC. The Fe-OMS-20.5/AC catalyst features a porous surface and a mesoporous structure, providing a substantial specific surface area that facilitates the uniform distribution of the Fe-OMS-2 active phase on the AC surface. The incorporation of Fe3+ ions enhances electron transfer between valence state transitions of Mn, thereby improving the catalyst's efficiency in ozone decomposition. Additionally, the AC component protects catalytic sites and enhances the catalyst's humidity resistance. In conclusion, this research presents a novel strategy for developing highly efficient and cost-effective ozone decomposition catalysts that enhance dehumidification, significantly contributing to industrial ozone treatment technologies and advancing environmental protection.