Engineered magnetic core-shell SiO2/Fe microspheres and "medusa-like" microspheres of SiO2/iron oxide/carbon nanofibers or nanotubes.

Iron oxide (IO) thin coatings of controlled thickness on SiO2 microspheres of narrow size distribution were prepared by decomposition at 160 °C of triiron dodecacarbonyl onto silica microspheres dispersed in diethylene glycol diethyl ether free of surfactant or stabilizer. The dried washed SiO2/IO core-shell microspheres were annealed at different temperatures and time periods under inert (Ar) or reducing (H2) atmosphere. The effect of temperature on the chemical composition, morphology, crystallinity, and magnetic properties of the IO and the elemental Fe nanoparticles type coatings onto the SiO2 core microspheres has been elucidated. "Medusa-like" SiO2/IO/carbon nanofibers and tubes particles were prepared by CVD of ethylene on the surface of the SiO2/IO microspheres at different temperatures. The morphology change of the grafted carbon nanofibers and tubes as a function of the CVD temperature was also elucidated.

Heat and let dye: Part II - Rapid heat-fixing of blood traces.

Blood-contaminated shoeprints and footmarks contain valuable operational information as they may bind an individual who stepped in the crime scene with the incident and not merely with the location. As determining the age of a bloodstain remains a challenge, while processing the scene, it is difficult to determine whether the blood is completely, or partially, dry. Thus, executing a dye staining protocol may wash these marks away as they might still be soluble. However, to meet this challenge, it is possible to fix blood marks using heat. This study aims to find a solution for floor surfaces covered by heavier blood traces (shoeprints and footmarks). For this purpose, a new pseudo-operating device was constructed for examining the blood-fixing process of both mentioned trace types. Two trials were performed with depletion marks. The results revealed that fully developed fresh and heavily blood deposits were obtained by heating to 200°C for 7.5 min using the fixing device, followed by a staining protocol using amido black solution. The achieved sharp resolution of the examined bloody prints demonstrates that in certain cases the dehydration mechanism of heating is preferred over precipitating the proteins attributed to 5-sulfosalycilic acid; thus, reducing the risk of washing blood evidence while processing the crime scene.

Finding GSR evidence on used towels.

When a firearm is discharged, gunshot residue (GSR) is produced and may be deposited on a shooter's body and his close vicinity. The tendency of GSR to drop off easily from the shooter may hinder forensic detection; this well-known phenomenon is accelerated by various common physical activities so that the number of particles detected on a suspect decreases over time. After shooting incidents, suspects will often try to cover their tracks by taking a shower. In these cases, it was assumed that no GSR will be detected upon examining the suspect's hand and hair. In the present study, we provide a way to overcome this loss of evidence by taking advantage of another occurrence, namely secondary transfer. Our participants were asked to take a shower after shooting a firearm. Samples were thereafter collected from the used bath towels and were found to contain up to a few dozen particles characteristic of GSR, including very large particles (>45 µm). The detection of GSR on a suspect's towel may provide significant forensic evidence aiding an investigation. When a shooter tries to remove evidence by taking a shower, sampling the towels that he may have used can preserve important evidence and connect a suspect to a shooting incident.