The structure-giving role of Rb+ ions for water-ice nanoislands supported on Cu(111).

We characterize the effect of rubidium ions on water-ice nanoislands in terms of area, fractal dimension, and apparent height by low-temperature scanning tunneling microscopy. Water nanoislands on the pristine Cu(111) surface are compared to those at similar coverage on a Rb+ pre-covered Cu(111) surface to reveal the structure-giving effect of Rb+. The presence of Rb+ induces changes in the island shape, and hence, the water network, without affecting the nanoisland volume. The broad area distribution shifts to larger values while the height decreases from three bilayers to one or two bilayers. The nanoislands on the Rb+ pre-covered surface are also more compact, reflected in a shift in the fractal dimension distribution. We relate the changes to a weakening of the hydrogen-bond network by Rb+.

Considerably Increased Dynamics of CO-Water Complexes over CO and Water Alone.

Solvents are increasingly known to influence chemical reactivity. However, the microscopic origin of solvent effects is scarcely understood, particularly at the individual molecule level. To shed light on this, we explored a well-defined model system of water (D2O) and carbon monoxide on a single-crystal copper surface with time-lapsed low-temperature scanning tunneling microscopy (STM) and ab initio calculations. Through detailed measurements on a time scale of minutes to hours at the limit of single-molecule solvation, we find that at cryogenic temperatures CO-D2O complexes are more mobile than individual CO or water molecules. We also obtain detailed mechanistic insights into the motion of the complex. In diffusion-limited surface reactions, such a solvent-triggered increase in mobility would substantially increase the reaction yield.

C-C Coupling of Carbene Molecules on a Metal Surface in the Presence of Water.

A novel surface-confined C-C coupling reaction involving two carbene molecules and a water molecule was studied by scanning tunneling microscopy in real space. Carbene fluorenylidene was generated from diazofluorene in the presence of water on a silver surface. While in the absence of water, fluorenylidene covalently binds to the surface to form a surface metal carbene, and water can effectively compete with the silver surface in reacting with the carbene. Water molecules in direct contact with fluorenylidene protonate the carbene to form the fluorenyl cation before the carbene can bind to the surface. In contrast, the surface metal carbene does not react with water. The fluorenyl cation is highly electrophilic and draws electrons from the metal surface to generate the fluorenyl radical which is mobile on the surface at cryogenic temperatures. The final step in this reaction sequence is the reaction of the radical with a remaining fluorenylidene molecule or with diazofluorene to produce the C-C coupling product. Both a water molecule and the metal surface are essential for the consecutive proton and electron transfer followed by C-C coupling. This C-C coupling reaction is unprecedented in solution chemistry.

Hydration at Highly Crowded Interfaces.

Understanding the molecular and electronic structure of solvated ions at surfaces requires an analysis of the interactions between the surface, the ions, and the solvent environment on equal footing. Here, we tackle this challenge by exploring the initial stages of Cs^{+} hydration on a Cu(111) surface by combining experiment and theory. Remarkably, we observe "inside-out" solvation of Cs^{+} ions, i.e., their preferential location at the perimeter of the water clusters on the metal surface. In addition, water-Cs complexes containing multiple Cs^{+} ions are observed to form at these surfaces. Established models based on maximum ion-water coordination and conventional solvation models cannot account for this situation, and the complex interplay of microscopic interactions is the key to a fundamental understanding.

Rapid Water Diffusion at Cryogenic Temperatures through an Inchworm-like Mechanism.

Water diffusion across the surfaces of materials is of importance to disparate processes such as water purification, ice formation, and more. Despite reports of rapid water diffusion on surfaces the molecular level, details of such processes remain unclear. Here, with scanning tunneling microscopy, we observe structural rearrangements and diffusion of water trimers at unexpectedly low temperatures (<10 K) on a copper surface, temperatures at which water monomers or other clusters do not diffuse. Density functional theory calculations reveal a facile trimer diffusion process involving transformations between elongated and almost cyclic conformers in an inchworm-like manner. These subtle intermolecular reorientations maintain an optimal balance of hydrogen-bonding and water-surface interactions throughout the process. This work shows that the diffusion of hydrogen-bonded clusters can occur at exceedingly low temperatures without the need for hydrogen bond breakage or exchange; findings that will influence Ostwald ripening of ice nanoclusters and hydrogen bonded clusters in general.

Halogen and structure sensitivity of halobenzene adsorption on copper surfaces.

The adsorption orientation of molecules on surfaces influences their reactivity, but it is still challenging to tailor the interactions that govern their orientation. Here, we investigate how the substituent and the surface structure alter the adsorption orientation of halogenated benzene molecules from parallel to tilted relative to the surface plane. The deviation of the parallel orientation of bromo-, chloro-, and fluorobenzene molecules adsorbed on Cu(111) and Cu(110) surfaces is determined, utilising the surface selection rule in reflection-absorption infrared spectroscopy. On Cu(111), all three halogenated molecules are adsorbed with their molecular plane almost parallel to the surface at low coverages. However, they are tilted at higher coverages; yet, the threshold coverages differ. On Cu(110), merely bromo- and chlorobenzene follow this trend, albeit with a lower threshold for both. In contrast, fluorobenzene molecules are tilted already at low coverages. The substantial influence of the halogen atom and the surface structure on the adsorption orientation, resulting from an interplay of molecule-molecule and molecule-surface interactions, is highly relevant for reactivity confined to two dimensions.

Surface Diffusion Aided by a Chirality Change of Self-Assembled Oligomers under 2D Confinement.

Chirality switching of self-assembled molecular structures is of potential interest for designing functional materials but is restricted by the strong interaction between the embedded molecules. Here, we report on an unusual approach based on reversible chirality changes of self-assembled oligomers using variable-temperature scanning tunneling microscopy supported by quantum mechanical calculations. Six functionalized diazomethanes each self-assemble into chiral wheel-shaped oligomers on Ag(111). At 130 K, a temperature far lower than expected, the oligomers change their chirality even though the molecules reside in an embedded self-assembled structure. Each chirality change is accompanied by a slight center-of-mass shift. We show how the identical activation energies of the two processes result from the interplay of the chirality change with surface diffusion, findings that open the possibility of implementing various functional materials from self-assembled supramolecular structures.

Controlling Reactivity-Real-Space Imaging of a Surface Metal Carbene.

Metal carbenes are key intermediates in a plethora of homogeneous and heterogeneous catalytic processes. However, despite their importance to heterogeneous catalysis, the influence of surface attachment on carbene reactivity has not yet been explored. Here, we reveal the interactions of fluorenylidene (FY), an archetypical aromatic carbene of extreme reactivity, with a Ag(111) surface. For the first time, the interaction of a highly reactive carbene with a metal surface could be studied by scanning tunneling microscopy (STM). FY chemisorbs on Ag(111) with an estimated desorption energy of 3 eV, forming a surface bound silver-carbene complex. The surface interaction leads to a switching of the electronic ground state of FY from triplet to singlet, and to controlled chemical reactivity. This atomistic understanding of the interplay between carbenes and metal surfaces opens the way for the development of novel classes of catalytic systems based on surface metal carbenes.

Polymorphic arrangement of an organic molecule in its hydration environment.

We investigate the polymorphism of complexes formed by the hydration of a functionalized azobenzene molecule by low-temperature scanning tunneling microscopy. Under conditions at which the water-less azobenzene molecules remain as monomers on Au(111), co-adsorption of water leads to water-azobenzene complexes. These complexes prefer to adopt linear arrangements of the azobenzene mediated by its functionalized end groups. Such structures may serve as model systems for investigating the influence of a solvent on a surface reaction.

The Influence of a Changing Local Environment during Photoinduced CO2 Dissociation.

Though largely influencing the efficiency of a reaction, the molecular-scale details of the local environment of the reactants are experimentally inaccessible hindering an in-depth understanding of a catalyst's reactivity, a prerequisite to maximizing its efficiency. We introduce a method to follow individual molecules and their largely changing environment during a photochemical reaction. The method is illustrated for a rate-limiting step in a photolytic reaction, the dissociation of CO2 on two catalytically relevant surfaces, Ag(100) and Cu(111). We reveal with a single-molecule resolution how the reactant's surroundings evolve with progressing laser illumination and with it their propensity for dissociation. Counteracting processes lead to a volcano-like reactivity. Our unprecedented local view during a photoinduced reaction opens the avenue for understanding the influence of the products on reaction yields on the nanoscale.

Common structures of CO2 on structurally different coin metal surfaces.

We investigate superstructures formed by CO2 on Ag(100) and Cu(111) from small clusters forming at 21 K up to multilayers grown at 43 K by low temperature scanning tunneling microscopy. On both surfaces, CO2 nucleates only at defects, here at co-adsorbed CO. At the lower adsorption temperature, superstructures of different symmetry coexist on both surfaces at submonolayer coverage, while the superstructures formed at the higher adsorption temperature differ largely for the two surfaces. On Ag(100), the CO2 monolayer exhibits a long-range order interrupted by antiphase domain boundaries. On Cu(111), a random distribution of domain structures of different symmetry leads to a monolayer without long-range order. Surprisingly, the degree of ordering is inverted for the 2nd layer of CO2. On Ag(100), the coexistence of different superstructures in the 2nd layer leads to reduced long-range order. On Cu(111), a hexagonal 2nd layer exhibits long-range order. A layer of a similar superstructure, hexagonal with long-range order, exists as the 3rd layer of Ag(100). Despite the different substrates, a multitude of common structural features of CO2 exist. Hexagonal layers grow with a long-range order on less ordered layers on both surfaces. Our results suggest that the preferred structure of a CO2 layer is hexagonal.

Anomalously Low Barrier for Water Dimer Diffusion on Cu(111).

A molecular-scale description of water and ice is important in fields as diverse as atmospheric chemistry, astrophysics, and biology. Despite a detailed understanding of water and ice structures on a multitude of surfaces, relatively little is known about the kinetics of water motion on surfaces. Here, we report a detailed study on the diffusion of water monomers and the formation and diffusion of water dimers through a combination of time-lapse low-temperature scanning tunnelling microscopy experiments and first-principles electronic structure calculations on the atomically flat Cu(111) surface. On the basis of an unprecedented long-time study of individual water monomers and dimers over days, we establish rates and mechanisms of water monomer and dimer diffusion. Interestingly, we find that the monomer and the dimer diffusion barriers are similar, despite the significantly larger adsorption energy of the dimer. This is thus a violation of the rule of thumb that relates diffusion barriers to adsorption energies, an effect that arises because of the directional and flexible hydrogen bond within the dimer. This flexibility during diffusion should also be relevant for larger water clusters and other hydrogen-bonded adsorbates. Our study stresses that a molecular-scale understanding of the initial stages of ice nanocluster formation is not possible on the basis of static structure investigations alone.

Microscopic Insight into Electron-Induced Dissociation of Aromatic Molecules on Ice.

We use scanning tunneling microscopy, photoelectron spectroscopy, and ab initio calculations to investigate the electron-induced dissociation of halogenated benzene molecules adsorbed on ice. Dissociation of halobenzene is triggered by delocalized excess electrons attaching to the π^{*} orbitals of the halobenzenes from where they are transferred to σ^{*} orbitals. The latter orbitals provide a dissociative potential surface. Adsorption on ice sufficiently lowers the energy barrier for the transfer between the orbitals to facilitate dissociation of bromo- and chloro- but not of flourobenzene at cryogenic temperatures. Our results shed light on the influence of environmentally important ice particles on the reactivity of halogenated aromatic molecules.

Temperature-dependent Shape Changes of Ice Nanoclusters on Ag(100).

We investigate the influence of the annealing temperature on the evolution of the ice nanoclusters' geometry by means of low-temperature scanning tunneling microscopy. The clusters, grown at 110 K on Ag(100), gradually increase in height and their shape becomes more compact during annealing at 120 K, 125 K, and 130 K. The increase in height indicates an upward mass transport and reflects a stronger water-water than water-surface bonding. The change in shape, quantitatively expressed as an increase in fractal dimension, is driven by a reduction of the total energy of the step edge. The significant changes in geometry induced by a relatively mild temperature increase underline the importance of temperature for the shape and all properties influenced by this shape of hydrogen-bonded clusters of water ice.

Imaging the Solvation of a One-Dimensional Solid on the Molecular Scale.

We have observed the inversion of the solvation environment of a one-dimensional solid by low-temperature scanning tunneling microscopy. Adsorption of 3-methoxy-9-diazofluorene on Ag(111) yields highly oriented supramolecular chains, which are then exposed to water molecules. The annealing of dry and water-decorated chains results in diametrically opposed outcomes. While the former simply leads to an increase in chain length and number, the latter results in a complete loss of order and produces water clusters decorated with the organic molecule.

Hydrophilicity and Microsolvation of an Organic Molecule Resolved on the Sub-molecular Level by Scanning Tunneling Microscopy.

Low-temperature scanning tunneling microscopy was used to follow the formation of a solvation shell around an adsorbed functionalized azo dye from the attachment of the first water molecule to a fully solvated molecule. Specific functional groups bind initially one water molecule each, which act as anchor points for additional water molecules. Further water attachment occurs in areas close to these functional groups even when the functional groups themselves are already saturated. In contrast, water molecules surround the hydrophobic parts of the molecule only when the two-dimensional solvation shell closes around them. This study thus traces hydrophilic and hydrophobic properties of an organic molecule down to a sub-molecular length scale.