Microplastics and Co-pollutants in soil and marine environments: Sorption and desorption dynamics in unveiling invisible danger and key to ecotoxicological risk assessment.

Microplastics (MPs) and their co-pollutants pose significant threats to soil and marine environments, necessitating understanding of their colonization processes to combat the plastic pandemic and protect ecosystems. MPs can act as invisible carriers, concentrating and transporting pollutants, leading to a more widespread and potentially toxic impact than the presence of either MPs or the pollutants alone. Analyzing the sorption and desorption dynamics of MPs is crucial for understanding pollutants amplification and predicting the fate and transport of pollutants in soil and marine environments. This review provides an in-depth analysis of the sorption and desorption dynamics of MPs, highlighting the importance of considering these dynamics in ecotoxicological risk assessment of MPs pollution. The review identifies limitations of current frameworks that neglect these interactions and proposes incorporating sorption and desorption data into robust frameworks to improve the ability to predict ecological risks posed by MPs and co-pollutants in soil and marine environments. However, failure to address the interplay between sorption and desorption can result in underestimation of the true impact of MPs and co-pollutants, affecting livelihoods and agro-employments, and exacerbate poverty and community disputes (SDGs 1, 2, 3, 8, 9, and 16). It can also affect food production and security (SDG 2), life below water and life on land (DSGs 14 and 15), cultural practices, and natural heritage (SDG 11.4). Hence, it is necessary to develop new approaches to ecotoxicological risk assessment that consider sorption and desorption processes in the interactions between the components in the framework to address the identified limitations.

Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO2 with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization.

The level of carbon dioxide in the atmosphere is growing rapidly due to fossil fuel combustion processes, heavy oil, coal, oil shelter, and exhausts from automobiles for energy generation, which lead to depletion of the ozone layer and consequently result in global warming. The realization of a carbon-neutral environment is the main focus of science and academic researchers of today. Several processes were employed to minimize carbon dioxide in the air, some of which include the utilization of non-fossil sources of energy like solar, nuclear, and biomass-based fuels. Consequently, these sources were reported to have a relatively high cost of production and maintenance. The applications of both homogeneous and heterogeneous processes in carbon capture and storage were investigated in recent years and the focus now is on the conversion of CO2 into useful chemicals and compounds. It was established that CO2 can undergo cycloaddition reaction with epoxides under the influence of special catalysts to give cyclic carbonates, which can be used as value-added chemicals at a different level of pharmaceutical and industrial applications. Among the various catalysts studied for this reaction, metal-organic frameworks are now on the frontline as a potential catalyst due to their special features and easy synthesis. Several metal-organic framework (MOF)-based catalysts were studied for their application in transforming CO2 to organic carbonates using epoxides. Here, we report some recent studies of porous MOF materials and an in-depth discussion of two repeatedly used metal-organic frameworks as a catalyst in the conversion of CO2 to organic carbonates.