Biochar-based functional materials for the abatement of emerging pollutants from aquatic matrices.

Biochar has emerged as a versatile and efficient multi-functional material, serving as both an adsorbent and catalyst in removing emerging pollutants (EPs) from aquatic matrices. However, pristine biochar's catalytic and adsorption capabilities are hindered by its poor surface functionality and small pore size. Addressing these limitations involves the development of functionalized biochar, a strategic approach aimed at enhancing its physicochemical properties and improving adsorption and catalytic efficiencies. Despite a growing interest in this field, there is a notable gap in existing literature, with no review explicitly concentrating on the efficacy of biochar-based functional materials (BCFMs) for removing EPs in aquatic environments. This comprehensive review aims to fill this void by delving into the engineering considerations essential for designing BCFMs with enhanced physiochemical properties. The focus extends to understanding the treatment efficiency of EPs through mechanisms such as adsorption or catalytic degradation. The review systematically outlines the underlying mechanisms involved in the adsorption and catalytic degradation of EPs by BCFMs. By shedding light on the prospects of BCFMs as a promising multi-functional material, the review underscores the imperative for sustained research efforts. It emphasizes the need for continued exploration into the practical implications of BCFMs, especially under environmentally relevant pollutant concentrations. This holistic approach seeks to contribute to advancing knowledge and applying biochar-based solutions in addressing the challenges posed by emerging pollutants in aquatic ecosystems.

Comparative study of the removal of sulfate by UASB in light and dark environment.

At present, the application of sewage treatment technologies is restricted by high sulfate concentrations. In the present work, the sulfate removal was biologically treated using an upflow anaerobic sludge blanket (UASB) in the absence/presence of light. First, the start-up of UASB for the sulfate removal was studied in terms of COD degradation, sulfate removal, and effluent pH. Second, the impacts of different operation parameters (i.e., COD/SO42- ratio, temperature and illumination time) on the UASB performance were explored. Third, the properties of sludge derived from the UASB at different time were analyzed. Results show that after 28 days of start-up, the COD removal efficiencies in both the photoreactor and non-photoreactor could reach a range of 85-90% while such reactors could achieve > 90% of sulfate being removed. Besides, higher illumination time could facilitate the removal of pollutants in the photoreactor. To sum up, the present study can provide technical support for the clean removal of sulfate from wastewater using photoreactors.

Ways to mitigate greenhouse gas production from rice cultivation.

Rice cultivation boasts a rich historical legacy, serving as the primary sustenance for over 50% of the global population. However, the cultivation process gives rise to the emission of methane (CH4) and nitrous oxide (N2O), two potent greenhouse gases. Notably, the global warming potential (GWP) of CH4 and N2O surpasses CO2 by 27-30 times and 273 times over 100 years, respectively. Addressing this environmental challenge necessitates exploring technical approaches and management strategies to curb gas emissions while sustaining rice yields. Several critical factors have been identified and analyzed for their potential to mitigate greenhouse gas production during rice cultivation. These include water management, fertilizer management, biochar application, cultivar selection, straw management, modified planting methods, and integration of new energy machinery. A comprehensive understanding and implementation of these methods can contribute significantly to achieving a dual objective: reducing emissions and maintaining optimal rice yields. Looking ahead, a synergistic integration of these diverse methods and management approaches holds promise for more effective results. Furthermore, the intricate water networks associated with rice cultivation should be carefully considered in the overall strategy. By adopting a holistic approach that addresses both emission reduction and sustainable water usage, the future of rice cultivation can be shaped to align with environmental stewardship and food security.

Mitigating microplastic pollution: A critical review on the effects, remediation, and utilization strategies of microplastics.

Microplastics are found ubiquitous in the natural environment and are an increasing source of worry for global health. Rapid industrialization and inappropriate plastic waste management in our daily lives have resulted in an increase in the amount of microplastics in the ecosystem. Microplastics that are <150 µm in size could be easily ingested by living beings and cause considerable toxicity. Microplastics can aggregate in living organisms and cause acute, chronic, carcinogenic, developmental, and genotoxic damage. As a result, a sustainable approach to reducing, reusing, and recycling plastic waste is required to manage microplastic pollution in the environment. However, there is still a significant lack of effective methods for managing these pollutants. As a result, the purpose of this review is to convey information on microplastic toxicity and management practices that may aid in the reduction of microplastic pollution. This review further insights on how plastic trash could be converted as value-added products, reducing the load of accumulating plastic wastes in the environment, and leading to a beneficial endeavor for humanity.

Magnetic biochar serves as adsorbents and catalyst supports for the removal of antibiotics from wastewater: A review.

Numerous antibiotics are being released into the natural environment through wastewater. As antibiotic usage increases annually, its detrimental impact on the environment is escalating. Addressing environmental sustainability and human health requires significant attention towards antibiotic removal. In recent years, magnetic biochar (MBC) has gained widespread application in water treatment due to its exceptional adsorption and catalytic degradation capabilities. Antibiotics such as sulfamethoxazole (SMX), tetracycline (TC), ciprofloxacin (CIP), and others commonly exhibit an adsorption capacity by MBC ranging from 5 mg/g to 900 mg/g. Moreover, MBC typically removes over 90% of these antibiotics within 60 min. The effectiveness of antibiotic removal is significantly influenced by various preparation and modification methods. Furthermore, the incorporation of magnetism enables the material to be recycled and reused multiple times, thereby reducing consumption costs. This article discusses recent studies on antibiotic removal using MBC. It has been observed that variations in the selection of raw material and preparation procedures significantly affect antibiotic removal, while the mechanisms involved in antibiotic removal remain ambiguous. Additionally, it has been noted that the removal process may lead to secondary pollution and high preparation costs. Therefore, this review comprehensively outlines the utilization of MBC in the removal of antibiotics from wastewater, including aspects such as modification, preparation, removal mechanism, and factors influencing removal, and providing recommendations for antibiotic development. The aim is to offer researchers a clear understanding to advance the field of MBC materials.

Membrane modification in enhancement of virus removal: A critical review.

Many waterborne diseases are related with viruses, and COVID-19 worldwide has raised the concern of virus security in water into the public horizon. Compared to other conventional water treatment processes, membrane technology can achieve satisfactory virus removal with fewer chemicals, and prevent the outbreaks of viruses to a maximal extent. Researchers developed new modification methods to improve membrane performance. This review focused on the membrane modifications that enhance the performance in virus removal. The characteristics of viruses and their removal by membrane filtration were briefly generalized, and membrane modifications were systematically discussed through different virus removal mechanisms, including size exclusion, hydrophilic and hydrophobic interactions, electronic interactions, and inactivation. Advanced functional materials for membrane modification were summarized based on their nature. Furthermore, it is suggested that membranes should be enhanced through different mechanisms mainly based on their ranks of pore size. The current review provided theoretical support regarding membrane modifications in the enhancement of virus removal and avenues for practical application.

An in-situ biochar-enhanced anaerobic membrane bioreactor for swine wastewater treatment under various organic loading rates.

A biochar-assisted anaerobic membrane bioreactor (BC-AnMBR) was conducted to evaluate the performance in treating swine wastewater with different organic loading rates (OLR) ranging from 0.38 to 1.13 kg-COD/(m3.d). Results indicated that adding spent coffee grounds biochar (SCG-BC) improved the organic removal efficiency compared to the conventional AnMBR, with an overall COD removal rate of > 95.01%. Meanwhile, methane production of up to 0.22 LCH4/gCOD with an improvement of 45.45% was achieved under a high OLR of 1.13 kg-COD/(m3.d). Furthermore, the transmembrane pressure (TMP) in the BC-AnMBR system was stable at 4.5 kPa, and no irreversible membrane fouling occurred within 125 days. Microbial community analysis revealed that the addition of SCG-BC increased the relative abundance of autotrophic methanogenic archaea, particularly Methanosarcina (from 0.11% to 11.16%) and Methanothrix (from 16.34% to 24.05%). More importantly, Desulfobacterota and Firmicutes phylum with direct interspecific electron transfer (DIET) capabilities were also enriched with autotrophic methanogens. Analysis of the electron transfer pathway showed that the concentration of c-type cytochromes increased by 38.60% in the presence of SCG-BC, and thus facilitated the establishment of DIET and maintained high activity of the electron transfer system even at high OLR. In short, the BC-AnMBR system performs well under various OLR conditions and is stable in the recovery energy system for swine wastewater.

New outlook on hazardous pollutants in the wastewater environment: Occurrence, risk assessment and elimination by electrodeionization technologies.

Over the decades, water contamination has increased substantially and has become a severe global issue. Degradation of natural resources is taking place at an alarming rate as a result of the use of chemicals like dyes, heavy metals, fertilizers, pesticides, and many more, necessitating the development of long-term pollution remediation methods/technologies. As a new development in the field of environmental engineering, electrodeionization incorporates both traditional ion exchange and electrodialysis. This communication provides an overview of hazardous contaminants such as dyes, heavy metals, fertilizers, and pesticides, as well as their converted forms, which are present in water. It highlights the risks of water pollutants to public health and the environment. Various electrochemical methods with a focus on electrodeionization for the treatment of wastewater and removal of hazardous contaminants are outlined in this review. Additionally, this review discusses the challenges and the future outlook for the development in this field of research.

Effect of hydraulic regime on sulfur-packed bed performance: Denitrification and disproportionation.

Sulfur-packed beds (SPBs) have been increasingly incorporated into constructed wetland systems to overcome limitations in achieving satisfactory nitrate removal efficiency. However, the underlying impact of hydraulic regimes on SPB performance remains understudied. This study investigated the performance of a pilot-scale SPB, encompassing sulfur autotrophic denitrification (SAD) and sulfur disproportionation (SDP) processes, under various horizontal flow (HF) and vertical flow (VF) regimes. The HF regime exhibited superior SAD efficiency, achieving 3.1-4.4 mg-N/L of nitrate removal compared to 0.9-2.8 mg-N/L under VF regimes. However, greater sulfide production of 3.8-5.6 mg/L was observed, in contrast to only 1.5-2.3 mg/L under VF regimes when SDP occurred. Employing current computational fluid dynamics simulations could predict general regimes but lacked precision in detailing sulfur layer dynamics. In contrast, determining the spatial distribution of SAD substrates and SDP products offered a viable solution, revealing stagnate, short-circuit, and back flows. Moreover, the feasibility of an aeration approach to reduce sulfide emissions below 0.5 mg/L in case of accidental SDP occurrence was confirmed. This study offers a method for assessing detailed hydraulic regimes within SPBs. Additionally, it provides guidance on optimizing the packing of sulfur-based materials when implementing SPBs in constructed wetland systems and presents a strategy for mitigating excessive sulfide emissions.

A review on control and abatement of soil pollution by heavy metals: Emphasis on artificial intelligence in recovery of contaminated soil.

"Save Soil Save Earth" is not just a catchphrase; it is a necessity to protect soil ecosystem from the unwanted and unregulated level of xenobiotic contamination. Numerous challenges such as type, lifespan, nature of pollutants and high cost of treatment has been associated with the treatment or remediation of contaminated soil, whether it be either on-site or off-site. Due to the food chain, the health of non-target soil species as well as human health were impacted by soil contaminants, both organic and inorganic. In this review, the use of microbial omics approaches and artificial intelligence or machine learning has been comprehensively explored with recent advancements in order to identify the sources, characterize, quantify, and mitigate soil pollutants from the environment for increased sustainability. This will generate novel insights into methods for soil remediation that will reduce the time and expense of soil treatment.

In-situ production of lactate driving the biotransformation of waste activated sludge to medium-chain fatty acid.

Medium-chain fatty acids (MCFAs) have drawn great attention due to their high energy density and superior hydrophobicity. Waste activated sludge (WAS) has been documented as a renewable feedstock for MCFAs production via anaerobic fermentation. However, MCFAs production from WAS depends on exogenous addition of electron donor (ED, e.g., lactate) for chain elongation (CE) bioprocess, which results in increased economic cost and limited practical application. In this study, a novel biotechnology was proposed to produce MCFAs from WAS with in-situ self-formed lactate by inoculating Yoghurt starter powder containing with Lactobacillales cultures. The batch experimental results revealed that the lactate was in-situ generated from WAS and the maximum production of MCFAs increased from 1.17 to 3.99 g COD/L with the increased addition of Lactobacillales cultures from 6✕107 to 2.3✕108 CFU/mL WAS. In continuous long-term test over 97 days, average MCFA production reached up to 3.94 g COD/L with a caproate yield of 82.74% at sludge retention time (SRT) 12 days, and the average MCFA production increased to 5.87 g COD/L with 69.28% caproate and 25.18% caprylate at SRT 15 days. A comprehensive analysis of the metagenome and metatranscriptome demonstrated that the genus of Lactobacillus and Streptococcus were capable of producing lactate from WAS and upgrading to MCFAs. Moreover, another genus, i.e., Candidatus Promineofilum, was firstly revealed that it might be responsible for lactate and MCFAs production. Further investigation of related microbial pathways and enzyme expression suggested that D-lactate dehydrogenase and pyruvate ferredoxin oxidoreductase contributed to lactate and acetyl-CoA production, which were the crucial steps for MCFAs generation and were most actively expressed. This study provides a conceptual framework of MCFAs from WAS with endogenous ED, potentially enhancing the energy recovery from WAS treatment.

Microplastics in the environment: A critical overview on its fate, toxicity, implications, management, and bioremediation strategies.

Microplastics are small plastic pieces ranging in size from 1µ to <5 mm in diameter, are water-soluble, and can be either primary as they are initially created in small sizes or secondary as they develop due to plastic degradation. Approximately 360 million tons of plastic are produced globally every year, with only 7% recycled, leaving the majority of waste to accumulate in the environment and pose a serious threat in the form of microplastics. All ecosystems, particularly freshwater ecosystems, experience microplastic accumulation and are also prone to degrading processes. Degraded microplastics accumulate in many aquatic systems, contaminate them, and enter the food chain as a result of the excessive discharge of plastic trash annually from the domestic to the industrial sector. Due to their pervasiveness, these tiny plastic particles are constantly present in freshwater environments, which are essential to human life. In this sense, microplastic pollution is seen as a worldwide problem that has a detrimental impact on every component of the freshwater environment. Microplastics act as carriers for various toxic components such as additives and other hazardous substances from industrial and urbanized areas. These microplastic-contaminated effluents are ultimately transferred into water systems and directly ingested by organisms associated with a particular ecosystem. The microplastics components also pose an indirect threat to aquatic ecosystems by adsorbing surrounding water pollutants. This review mainly focuses on the sources of microplastics, the ecotoxicity of microplastics and the impact microplastics have on aquatic and marine life, management, and bioremediation of microplastics. Policies and strategies adopted by the Government to combat microplastic pollution are also discussed in this review.

Application of Chlorella vulgaris for nutrient removal from synthetic wastewater and MBR-treated bio-park secondary effluent: growth kinetics, effects of carbon and phosphate concentrations.

Application of Chlorella vulgaris for polishing secondary effluent of a wastewater treatment (containing C, N and P) was investigated. As a first step, batch experiments were conducted in Bold's Basal Media (BBM) to quantify the effects of orthophosphates (0.1-107 mg/L), organic carbon (0-500 mg/L as acetate) and N/P ratio on the growth of Chlorella vulgaris. The results revealed that the orthophosphate concentration was found to control the removal rates of nitrates and phosphates; however, both were effectively removed (> 90%) when the initial orthophosphate concentration was 4-12 mg/L. The maximum nitrate and orthophosphate removals were observed at an N:P ratio of ~ 11. However, the specific growth rate (µ) was significantly increased (from 0.226 to 0.336 g/g/day) when the initial orthophosphate concentration was 0.1-4.3 mg/L. On the other hand, the presence of acetate had significantly improved the specific growth and specific nitrate removal rates of Chlorella vulgaris. The specific growth rate increased from 0.34 g/g/day in a purely autotrophic culture to 0.70 g/g/day in the presence of acetate. Subsequently, the Chlorella vulgaris (grown in BBM) was acclimated and grown in the membrane bioreactor (MBR)-treated real-time secondary effluent. Under the optimised conditions, 92% nitrate and 98% phosphate removals (with a growth rate of 0.192 g/g/day) were observed in the bio-park MBR effluent. Overall, the results indicate that coupling Chlorella vulgaris as a polishing treatment in existing wastewater treatment units could be beneficial for highest level of water reuse and energy recovery goals.

Advancements in heavy metals removal from effluents employing nano-adsorbents: Way towards cleaner production.

Due to the development in science field which gives not only benefit but also introducesundesirable pollution to the environment. This pollution is due to poor discharge activities of industrial effluents into the soil and water bodies, surface run off from fields of agricultural lands, dumping of untreated wastes by municipalities, and mining activites, which deteriorates the cardinal virtue of our environment and causes menace to human health and life. Heavy metal(s), a natural constituent on earth's crust and economic important mineral, due to its recalcitrant effects creates heavy metal pollution which affects food chain and also reduces the quality of water. For this, many researchers have performed studies to find efficient methods for wastewater remediation. One of the most promising methods from economic point of view is adsorption, which is simple in design, but leads to use of a wide range of adsorbents and ease of operations. Due to advances in nanotechnology, many nanomaterials were used as adsorbents for wastewater remediation, because of their efficiency. Many researchers have reported that nanoadsorbents are unmitigatedly a fruitful solution to address this world's problem. This review presents a potent view on various classes of nanoadsorbents and their application to wastewater treatment. It provides a bird's eye view of the suitability of different types of nanomaterials for remediation of wastewater and Backspace gives up-to-date information about polymer based and silica-based nanoadsorbents.

Effective fluorine removal using mixed matrix membrane based on polysulfone: adsorption performance and diffusion behavior.

Fluorine is one of the essential trace elements for human life activities, but excessive intake of fluoride poses a great risk to people's health. In this paper, a series of mixed matrix membrane (MMM)-based polysulfone for removing fluoride were prepared by phase inversion, and their properties, adsorption capacity, adsorption isotherms, adsorption kinetics of fluoride ions, and mechanism were all investigated. The results confirmed that the MMM contained a large number of hydroxyl and aluminum functional groups due to resin being added. The MMM exhibited the best fluorine ion adsorption capacity of 2.502 mg/g at a pH of 6 with the initial concentration of 6 mg/L. As well, adsorption kinetics of fluorine ion on MMM followed the pseudo-second-order model, while the adsorption behavior of fluorine ion on MMM was well simulated by the Langmuir isotherm model. The adsorption capacity of MMM remained stable after six cycles and the regeneration efficiency was still above 80%, resulting in a long-term stability adequate for fluorine ion removal. Complexation and ion exchange played a key role in the fluorine ion adsorption of MMM. These results indicated the MMM as novel type of absorbent had an excellent capacity for removing fluoride.

A critical review on various feedstocks as sustainable substrates for biosurfactants production: a way towards cleaner production.

The quest for a chemical surfactant substitute has been fuelled by increased environmental awareness. The benefits that biosurfactants present like biodegradability, and biocompatibility over their chemical and synthetic counterparts has contributed immensely to their popularity and use in various industries such as petrochemicals, mining, metallurgy, agrochemicals, fertilizers, beverages, cosmetics, etc. With the growing demand for biosurfactants, researchers are looking for low-cost waste materials to use them as substrates, which will lower the manufacturing costs while providing waste management services as an add-on benefit. The use of low-cost substrates will significantly reduce the cost of producing biosurfactants. This paper discusses the use of various feedstocks in the production of biosurfactants, which not only reduces the cost of waste treatment but also provides an opportunity to profit from the sale of the biosurfactant. Furthermore, it includes state-of-the-art information about employing municipal solid waste as a sustainable feedstock for biosurfactant production, which has not been simultaneously covered in many published literatures on biosurfactant production from different feedstocks. It also addresses the myriad of other issues associated with the processing of biosurfactants, as well as the methods used to address these issues and perspectives, which will move society towards cleaner production.

Exploring potential impact(s) of cerium in mining wastewater on the performance of partial-nitrification process and nitrogen conversion microflora.

Cerium Ce(III) is one of the major pollutants contained in wastewater generated during Ce(III) mining. However, the effect(s) of Ce(III) on the functional genera responsible for removing nitrogen biologically from wastewater has not been studied and reported. In this study, the effects of Ce(III) on aspects of partial-nitritation-(PN) process including ammonia oxidation rate (AOR), process kinetics, and microbial activities were investigated. It was found that the effect of dosing Ce(III) in the PN system correlated strongly with the AOR. Compared to the control, batch assays dosed with 5 mg/L Ce(III) showed elevated PN efficiency of about 121%, an indication that maximum biological response was feasible upon Ce(III) dose. It was also found that, PN performance was not adversely affected, given that Ce(III) dose was ≤20 mg/L. Process kinetics investigated also suggested that the maximum Ce(III) dose without any visible inhibition to the activities of ammonium oxidizing bacteria was 1.37 mg/L, but demonstrated otherwise when Ce(III) dose exceeded 5.63 mg/L. Compared to the control, microbes conducted efficient Ce(III) removal (averaged 98.66%) via biosorption using extracellular polymeric substances (EPS). Notably, significant deposits of Ce(III) was found within the EPS produced as revealed by SEM, EDX, CLSM and FTIR. 2-dimensional correlation infrared-(2DCOS-IR) revealed ester group (uronic acid) as a major organic functional group that promoted Ce(III) removal. Excitation-emission matrix-(EEM) spectrum and 2DCOS-IR suggested the dominance of Fulvic acid, hypothesized to have promoted the performance of the PN process under Ce(III) dosage.

Sustainable enzymatic technologies in waste animal fat and protein management.

Waste animal fats and proteins (WAFP) are rich in various animal by-products from food industries. On one hand, increasing production of huge amounts of WAFP brings a great challenge to their appropriate disposal, and raises severe risks to environment and life health. On the other hand, the high fat and protein contents in these animal wastes are valuable resources which can be reutilized in an eco-friendly and renewable way. Sustainable enzymatic technologies are promising methods for WAFP management. This review discussed the application of various enzymes in the conversion of WSFP to value-added biodiesel and bioactivate hydrolysates. New biotechnologies to discover novel enzymes with robust properties were proposed as well. This paper also presented the bio-utilization strategy of animal fat and protein wastes as alternative nutrient media for microorganism growth activities to yield important industrial enzymes cost-effectively.

Integrated methods and scenarios for assessment of sand dunes ecosystem services.

Anthropogenic and natural ecosystems in coastal dunes provide considerable benefits to human well-being. However, to date, we still lack a good understanding of how ecosystem services (ES) supply varies from young dunes (e.g., embryo and fore dunes) to mature dunes (e.g., brown and red dunes). This study proposed a novel modelling methodology by integrating an expert-based matrix, a Bayesian Belief Network (BBN), a structural equation model, and a scenario development method. It aims at evaluating dune ecosystem services for the sustainable development of coastal areas. The model was tested using data collected from dunes in Vietnam. An expert-based matrix to assess the supply capacity of 18 ES in different types of dunes was generated with the participation of 21 interdisciplinary scientists. It was found that red dune ecosystems could supply the most regulation and cultural ecosystem services, while gray dunes provided the least amount. Results from a scenario analysis recommended that decision-making is able to optimize multiple ES by: (i) keeping embryo/fore dunes in their natural state instead of using them for mineral mining and urbanization; (ii) enlarging certified and protected forests areas in gray and yellow dunes; and (iii) optimizing cultural ES supply in red dunes.

Intensive removal of PAHs in constructed wetland filled with copper biochar.

In this study, biochar-loading copper ions (Cu-BC), a novel composite for removing phenanthrene very efficiently from water, was prepared using the impregnation method. The performance of constructed wetlands (CWs) with these modified and original biochar as substrates was analyzed. CW with Cu-BC removed a large amount of phenanthrene (94.09 ± 3.02%). According to the surface characteristics analysis, Cu-BC can promote the removal of pollutants via complex absorption, hydrophobic adsorption, increasing the Lewis Pair and electrostatic attraction. Furthermore the higher nitrate removal rate in the treated system (91.11 ± 1.17%) was observed to have higher levels of bacterial metabolic diversity and denitrifier types. The phenanthrene accumulated in plants with this treatment system was enhanced by the role of copper in photosynthesis. It is able to boost the plant extraction of organic matter.