Local heating with lithographically fabricated plasmonic titanium nitride nanoparticles.

Titanium nitride is considered a promising alternative plasmonic material and is known to exhibit localized surface plasmon resonances within the near-infrared biological transparency window. Here, local heating efficiencies of disk-shaped nanoparticles made of titanium nitride and gold are compared in the visible and near-infrared regions numerically and experimentally with samples fabricated using e-beam lithography. Results show that plasmonic titanium nitride nanodisks are efficient local heat sources and outperform gold nanodisks in the biological transparency window, dispensing the need for complex particle geometries.

Enhanced solar-driven evaporation and mineral extraction from hypersaline produced water using low-cost microporous photothermal foam.

The beneficial reuse of produced water (PW) holds significant promise to alleviate water scarcity. However, it still suffers major limitations associated with the high cost of treatment due to energy consumption, economics of scale, and the complex physiochemical constituents. PW is a hypersaline (TDS âˆ¼ 250,000 mg/l) oilfield water with bio-species, organic matter, anions, divalent cations, and radioactive elements. A sustainable treatment option is solar-driven floating photothermal evaporation (PTE), a desalination technology implemented for seawater characterized by simpler chemical compositions and low salinity. In this work, the photothermal evaporator for PW was fabricated using low-cost commercially available charcoal polyurethane foam. The engineered macrochannels and structural alterations created unique pathways for salt extraction and evaporation; and ensured hydrodynamic balance between the rates of capillary flow and evaporation. This novel design mitigated flooding or dry out on the evaporating surface and kept the system running steadily while simultaneously harvesting freshwater and valuable salts. The key findings from this work are (a) the development of a novel temperature ratio-based method to determine optimum PTE thickness that results in maximum evaporation and thermal localization, (b) the development of the empirical correlation between the rate of thermal localization, evaporation rate, and PTE thickness. It combines the interplay of convection, evaporative flux, conduction, heat capacitance, and thickness on the thermal response of PTE foam to incident solar flux, and (c) experimental evidence revealing efflorescence and subflorescence salt on the evaporating surface and pore, and (d) enhanced evaporation rate of 118 % or 71.6 kg/day-m2 of clean water from chemically complex hypersaline produced water. These findings are significant for the engineering design and estimation of the performance of a PTE in a solar-driven evaporation system.

Meeting world's most stringent Hg criterion: a pilot-study for the treatment of oil refinery wastewater using an ultrafiltration membrane process.

A membrane ultrafiltration (UF) technology was tested using an oil refinery's end-of-pipe effluent to demonstrate the proof of concept, i.e. can the Great Lakes Initiative criterion of less than 1.3 ppt be consistently met at the pilot-scale, and to provide the data necessary for preliminary full-scale process design. This study presents the successful pilot test conducted with continuous but varying feed conditions over a protracted period. The UF membrane process consistently provided a constant permeate quality at all tested operating conditions, virtually independent of the feed water characteristics and the feed Hg concentration (0.5-22.7 ppt). The treatment target of less than 1.3 ppt of Hg was met and exceeded for all tested conditions during the pilot study. Turbidity measurements were <0.5 NTU (with a MDL of 0.5 NTU) 85% of the time and <0.16 NTU 95% of the time when analyzed on-line. The TMP values were below the specification of (negative) 7-12 psi at all tested conditions during the pilot-study. Weekly maintenance cleans and monthly clean in place (CIP) events were very effective in consistently restoring the membrane permeability during the pilot-study.

Fabrication and calibration of oxazine-based optic fiber sensor for detection of ammonia in water.

This paper presented the fabrication and calibration of a clad-modified evanescent based plastic optical fiber (POF) sensor for the detection of ammonia in both stagnant and dynamic aqueous media. This optochemical sensor was based on Oxazine 170 perchlorate (sensing material) and polydimethylsiloxane (PDMS) (protective material) thin layers. A special chemical solution was developed for the etching removal of cladding and a methodology for trapping moisture was exercised. Experimental results on dissolved ammonia detection exhibited short response time (≤10 s), low detection limit (minimum detection limit 1.4 ppm), high sensitivity, and excellent reversibility (over 99%).

Removal of Trace Pharmaceuticals from Water using coagulation and powdered activated carbon as pretreatment to ultrafiltration membrane system.

In this study, the efficacy of water treatment technologies: ultra-filtration (UF), powdered activated carbon (PAC), coagulation (COA) and a combination of these technologies (PAC/UF and COA/UF) to remove target pharmaceuticals (Acetaminophen, Bezafibrate, Caffeine, Carbamazepine, Cotinine, Diclofenac, Gemfibrozil, Ibuprofen, Metoprolol, Naproxen, Sulfadimethoxine, Sulfamethazine, Sulfamethoxazole, Sulfathiazole, Triclosan and Trimethoprim) was investigated. Samples of wastewater from municipal WWTPs were analyzed using direct aqueous injection High Performance Liquid Chromatography with Tandem Quadrupole Mass Spectrometric (LC/MS/MS) detection. On concentration basis, results showed an average removal efficiency of 29%, 50%, and 7%, respectively, for the UF, PAC dosage of 50ppm, and COA dosage of 10ppm. When PAC dosage of 100ppm was used as pretreatment to the combined PAC and UF in-line membrane system, a 90.3% removal efficiency was achieved. The removal efficiency of UF in tandem with COA was 33%, an increase of 4% compared with the single UF treatment. The adsorption effect of PAC combined with the physical separation process of UF revealed the best treatment strategy for removing pharmaceutical contaminant from water.