Aqueous-phase product treatment and monetization options of wet waste hydrothermal liquefaction: Comprehensive techno-economic and life-cycle GHG emission assessment unveiling research opportunities.

While wet waste hydrothermal liquefaction technology has a high biofuel yield, a significant amount of the carbon and nitrogen in the feedstock reports to the aqueous-phase product. Pretreatment of this stream before sending to a conventional wastewater plant is essential or at the very least, advisable. In this work, techno-economic and life-cycle assessments were conducted for the state-of-technology baseline and four aqueous-phase product treatment and monetization options based on experimental data. These options can cut minimum fuel selling prices by up to 13 % and life-cycle greenhouse gas emissions by up to 39 % compared to the baseline. These findings highlight the substantial influence of aqueous produce treatment strategies on the entire wet waste hydrothermal liquefaction process, demonstrating the potential for optimizing economic viability and environmental impact through further research and development of milder treatment methods and diversified by-product valorization pathways.

Decarbonization of Agriculture: The Greenhouse Gas Impacts and Economics of Existing and Emerging Climate-Smart Practices.

The worldwide emphasis on reducing greenhouse gas (GHG) emissions has increased focus on the potential to mitigate emissions through climate-smart agricultural practices, including regenerative, digital, and controlled environment farming systems. The effectiveness of these solutions largely depends on their ability to address environmental concerns, generate economic returns, and meet supply chain needs. In this Review, we summarize the state of knowledge on the GHG impacts and profitability of these three existing and emerging farming systems. Although we find potential for CO2 mitigation in all three approaches (depending on site-specific and climatic factors), we point to the greater level of research covering the efficacy of regenerative and digital agriculture in tackling non-CO2 emissions (i.e., N2O and CH4), which account for the majority of agriculture's GHG footprint. Despite this greater research coverage, we still find significant methodological and data limitations in accounting for the major GHG fluxes of these practices, especially the lifetime CH4 footprint of more nascent climate-smart regenerative agriculture practices. Across the approaches explored, uncertainties remain about the overall efficacy and persistence of mitigation-particularly with respect to the offsetting of soil carbon sequestration gains by N2O emissions and the lifecycle emissions of controlled environment agriculture systems compared to traditional systems. We find that the economic feasibility of these practices is also system-specific, although regenerative agriculture is generally the most accessible climate-smart approach. Robust incentives (including carbon credit considerations), investments, and policy changes would make these practices more financially accessible to farmers.

On-Line Raman Measurement of the Radiation-Enhanced Reaction of Cellobiose with Hydrogen Peroxide.

Production of a chemical feedstock as a secondary product from a commercial nuclear reactor can increase the economic viability of the reactor and enable the deployment of nuclear energy as part of the low-carbon energy grid. Currently, commercial nuclear reactors produce underutilized energy in the form of neutrons and gamma photons. This excess energy can be exploited to drive chemical reactions, increasing the fraction of utilized energy in reactors and providing a valuable secondary product from the reactor. Gamma degradation of cellulosic biomass has been studied previously. However, real-time, on-line monitoring of the breakdown of biomass materials under gamma radiation has not been demonstrated. Here, we demonstrate on-line monitoring of the reaction of cellobiose with hydrogen peroxide under gamma radiation using Raman spectroscopy, providing in situ quantification of organic and inorganic system components.