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1.
Psychother Res ; : 1-14, 2023 Nov 14.
Artigo em Inglês | MEDLINE | ID: mdl-37963339

RESUMO

OBJECTIVE: Resistance management in psychotherapy remains a foundational skill that is associated with positive client outcomes (Westra, H. A., & Norouzian, N. (2018). Using motivational interviewing to manage process markers of ambivalence and resistance in cognitive behavioral therapy. Cognitive Therapy and Research, 42(2), 193-203). However, little is known about which therapist characteristics contribute to successful management of resistance. Research has suggested that psychotherapy performance does not improve with experience (Goldberg, S. B., Rousmaniere, T., Miller, S. D., Whipple, J., Nielsen, S. L., Hoyt, W. T., & Wampold, B. E. (2016). Do psychotherapists improve with time and experience? A longitudinal analysis of outcomes in a clinical setting. Journal of Counseling Psychology, 63(1), 1-11), that psychotherapists lack humility (Macdonald, J., & Mellor-Clark, J. (2015). Correcting psychotherapists' blindsidedness: Formal feedback as a means of overcoming the natural limitations of therapists. Clinical Psychology & Psychotherapy, 22(3), 249-257), and that difficult therapeutic moments may dysregulate therapist emotions (Muran, J. C., & Eubanks, C. F. (2020). Therapist performance under pressure: Negotiating emotion, difference, and rupture. American Psychological Association). This study aimed to 1) identify whether psychotherapy experience (i.e., training versus no training and number of years of psychotherapy experience) was associated with resistance management skill, and 2) identify whether humility and difficulties regulating emotions among trained individuals were each associated with resistance management. METHOD: A sample of 76 trained and 98 untrained participants were recruited for the present study. All participants completed the Comprehensive Intellectual Humility Scale (CIHS, Krumrei-Mancuso, E. J., & Rouse, S. V. (2016). The development and validation of the comprehensive intellectual humility scale. Journal of Personality Assessment, 98(2), 209-221), the Difficulties in Emotion Regulation Scale (DERS; Gratz, K. L., & Roemer, L. (2004). Multidimensional assessment of emotion regulation and dysregulation: Development, factor structure, and initial validation of the difficulties in emotion regulation scale. Journal of Psychopathology and Behavioral Assessment, 26(1), 41-54), and the Resistance Vignette Task (RVT; Westra, H. A., Nourazian, N., Poulin, L., Hara, K., Coyne, A., Constantino, M. J., Olson, D., & Antony, M. M. (2021). Testing a deliberate practice workshop for developing appropriate responsivity to resistance markers: A randomized clinical trial. Psychotherapy, 58, 175-185 ) which was used to assess resistance management skill. RESULTS: Trained individuals performed significantly better on resistance management than untrained individuals; however, years of experience within the trained sample were not associated with resistance management. Conversely, lower humility and greater difficulties regulating emotions were each associated with significantly poorer resistance management in trained individuals. CONCLUSION: These findings suggest the possibility of improving training to focus on key skills, like resistance management, through supporting humility and emotion regulation in training, as opposed to simply acquiring more experience.

2.
J Clin Psychol ; 78(9): 1851-1865, 2022 09.
Artigo em Inglês | MEDLINE | ID: mdl-35218229

RESUMO

BACKGROUND: Therapist appropriate responsivity to client ambivalence and resistance is considered an important interpersonal skill to avoid disengagement and ensure a continued collaborative, productive process. The present study examined the predictive validity of the newly developed Resistance Vignette Task (RVT), a 10-item rapidly administered measure of therapist ability to appropriately respond to various presentations of client resistance. METHODS: Following a resistance management workshop, the concurrent and prospective predictive capacity of RVT scores were examined through test interviews with ambivalent simulators and volunteers. RESULTS: Prospectively, in test interviews with ambivalent interviewees, higher RVT scores immediately postworkshop were associated with significantly greater responsivity (appropriate responsivity and fewer responsivity errors) at 4-month follow-up. RVT scores at the 4-month follow-up point were also concurrently associated with significantly greater therapist responsivity and lower levels of interviewee resistance. CONCLUSIONS: These findings provide further validation for the RVT as a measure of therapist responsivity in vivo, in actual interviews by predicting and being concurrently associated with therapist performance in response to client resistance. Thus, the RVT holds promise in advancing therapist training, as well as research on resistance as it represents an efficient measure of this key therapist skill.


Assuntos
Relações Profissional-Paciente , Psicoterapia , Humanos , Estudos Prospectivos
3.
Atmos Environ (1994) ; 259: 1-118538, 2021 Aug 15.
Artigo em Inglês | MEDLINE | ID: mdl-34385886

RESUMO

This paper uses a machine learning model called a relevance vector machine (RVM) to quantify ozone (O3) and nitrogen oxides (NOx) formation under wintertime conditions. Field study measurements were based on previous work described by Olson et al. (2019), where continuous measurements were reported from a wintertime field study in Utah. RVMs were formulated using either O3 or nitrogen dioxide (NO2) as the output variable. Values of the correlation coefficient (r2) between predicted and measured concentrations were 0.944 for O3 and 0.931 for NO2. RVMs are constructed from the observed measurements and result in sparse model formulations, meaning that only a subset of the data is used to approximate the entire dataset. For this study, the RVM with O3 as the output variable used only 20% of the measurement data while the RVM with NO2 used 16%. RVMs were then used as a predictive model to assess the importance of individual precursors. Using O3 as the output variable, increases in three species resulted in increased O3 concentrations: hydrogen peroxide (H2O2), dinitrogen pentoxide (N2O5), and molecular chlorine (Cl2). For the two termination products measured during the study, nitric acid (HNO3) and formic acid (CH2O2), no change in O3 concentration was observed. Using NO2 as the output variable, only increases in N2O5 resulted in increased NO2 concentrations.

4.
Atmos Environ (1994) ; 2522021 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-33897265

RESUMO

This research used data mining approaches to better understand factors affecting the formation of secondary organic aerosol (SOA). Although numerous laboratory and computational studies have been completed on SOA formation, it is still challenging to determine factors that most influence SOA formation. Experimental data were based on previous work described by Offenberg et al. (2017), where volume concentrations of SOA were measured in 139 laboratory experiments involving the oxidation of single hydrocarbons under different operating conditions. Three different data mining methods were used, including nearest neighbor, decision tree, and pattern mining. Both decision tree and pattern mining approaches identified similar chemical and experimental conditions that were important to SOA formation. Among these important factors included the number of methyl groups for the SOA precursor, the number of rings for the SOA precursor, and the presence of dinitrogen pentoxide (N2O5).

5.
Atmos Environ (1994) ; 218: 1-116988, 2019.
Artigo em Inglês | MEDLINE | ID: mdl-31666799

RESUMO

Concentrations of 11 species are reported from continuous measurements taken during a wintertime field study in Utah. Time series data for measured species generally displayed strong diurnal patterns. Six species show a diurnal pattern of daytime maximums (NO, NOy, O3, H2O2, CH2O2, and Cl2), while five species show a diurnal pattern of night time maximums (NO2, HONO, ClNO2, HNO3, and N2O5). Vector autoregression analyses were completed to better understand important species influencing the formation of O3 and NOx. For the species studied, r2 values of predicted versus measured concentrations ranged from 0.82-0.99. Fitting parameters for the autoregressive matrix, Π, indicated the importance of species precursors. In addition, values of fitting parameters for Π were relatively insensitive to data size, with variations generally <10%. Variable causation was quantified using the Granger causation method. Assuming O3 and NOx behave as chemical products, reactants (in order of importance) are as follows: H2O2, N2O5, HONO, and ClNO2.

6.
Environ Sci Technol ; 51(17): 9911-9919, 2017 Sep 05.
Artigo em Inglês | MEDLINE | ID: mdl-28796509

RESUMO

Volume concentrations of secondary organic aerosol (SOA) are measured in 139 steady-state, single precursor hydrocarbon oxidation experiments after passing through a temperature controlled inlet. The response to change in temperature is well predicted through a feedforward Artificial Neural Network. The most parsimonious model, as indicated by Akaike's Information Criterion, Corrected (AIC,C), utilizes 11 input variables, a single hidden layer of 4 tanh activation function nodes, and a single linear output function. This model predicts thermal behavior of single precursor aerosols to less than ±5%, which is within the measurement uncertainty, while limiting the problem of overfitting. Prediction of thermal behavior of SOA can be achieved by a concise number of descriptors of the precursor hydrocarbon including the number of internal and external double bonds, number of methyl- and ethyl- functional groups, molecular weight, and number of ring structures, in addition to the volume of SOA formed, and an indicator of which of four oxidant precursors was used to initiate reactions (NOx photo-oxidation, photolysis of H2O2, ozonolysis, or thermal decomposition of N2O5). Additional input variables, such as chamber volumetric residence time, relative humidity, initial concentration of oxides of nitrogen, reacted hydrocarbon concentration, and further descriptors of the precursor hydrocarbon, including carbon number, number of oxygen atoms, and number of aromatic ring structures, lead to over fit models, and are unnecessary for an efficient, accurate predictive model of thermal behavior of SOA. This work indicates that predictive statistical modeling methods may be complementary to descriptive techniques for use in parametrization of air quality models.


Assuntos
Aerossóis , Peróxido de Hidrogênio , Oxigênio , Poluentes Atmosféricos , Carbono , Oxirredução
7.
Psychotherapy (Chic) ; 58(2): 186-195, 2021 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-32915009

RESUMO

The present study used a newly developed simplified coding system, the Therapist Demand and Support Code, to examine specific therapist behaviors in the context of a previously conducted training trial on Deliberate Practice (DP). The parent trial randomized trainees to a DP workshop or its Traditional, more didactic counterpart (Westra et al., 2020). In both groups, trainees were taught to use Support, rather than Demand, for managing ambivalence and resistance, with the DP group having more feedback and practice. In this study, 68 trainees interviewed both an ambivalent community volunteer and an ambivalent simulator 4 month post workshop. The DP group was found to exhibit significantly fewer Demand behaviors than the Traditional group, with the latter also being significantly quicker to use Demand in the interviews. Moreover, the simulator evoked significantly greater Demand from therapists, regardless of the Training group, suggesting the simulators were more resistant. Although therapist use of Support was equal for community volunteers across training groups, Traditional workshop trainees decreased Support when interviewing the more resistant simulators, whereas DP trainees increased their Support with this same group. This is consistent with findings that DP trainees were more appropriately responsive, making fewer Demands following interviewee counterchange talk and using more Support at these times. These results provide some initial validation of the simplified therapist behavior coding system and offer further evidence for the benefits of DP workshop training for managing resistance. (PsycInfo Database Record (c) 2021 APA, all rights reserved).


Assuntos
Competência Clínica , Pais , Humanos , Voluntários
8.
Anal Bioanal Chem ; 397(6): 2451-63, 2010 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-20526587

RESUMO

Recovery, precision, limits of detection and quantitation, blank levels, calibration linearity, and agreement with certified reference materials were determined for two classes of organic components of airborne particulate matter, polycyclic aromatic hydrocarbons and hopanes, using typical sampling and gas chromatography/mass spectrometry analysis methods. These determinations were based on initial method proficiency tests and on-going internal quality control procedures. Recoveries generally ranged from 75% to 85% for all target analytes and collocated sample precision estimates were generally better than 20% for polycyclic aromatic hydrocarbons and better than 25% for hopanes. Results indicated substantial differences in data quality between the polycyclic aromatic hydrocarbons and hopanes. Polycyclic aromatic hydrocarbons demonstrated better collocated precision, lower method detection limits, lower blank levels, and better agreement with certified reference materials than the hopanes. The most serious area of concern was the disagreement between measured and expected values in the standard reference material for hopanes. With this exception, good data quality was demonstrated for all target analytes on all other data quality indicators.

9.
J Expo Anal Environ Epidemiol ; 14(2): 109-19, 2004 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-15014541

RESUMO

This study involved an assessment of chloroform formation due to the use of hypochlorite-containing detergents in dishwashers. The objective of this research was to quantify in-home formation of trihalomethanes, particularly as related to dishwasher usage. A series of 14 flask and 15 laboratory experiments were completed. Flask experiments involved the mixing of food with dishwasher detergent in water for a 12-min reaction period, and were intended to identify chemicals and relative levels of those chemicals that may form from dishwasher usage with different food groups. Liquid concentrations of chloroform ranged from 1 to 41 mg/l. Laboratory experiments involved collection of liquid and gas samples over the course of an operating cycle with an actual residential dishwasher. Background concentrations of chloroform in the water supply were generally between 0 and 10 microg/l; liquid chloroform levels in the wash cycle were typically at least 50 microg/l. Chloroform concentrations were as high as 20 microg/l in the dishwasher headspace. Using mass balance equations for a typical residential house and laboratory results from this research, predicted concentrations resulting from dishwasher usage were similar to typical background concentrations in residential dwellings.


Assuntos
Poluição do Ar em Ambientes Fechados , Detergentes/química , Trialometanos , Poluição do Ar em Ambientes Fechados/análise , Utensílios Domésticos , Humanos , Poluentes Químicos da Água
10.
Am J Primatol ; 20(2): 83-94, 1990.
Artigo em Inglês | MEDLINE | ID: mdl-31963993

RESUMO

Hand preference was assessed in 12 gorillas (Gorilla gorilla gorilla), 13 orang-utans (Pongo pygmaeus abelii), and 9 gibbons (Hylobates lar) by using a floor retrieval task and a mesh retrieval task. Hand preference was also assessed in 8 gorillas and 8 orang-utans by using a task involving the unfastening of a hasp. A bipedal requirement during testing (mesh retrieval task) facilitated detection of hand preferences. A significant left-hand preference was found for the gibbons with 6 of 6 gibbons preferring their left hand on the mesh retrieval task. Similarly, a significant right-hand preference was found for the gorillas with 10 of 12 gorillas preferring their right hand on the mesh retrieval task. The data for the orang-utan suggest a bimodal distribution on all tasks. Since the gibbon and gorilla in the wild engage in bipedal locomotion more frequently than the orangutan, one possible interpretation for these results correlates the degree of bipedal behavior of a species in its natural environment with its readiness to exhibit a unilateral population-level hand preference.

11.
J Air Waste Manag Assoc ; 54(3): 367-77, 2004 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-15061618

RESUMO

Consumer products can emit significant quantities of terpenes, which can react with ozone (O3). Resulting byproducts include compounds with low vapor pressures that contribute to the growth of secondary organic aerosols (SOAs). The focus of this study was to evaluate the potential for SOA growth, in the presence of O3, following the use of a lime-scented liquid air freshener, a pine-scented solid air freshener, a lemon-scented general-purpose cleaner, a wood floor cleaner, and a perfume. Two chamber experiments were performed for each of these five terpene-containing agents, one at an elevated O3 concentration and-the other at a lower O3 concentration. Particle number and mass concentrations increased and O3 concentrations decreased during each experiment. Experiments with terpene-based air fresheners produced the highest increases in particle number and mass concentrations. The results of this study clearly demonstrate that homogeneous reactions between O3 and terpenes from various consumer products can lead to increases in fine particle mass concentrations when these products are used indoors. Particle increases can occur during periods of elevated outdoor O3 concentrations or indoor O3 generation, coupled with elevated terpene releases. Human exposure to fine particles can be reduced by minimizing indoor terpene concentrations or O3 concentrations.


Assuntos
Poluição do Ar em Ambientes Fechados/análise , Produtos Domésticos , Ozônio/química , Terpenos/química , Monitoramento Ambiental , Tamanho da Partícula , Estações do Ano , Volatilização
13.
Environ Sci Technol ; 40(1): 163-9, 2006 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-16433347

RESUMO

Emission rates, decay rates, and cooking durations are reported from continuous PM2.5 (particulate matter less than 2.5 microm) concentrations measured using personal DataRam nephelometers (1-min time resolution) from the Research Triangle Park (RTP) PM panel study. The study (n = 37 participants) included monitoring for 7 consecutive days in each of four consecutive seasons (summer 2000 through spring 2001). Cooking episodes (n = 411) were selected using time-activity diaries and criteria for cooking event duration, peak concentration level, and decay curve quality. Averaged across all cooking events, mean source strengths were 36 mg/min (median = 12 mg/min), mean decay rates were 0.27 h(-1) (0.17 h(-1)), and mean cooking durations were 11 min (7 min). Cooking events were further separated into one of seven categories representing cooking method: burned food (oven cooking, toaster, or stovetop cooking), grilling, microwave, toaster oven, frying, oven cooking, and stovetop cooking. The highest mean source strengths were identified from burned food (mean = 470 mg/min), grilling (173 mg/min), and frying (60 mg/ min); differences between both burned food and grilling compared with all remaining cooking methods were statistically significant. Source strengths, decay rates, and cooking durations were also compared by season and typical meal times (8:00 a.m., 12:00 p.m., and 6:00 p.m.); differences were generally not statistically significant for these cases. Mean source strengths using electric appliances were typically a factor of 2 greater than those using gas appliances for identical cooking methods (frying, oven cooking, or stovetop cooking), although in all cases the difference was not statistically significant. Distributions of source strengths and decay rates for cooking events were also compared among study subjects to assess both within- and between-subject variability. Each subject's distribution of source strengths during the study tended to be either lower than the overall study average (and with lower variability) or higher than the overall study average (and with higher variability). No relationships could be found between source strength and either subject characteristics (age, gender, employment status) or home characteristic (daily air exchange rate). The large number of cooking events and the broad range of cooking activities included in this analysis makes the reported distributions of PM2.5 source strengths useful for probabilistic exposure modeling even though the study population was limited.


Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar em Ambientes Fechados/análise , Culinária , Exposição Ambiental/legislação & jurisprudência , Monitoramento Ambiental , Humanos , Tamanho da Partícula , Medição de Risco , Estações do Ano , Ventilação
14.
J Am Chem Soc ; 128(41): 13625-33, 2006 Oct 18.
Artigo em Inglês | MEDLINE | ID: mdl-17031977

RESUMO

A versatile method for preparing amorphous degradable elastomers with tunable properties that can be easily fabricated into a wide variety of shape-specific devices was investigated. Completely amorphous, liquid poly(ester ether) prepolymers with number-average molecular weights between 4 and 6 x 10(3) g/mol were prepared via condensation polymerization. These liquid prepolymers were then thermally cross-linked to form degradable elastomeric structures. The ability to vary the composition of these liquid prepolymers allows for easy control of the mechanical and degradation properties of the resulting elastomeric structures. Materials can be designed to completely degrade in vitro over a range of 30 days to 6 months, while the Young's modulus can be varied over 3 orders of magnitude (G = 0.02-20 MPa). Also, the liquid nature of these prepolymers makes them amenable to a wide variety of fabrication techniques. Using traditional and modified imprint lithography techniques, we have fabricated devices that demonstrate a wide variety of biologically applicable topologies, which could easily be extended to fabricate devices with more complex geometries. Until now, no method has combined this ease and speed of fabrication with the ability to control the mechanical and degradation properties of the resulting elastomers over such a broad range.


Assuntos
Materiais Biocompatíveis/síntese química , Elastômeros/síntese química , Poliésteres/química , Reagentes de Ligações Cruzadas/química , Teste de Materiais , Microscopia Eletrônica de Varredura , Modelos Químicos , Peso Molecular , Temperatura , Fatores de Tempo
15.
Environ Sci Technol ; 38(17): 4465-73, 2004 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-15461151

RESUMO

Concentrations of elemental carbon (EC), organic carbon matter (OM), particulate matter less than 2.5 microm (PM2.5), reconstructed soil, trace element oxides, and sulfate are reported from four locations near the World Trade Center (WTC) complex for airborne particulate matter (PM) samples collected from September 2001 through January 2002. Across the four sampling sites, daily mean concentrations ranged from 1.5 to 6.8 microg/m3 for EC, from 10.2 to 31.4 microg/m3 for OM, and from 22.6 to 66.2 microg/m3 for PM2.5. Highest concentrations of PM species were generally measured north and west of the WTC complex. Total carbon matter and sulfate constituted the largest fraction of reconstructed PM2.5 concentrations. Concentrations of PM species across all sites decreased from the period when fires were present at the WTC complex (before December 19, 2001) to the period after the fires. Averaged over all sites, concentrations decreased by 25.6 microg/m3 for PM2.5, 2.7 microg/m3 for EC, and 9.2 microg/m3 for OM from the fire period to after fire period.


Assuntos
Poluentes Atmosféricos/química , Carbono/análise , Poeira/análise , Monitoramento Ambiental/estatística & dados numéricos , Poluentes Atmosféricos/análise , Exposição Ambiental/estatística & dados numéricos , Explosões/estatística & dados numéricos , Incêndios/estatística & dados numéricos , Cidade de Nova Iorque , Tamanho da Partícula , Solo/análise , Sulfatos/análise , Terrorismo , Fatores de Tempo , Oligoelementos/análise
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