Large chocked lagoon as a barrier for river-sea flux of dissolved pollutants: Case study of the Azov Sea and the Black Sea.

The Don River is among the largest rivers in the Eastern Europe and is heavily polluted. This river inflows into small and semi-isolated Sea of Azov, which is connected with the Black Sea by a narrow strait. Generally, the Sea of Azov is a large choked lagoon, which serves as a barrier for river-borne constituents. Using numerical modeling, we reveal that presence of the choked lagoon significantly slows down the estuary-seawater flux of dissolved pollutants and slackens its discharge-induced seasonal variability. In particular, the Sea of Azov delays the 5 % and 95 % of the total flux of riverine pollution to the Black Sea by 9 and 36 months, respectively. The obtained results are important for assessment the influence of background and emergency pollution accidents at the Don River on water quality in the study region. Moreover, these results could be applied to many other chocked lagoons in the World Ocean.

Intense zonal freshwater transport in the Eurasian Arctic during ice-covered season revealed by in situ measurements.

The Kara Sea receives ~ 1/3 of total freshwater discharge to the Arctic Ocean, mainly from the large Ob and Yenisei rivers. The Ob-Yenisei plume covers wide area in the central part of the Kara Sea during ice-free season (June-October) and accumulates ~ 1000 km3 of freshwater volume. In late autumn, the Kara Sea becomes covered by ice, which hinders in situ measurements at this area. As a result, the fate of the Ob-Yenisei plume below sea ice during winter and spring remains unclear. In this study, we report multiple in situ measurements performed in the Kara Sea shortly before and during ice-covered season. We demonstrate that late autumn convection in the plume shortly before ice formation significantly reduces friction between the plume and the subjacent sea. The subsequent formation of solid sea ice coverage isolates the plume from wind forcing. These two factors precondition the Ob-Yenisei plume to form an intense buoyancy-driven coastal current below sea ice. As a result, the plume advects eastward to the Laptev Sea through the Vilkitsky Strait during several months in November-February. Eventually, by late winter this huge freshwater volume disappears from the Kara Sea and contributes to freshwater content of the Laptev Sea. The obtained result improves our understanding of freshwater balance of the Kara and Laptev seas, as well as provides an important insight into the large-scale freshwater transport in the Eurasian Arctic, which remain largely unknown during ice-covered season.

Production of Fluorescent Dissolved Organic Matter by Microalgae Strains from the Ob and Yenisei Gulfs (Siberia).

Dissolved organic matter (DOM) is an important component of aquatic environments; it plays a key role in the biogeochemical cycles of many chemical elements. Using excitation-emission matrix fluorescence spectroscopy, we examined the fluorescent fraction of DOM (FDOM) produced at the stationary phase of growth of five strains of microalgae sampled and isolated from the Ob and Yenisei gulfs. Based on the morphological and molecular descriptions, the strains were identified as diatoms (Asterionella formosa, Fragilaria cf. crotonensis, and Stephanodiscus hantzschii), green microalgae (Desmodesmus armatus), and yellow-green microalgae (Tribonema cf. minus). Three fluorescent components were validated in parallel factor analysis (PARAFAC): one of them was characterized by protein-like fluorescence (similar to peak T), two others, by humic-like fluorescence (peaks A and C). The portion of fluorescence intensity of humic compounds (peak A) to the total fluorescence intensity was the lowest (27 ± 5%) and showed little variation between species. Protein-like fluorescence was most intense (45 ± 16%), but along with humic-like fluorescence with emission maximum at 470 nm (28 ± 14%), varied considerably for different algae strains. The direct optical investigation of FDOM produced during the cultivation of the studied algae strains confirms the possibility of autochthonous production of humic-like FDOM in the Arctic shelf regions.

Distribution of floating marine macro-litter in relation to oceanographic characteristics in the Russian Arctic Seas.

The main objectives of this work were the acquisition of new data on floating marine macro litter (FMML) and natural floating objects in the Arctic seas, an initial assessment of the level of pollution by FMML and an analysis of potential sources. The results of this study present the first data on FMML distribution in Russian Arctic shelf seas in relation to oceanographic conditions (i.e. position of water masses of different origin as described by temperature, salinity, dissolved oxygen and pH). The main finding of this study is that FMML was found only in the water of Atlantic origin, inflowing from the Barents Sea, where FMML average density on the observed transects was 0.92 items/ km2. Eastern parts of the study, Kara Sea, Laptev Sea and East Siberian Sea were practically free from FMML. No input from rivers was detected, at least in autumn, when the observations were performed.

Fate of river-borne floating litter during the flooding event in the northeastern part of the Black Sea in October 2018.

This study is focused on delivery and fate of floating marine litter (FML) carried by rivers to coastal sea. We examine a large flooding event which happened in the northeastern part of the Black Sea in October 2018. A high resolution circulation model coupled with a Lagrangian particle model is applied to simulate transport of riverine FML in the coastal sea. During this flood multiple river plumes in the study area coalesced into one stripe of freshened water which occupied large segment of coastal sea along the shoreline. Riverine FML was transported within this stripe far off its sources in river mouths and remained arrested near the shore. As a result, approximately half of the discharged FML was washed ashore by the Stokes drift. FML, which remained in the sea, accumulated at convergence lines associated with large salinity gradients at the fronts between the river plumes and the ambient sea.