Rh-induced support transformation phenomena in titanate nanowire and nanotube catalysts.

High-aspect-ratio titanate nanotubes (NT) and nanowires (NW) were produced by the hydrothermal conversion of TiO2 at 400 K. The titanate morphology was studied by high-resolution transmission electron microscopy (HRTEM). The formation of ordered titanate nanoobjects depended on the time of conversion. Shorter synthesis times favored hollow nanotube production while during prolonged treatment the thermodynamically more stable nanowires were formed. Titanate nanotubes and nanowires were decorated by Rh nanoparticles. The structure and stability of titanate nanocomposites were studied by thermal gravimetric (TG), X-ray diffraction (XRD), X-ray photoelectron spectroscopic (XPS), Fourier transformed infrared spectroscopic (FTIR), and Raman spectroscopic methods. The nanowires preserve their structure up to 850 K, while the nanotubes start to recrystallize above 600 K. FTIR measurements showed that the water and hydroxyl content gradually decreased with increasing temperature in both cases. XPS data revealed the existence of high binding energy, highly dispersed Rh species on both supports. A small portion of Rh may participate in an ion exchange process. Support transformation phenomena were observed in Rh containing titanate nanowires and nanotubes. Rh decorated nanowires transform into the ß-TiO2 structure, whereas their pristine counterparts' recrystallize into anatase. The formation of anatase was dominant during the thermal annealing process in both acid treated and Rh decorated nanotubes. Transformation to anatase was enhanced in the presence of Rh. The average diameters Rh nanoparticles were 4.9 ± 1.4 and 2.8 ± 0.7 nm in the case of nanowires and nanotubes, respectively.

Metal loading determines the stabilization pathway for Co2+ in titanate nanowires: ion exchange vs. cluster formation.

Co nanoparticles were produced and characterized on protonated titanate nanowires. Co deposits were obtained after low-temperature decomposition of Co2(CO)8 on titanate nanostructures. The carbonylation was carried out by vapor-phase adsorption in a fluidized bed reactor and the decarbonylation processes were followed by FT-IR spectroscopy and microbalance combined with temperature programmed reaction mass spectrometry. The band gap of Co-decorated titanate nanostructures determined by UV-VIS diffuse reflectance spectroscopy decreased sharply from 3.14 eV to 2.41 eV with increasing Co content up to 2 wt%. The Co-decorated titanate morphology was characterized by high-resolution transmission electron microscopy (HRTEM) and electron diffraction (ED). The chemical environment of Co deposition was studied by photoelectron spectroscopy (XPS). A certain amount of cobalt underwent an ion exchange process. Higher cobalt loadings led to the formation of nanosized-dispersed particles complexed to oxygen vacancies. The average sizes were found to be mostly between 2 and 6 nm. This size distribution and the measured band gap could be favorable regimes for some important low-temperature thermal- and photo-induced catalytic reactions.