The effect of the combined addition of copper, lithium and sulphur on the formation of Portland cement clinker.

Both copper and lithium act as strong fluxes and lower the temperature of the clinker melt formation. Sulphur promotes the stabilisation of more hydraulically active modification of alite M1. It is expected that this combination could produce an alite clinker at significantly lower temperatures with high quality technological parameters. In this paper, the effect of combined oxides of copper, lithium and sulphur addition on the phase composition and clinker structure of Portland cement was investigated. The reference raw meal was prepared from common cement raw materials. Each of the mentioned oxides was added to the reference raw meal in two different concentrations, and 8 combinations were prepared. Chemically pure compounds (NH4)2SO4, CuO and Li2CO3 were used as a source of these oxides. The raw meals were burned to equilibrium at 1450°C. Their phase composition was determined by X-ray diffraction analysis, the microstructure was monitored by optical microscopy, and the microchemistry of the clinker phases was observed by electron microscopy with EDS analysis. It was found that in samples with high lithium or copper content, there is an increase in belite and free lime at the expense of alite. The combination of Cu + Li has the most negative effect, followed by Li alone and Cu alone. The higher SO3 content slightly offsets this negative effect.

Early hydration of C4AF with silica fume and its role on katoite composition.

C4AF is considered the least reactive main clinker phase, but its reactivity may be affected by adding supplementary cementitious materials (SCMs). Pure C4AF was synthesised in a laboratory furnace, and the role of silica fume without gypsum on its early hydration properties was monitored. Burning was carried out in four stages to achieve 99% purity of C4AF. Heat flow development was monitored by isothermal calorimetry over 7 days of hydration at 20°C and 40°C. The role of silica fume on hydrogarnet phase katoite (Ca3Al2(SiO4)3 - x(OH)4 x x = 1.5-3) formation during early hydration was studied. Rapid dissolution of C4AF, formation of metastable C-(A,F)-H and its conversion to C3(A, F)H6 was evidenced by isothermal calorimetry as a large exotherm. Changes in microstructure during early hydration were documented by SE micrographs, EDS point analyses, X-ray mapping and line scans by SEM-EDS. The phase composition was characterised by DTA-TGA and QXRD after 7 days of hydration. The katoite diffraction pattern is similar for the reference sample and sample with silica fume, but substitution in its structure can be revealed by X-ray microanalyses. The composition of katoite is variable due to the various extent of substitution of 4OH- by SiO4 4- due to silica fume.

Influence of Fumed Nanosilica on Ballistic Performance of UHPCs.

This research delves into the potential use of fumed nanosilica in ultra-high performance concrete for ballistic protection. First, the mechanical properties, slump flow, and specific gravity of UHPC with different contents of Aerosil 200 were determined. Then, calorimetric studies were conducted on these cement composites. Lastly, the differential efficiency factor and spalling area of UHPC with fumed nanosilica were determined. It was found out that the slump flow, the mechanical properties, and differential efficiency factor are slightly decreased by the addition of fumed nanosilica. However, the addition of the fumed nanosilica is beneficial in terms of the spalling area decrease and it is highly reactive during the induction period. Some of the results are supported by BSEM imaging.

Influence of Anticorrosive Surface Treatment of Steel Reinforcement Fibers on the Properties of Ultra-High Performance Cement Composite.

The influence on the bond between the steel fiber and the matrix of the anticorrosive treatments of steel used for concrete reinforcement is not yet fully understood. The topic of steel fiber treatment was not also studied clearly in terms of brass removal before. This paper deals with how the brass on the surface of steel fibers behaves in the UHPC matrix and how it affects its properties. The steel fibers were firstly modified with a number of surface treatments to remove brass on their surface. Some of the treatments have never been tried before for this purpose. Secondly, the surface of the fibers was analyzed by SEM, EDS, XRF, and stereomicroscopy. Lastly, the properties of the composites were analyzed. It was found out that the majority of brass on the surface of the fibers could be removed by mixture of NH3 and H2O2 with a ratio of 3:1 (v/v). It was also found out that the surface treatment slightly affects the mechanical properties, but it does that only by mechanical interlocking between the fiber and the matrix. No dissolution of the surface treatment was observed under the given conditions. According to the results, steel fibers without surface treatment should be used in UHPC if available.

Structural Changes of Sodium Warfarin in Tablets Affecting the Dissolution Profiles and Potential Safety of Generic Substitution.

At present, the risk of generic substitutions in warfarin tablets is still being discussed. The aim of this study was to assess whether API interactions with commonly used excipients may affect the safety of generic replacement of warfarin sodium tablets. These interactions were observed during an accelerated stability study, and the effect of the warfarin solid phase (crystalline/amorphous form) as well as the API particle size distribution was studied. Commercial tablets and prepared tablets containing crystalline warfarin or amorphous warfarin were used. In addition, binary mixtures of warfarin with various excipients were prepared. The structural changes before and after the stability study were monitored by dissolution test in different media, solid-state NMR spectroscopy and Raman microscopy. During the stability study, the conversion of the sodium in warfarin to its acid form was demonstrated by some excipients (e.g., calcium phosphate). This change in the solid phase of warfarin leads to significant changes in dissolution, especially with the different particle sizes of the APIs in the tablet. Thus, the choice of suitable excipients and particle sizes are critical factors influencing the safety of generic warfarin sodium tablets.