Oxygen nonstoichiometry and thermodynamic quantities of Gd and Cu doped misfit-layered calcium cobaltites.

Hyperstoichiometric (p-type) misfit-layered calcium cobaltites have been studied as components in various high-temperature electrochemical devices. Multiple studies have reported their applications or physical properties, but systematic studies on their defect structures and thermodynamic quantities are still insufficient. In this study, the oxygen nonstoichiometry and the electrical conductivity of Gd-Cu co-doped misfit cobalt oxide were measured as functions of temperature and oxygen partial pressure, along with thermodynamic quantities. The behavior of oxygen nonstoichiometry could not be explained by a defect structure assuming the ideal solution, as it showed a positive deviation in Raoult's law. The redesigned nonideal proposed defect structure, considering that the deviation originated from the high concentration of degenerate holes, could describe the oxygen nonstoichiometry precisely; and in this process, the values of , , Nv, , γh, and were quantitatively extracted. These values were compared with those obtained for the undoped system. The total electrical conductivity was measured using a dense specimen obtained via spark plasma sintering, and the anisotropic nature of the material was confirmed.

Three-dimensional assessment of the anterior and inferior loop of the inferior alveolar nerve using computed tomography images in patients with and without mandibular asymmetry.

BACKGROUND: The purpose of this study was to investigate the differences in configuration and dimensions of the anterior loop of the inferior alveolar nerve (ALIAN) in patients with and without mandibular asymmetry. METHOD: Preoperative computed tomography images of patients who had undergone orthognathic surgery from January 2016 to December 2018 at a single institution were analyzed. Subjects were classified into two groups as "Asymmetry group" and "Symmetry group". The distance from the most anterior and most inferior points of the ALIAN (IANant and IANinf) to the vertical and horizontal reference planes were measured (dAnt and dInf). The distance from IANant and IANinf to the mental foramen were also calculated (dAnt_MF and dInf_MF). The length of the mandibular body and symphysis area were measured. All measurements were analyzed using 3D analysis software. RESULTS: There were 57 total eligible subjects. In the Asymmetry group, dAnt and dAnt_MF on the non-deviated side were significantly longer than the deviated side (p < 0.001). dInf_MF on the non-deviated side was also significantly longer than the deviated side (p = 0.001). Mandibular body length was significantly longer on the non-deviated side (p < 0.001). There was no significant difference in length in the symphysis area (p = 0.623). In the Symmetry group, there was no difference between the left and right sides for all variables. CONCLUSION: In asymmetric patients, there is a difference tendency in the ALIAN between the deviated and non-deviated sides. In patients with mandibular asymmetry, this should be considered during surgery in the anterior mandible.

Is There a Difference in Condyle Position Changing Pattern Between Deviated and Non-Deviated Sides After Intraoral Vertical Ramus Osteotomy in Facial Asymmetry?

PURPOSE: The position changing pattern of the condyles after intraoral vertical ramus osteotomy (IVRO) on the deviated and non-deviated sides is not clearly known. This study was conducted to evaluate the changes in condylar position after IVRO in patients with facial asymmetry and to compare the deviated and non-deviated sides using computed tomography imaging. MATERIALS AND METHODS: This retrospective cohort study investigated patients with a diagnosis of mandibular prognathism with facial asymmetry who had undergone bilateral IVRO with Le Fort I osteotomy. Condylar positions were recorded on the non-deviated and deviated sides in the midaxial, midsagittal, and coronal planes at 3 time points using 3-dimensional analysis software: preoperatively (T1), at 6 months postoperatively (T2), and at 12 months postoperatively (T3). Linear and angular changes in condyle position were measured and analyzed between T1, T2, and T3. Reliability and comparative analyses were conducted. RESULTS: Thirty-two patients were involved in this study. At T2, the most superior point of the condyle moved to 1.15 ± 0.24 mm (inferiorly) and 0.88 ± 0.23 mm (anteriorly) on the deviated side (P = .0002 and P = .0005, respectively) and to 0.99 ± 0.25 mm (inferiorly) and 1.08 ± 0.34 mm (anteriorly) on the non-deviated side, showing significant differences (P < .0001 and P = .0007, respectively) compared with T1. The condyle position showed a tendency to recover to its original position by T3. However, there were no statistically significant differences between T2 and T3 (P > .05). Furthermore, there were no statistically significant differences between the deviated and non-deviated sides over the entire follow-up period (P > .05). CONCLUSIONS: The condyles did not completely recover to their preoperative positions until 12 months postoperatively. There was no significant difference between the deviated and non-deviated sides in mandibular prognathism with facial asymmetry.

Ionic-Liquid-Based Heterogeneous Covalent Triazine Framework Cobalt Catalyst for the Direct Synthesis of Methyl 3-Hydroxybutyrate from Propylene Oxide.

ß-Hydroxy esters are considered as potential building blocks for the production of fine chemicals and potential drug molecules in various industries. Developing an efficient and recyclable catalyst for the synthesis of ß-hydroxy esters is challenging. Here we report the first ionic-liquid-based heterogenized cobalt catalyst, [imidazolium-CTF][Co(CO)4], for the direct ring-opening carbonylation of propylene oxide to methyl 3-hydroxybutyrate (MHB) with 86% selectivity (>99% conversion).

Effects of thread size in the implant neck area on peri-implant hard and soft tissues: an animal study.

OBJECTIVES: The aim of this animal study was to examine the effects of thread size in the implant neck area on peri-implant tissues in terms of BIC and hard- and soft-tissue dimensions. MATERIALS AND METHODS: Six Beagle dogs received experimental implants in the mandible 3 month after the removal of premolars and first molars (P2, P3, P4, and M1). Two different types of implants were installed in each animal: Anyone microthread(®) as Group 1 and Anyone(®) as Group 2. Resonance frequency test, intraoral radiography, micro-CT, and histomorphometry were used to evaluate peri-implant tissue after implantation periods of 4 and 8 weeks. RESULTS: No remarkable complication was observed during the healing period in either group. Resonance frequency testing revealed no significant difference between groups. In radiographic evaluation, Group 2 showed more bone loss than Group 1. However, this difference was not statistically significant. In the micro-CT analysis, BIC and BIV values and soft-tissue height were not significant in both groups. Histological analysis revealed no significant difference in BIC ratio, bone density, or bone loss between groups. However, soft-tissue height was significantly greater in Group 2 than in Group 1 (P = 0.0004). CONCLUSION: No difference in peri-implant hard or soft tissues was observed according to thread size in the implant neck area.

The effects of off-axial loading on periimplant marginal bone loss in a single implant.

STATEMENT OF PROBLEM: A discrepancy between crown width and implant width may contribute to potential bending overload. PURPOSE: The purpose of this study was to evaluate the influence of the crown width-fixture width ratio on crestal bone loss around single dental implants placed in the first molar area. MATERIAL AND METHODS: Seventy-six participants (37 men and 39 women; age range, 25-83 years; mean age [standard deviation], 56.3 ±10.6 years) were selected from individuals who were treated with single tooth implants between May 2004 and December 2009 at the Department of Periodontology, Gangnam Severance Dental Hospital. The marginal bone-level change and gingival parameters (modified plaque index and modified sulcus bleeding index) of the periimplant soft tissue were assessed 1 year after functional loading. The perpendicular distances from the vertical axis of each fixture to the most distal aspect of the crown and most mesial aspect of the crown were measured in the periapical radiographic view. RESULTS: No statistically significant relationship was found between crown width-fixture width ratio and the 1-year bone-level change (Pearson correlation, P=.06; Spearman rank test, P=.14). No statistically significant differences in marginal bone-level change were found between axial and nonaxial loading implants (2 independent samples t test; P=.19). The bone-level change for the surface adjacent and distant to the cantilever was not statistically significant (paired t test; P=.10). CONCLUSION: From this study, it may be concluded that off-axial loading that results from a high crown width-fixture width ratio does not increase the risk for periimplant marginal bone loss after 1-year functional loading.

Change in masticatory ability with the implant restoration of second molars.

STATEMENT OF PROBLEM: Controversy exists as to whether missing second molars should be replaced to restore masticatory ability. PURPOSE: The purpose of this study was to analyze the alteration in masticatory ability associated with the implant restoration of the second molar; the subjective effect of implant treatment on the participant was also assessed. MATERIAL AND METHODS: Twenty-one individuals (13 men and 8 women) participated. Masticatory ability was recorded before the cementation of implant-supported single crowns, immediately after cementation, and 1 month after cementation. The occlusal load (Pa), the load-bearing contact area (mm(2)), and the maximum occlusal force (N) were calculated. A subjective evaluation of masticatory ability was conducted before treatment and 1 month after treatment through the use of a questionnaire to evaluate chewing difficulties and global satisfaction with treatment. The Wilcoxon signed rank test was used to analyze the difference in scores. RESULTS: The load-bearing contact area, maximum occlusal force, and participant satisfaction were found to increase significantly 1 month after the cementation of implant-supported single crowns. The restoration of the second molar with an implant increased both objective masticatory ability and subjective satisfaction 1 month after cementation of the implant-supported single crowns. CONCLUSIONS: Patients presenting with a missing second molar may benefit from replacement with implant-supported crowns. Longer study periods and larger sample populations are needed to obtain more definitive results.

Protocol to operate a large-scale CO2 hydrogenation process for formic acid production.

Formic acid is a viable product of CO2 utilization. Here, we present a protocol for designing and operating a pilot-scale formic acid production plant with a 10 kg/day capacity produced via CO2 hydrogenation. We describe the essential process specifications required for successful operation, including prevention of corrosion and formic acid decomposition. We then detail procedures for steady-state operation of the individual units. This protocol provides the necessary information for further scale-up and commercialization of the CO2 hydrogenation process. For complete details on the use and execution of this protocol, please refer to Kim et al.1.

Effect of thread size on the implant neck area: preliminary results at 1 year of function.

OBJECTIVES: To evaluate and compare the effect of the coronal thread size on the marginal bone loss around the fixtures, when both implants were provided with threads to the top of fixture. MATERIALS AND METHODS: Two groups of implants, one with a macro-thread to the top of the fixture (A) and the other with a micro-thread to the top of the fixture (B), were placed adjacent to each other in the partially edentulous areas of 20 patients. Bone loss around each implant was analyzed after 1 year of functional loading. The bone losses after loading were compared using Wilcoxon's signed-rank test. RESULTS: The mean marginal bone losses (A, 0.154 ± 0.144 mm; B, 0.125 ± 0.136 mm) were not statistically significant between the two groups (P = 0.669). CONCLUSIONS: There was no significant difference between implant with macro- and micro-neck thread in terms of marginal bone loss after 1 year of loading.

Toward economical application of carbon capture and utilization technology with near-zero carbon emission.

Carbon capture and utilization technology has been studied for its practical ability to reduce CO2 emissions and enable economical chemical production. The main challenge of this technology is that a large amount of thermal energy must be provided to supply high-purity CO2 and purify the product. Herein, we propose a new concept called reaction swing absorption, which produces synthesis gas (syngas) with net-zero CO2 emission through direct electrochemical CO2 reduction in a newly proposed amine solution, triethylamine. Experimental investigations show high CO2 absorption rates (>84%) of triethylamine from low CO2 concentrated flue gas. In addition, the CO Faradaic efficiency in a triethylamine supplied membrane electrode assembly electrolyzer is approximately 30% (@-200 mA cm-2), twice higher than those in conventional alkanolamine solvents. Based on the experimental results and rigorous process modeling, we reveal that reaction swing absorption produces high pressure syngas at a reasonable cost with negligible CO2 emissions. This system provides a fundamental solution for the CO2 crossover and low system stability of electrochemical CO2 reduction.

Degradation Mechanisms of Solid Oxide Fuel Cells under Various Thermal Cycling Conditions.

A critical issue to tackle before successful commercialization of solid oxide fuel cells (SOFCs) can be achieved is the long-term thermal stability required for SOFCs to operate reliably without significant performance degradation despite enduring thermal cycling. In this work, the impact of thermal cycling on the durability of NiO-yttria-stabilized zirconia-based anode-supported cells is studied using three different heating/cooling rates (1, 2, and 5 °C min-1) as the temperature fluctuated between 400 and 700 °C. Our experiments simulate time periods when power from SOFCs is not required (e.g., as might occur at night or during an emergency shutdown). The decay ratios of the cell voltages are 8.8% (82 µV h-1) and 19.1% (187 µV h-1) after thermal cycling testing at heating/cooling rates of 1 and 5 °C min-1, respectively, over a period of 1000 h. The results indicate SOFCs that undergo rapid thermal cycling experience much greater performance degradation than cells that experience slow heating/cooling rates. The changes in total resistance for thermally cycled cells are determined by measuring the Rpol of the electrodes (whereas the ohmic resistances of the cells remain unchanged from their initial value), signifying that electrode deterioration is the main degradation mechanism for SOFCs under thermal cycling. In particular, fast thermal cycling leads to severe degradation in the anode part of SOFCs with substantial agglomeration and depletion of Ni particles seen in our characterizations with field emission-scanning electron microscopy and electron probe microanalysis. In addition, the mean particle size in the cathode after thermal cycling testing increases from 0.104 to 0.201 µm for the 5 °C min-1 cell. Further, the presence of Sr-enriched regions is more significant in the La0.6Sr0.4Co0.2Fe0.8O3-δ cathode after fast thermally cycled SOFCs.

Utilizing the Intrinsic Thermal Instability of Swedenborgite Structured YBaCo4O7+δ as an Opportunity for Material Engineering in Lithium-Ion Batteries by Er and Ga Co-Doping Processes.

We firstly introduce Er and Ga co-doped swedenborgite-structured YBaCo4O7+δ (YBC) as a cathode-active material in lithium-ion batteries (LIBs), aiming at converting the phase instability of YBC at high temperatures into a strategic way of enhancing the structural stability of layered cathode-active materials. Our recent publication reported that Y0.8Er0.2BaCo3.2Ga0.8O7+δ (YEBCG) showed excellent phase stability compared to YBC in a fuel cell operating condition. By contrast, the feasibility of the LiCoO2 (LCO) phase, which is derived from swedenborgite-structured YBC-based materials, as a LIB cathode-active material is investigated and the effects of co-doping with the Er and Ga ions on the structural and electrochemical properties of Li-intercalated YBC are systemically studied. The intrinsic swedenborgite structure of YBC-based materials with tetrahedrally coordinated Co2+/Co3+ are partially transformed into octahedrally coordinated Co3+, resulting in the formation of an LCO layered structure with a space group of R-3m that can work as a Li-ion migration path. Li-intercalated YEBCG (Li[YEBCG]) shows effective suppression of structural phase transition during cycling, leading to the enhancement of LIB performance in Coulombic efficiency, capacity retention, and rate capability. The galvanostatic intermittent titration technique, cyclic voltammetry and electrochemical impedance spectroscopy are performed to elucidate the enhanced phase stability of Li[YEBCG].

Effect of conical configuration of fixture on the maintenance of marginal bone level: preliminary results at 1 year of function.

OBJECTIVES: To evaluate and to compare the effect of the conical neck design on marginal bone loss around the fixtures, when both implants were provided with micro-threads to the top of the fixture. MATERIALS AND METHODS: Two types of implant, one with a straight shape (S) and the other with a conical neck design (C) provided with a retentive element to the top of the fixture, were placed adjacent to each other in the partially edentulous areas of 12 patients. Bone loss around each implant was analyzed after 1 year of functional loading. The bone losses after loading were compared using Wilcoxon's signed-rank test. RESULTS: The mean marginal bone losses (S, 0.05 + or - 0.09 mm; C, 0.07 + or - 0.14 mm) were not statistically significant between the two groups (P=0.578). CONCLUSIONS: There was no significant difference between conical and straight neck implants in terms of marginal bone loss after 1 year of loading.

An Efficient and Practical System for the Synthesis of N,N-Dimethylformamide by CO2 Hydrogenation using a Heterogeneous Ru Catalyst: From Batch to Continuous Flow.

In the context of CO2 utilization, a number of CO2 conversion methods have been identified in laboratory-scale research; however, only a very few transformations have been successfully scaled up and implemented industrially. The main bottleneck in realizing industrial application of these CO2 conversions is the lack of industrially viable catalytic systems and the need for practically implementable process developments. In this study, a simple, highly efficient and recyclable ruthenium-grafted bisphosphine-based porous organic polymer (Ru@PP-POP) catalyst has been developed for the hydrogenation of CO2 to N,N-dimethylformamide, which affords a highest ever turnover number of 160 000 and an initial turnover frequency of 29 000 h-1 in a batch process. The catalyst is successfully applied in a trickle-bed reactor and utilized in an industrially feasible continuous-flow process with an excellent durability and productivity of 915 mmol h-1 gRu -1 .

Influence of early cover screw exposure on crestal bone loss around implants: intraindividual comparison of bone level at exposed and non-exposed implants.

BACKGROUND: The objective of this study was to evaluate the influence of early exposure of the cover screw on crestal bone loss around implants. METHODS: The study population consisted of 19 patients who were treated with dental implants placed using a two-stage surgical protocol and had early exposed and non-exposed implants (20 early exposed and 20 non-exposed implants). The crestal bone loss at exposed and non-exposed implants in each patient was evaluated with a periapical radiograph taken at the first surgery and at suprastructure insertion using a computerized image-analysis system. The bone loss was compared using the Wilcoxon signed-rank test. RESULTS: The mean crestal bone loss at exposed implants was 0.40 +/- 0.53 mm, and it was 0.18 +/- 0.26 mm at non-exposed implants. The Wilcoxon signed-rank test revealed a statistically significant difference in crestal bone loss between exposed and non-exposed implants in the same patient (P = 0.02). CONCLUSIONS: The early exposure of the cover screw that results in breakdown of the mucosal seal seems to accelerate early peri-implant crestal bone loss. Periodic follow-up after the first surgery may be critical for minimizing the influence of early exposure.

Influence of the tooth- and implant-side marginal bone level on the interproximal papilla dimension in a single implant with a microthread, conical seal, and platform-switched design.

BACKGROUND: The purpose of the present study was to investigate whether bone level on the tooth side was the single dominant factor on the dimension of an interproximal papilla around single-tooth restorations made on a microthread, conical seal, and platform-switched design implant. METHODS: Periapical radiographs were taken of 17 patients, each of whom was treated with a single implant. The bone levels on the tooth (Dt) and implant (Di) sides were recorded. The dimension of the papilla (Ph) was measured as the shortest distance from the top of the papilla to the crestal bone. The marginal bone levels of the implants were also measured. The Pearson correlation coefficient was used to correlate the variables, and a regression analysis was used to determine whether Di or Dt had a significant (P <0.05) influence on Ph. RESULTS: A positive correlation existed between Ph and Di (r = 0.413; P = 0.023) and between Ph and Dt (r = 0.830; P <0.0001). However, only Dt had a significant influence on Ph. CONCLUSION: Dt is the dominant factor that influences the interproximal soft tissue dimension between a natural tooth and a single implant with a microthread, conical seal, and platform-switched design.

Comparison of interproximal soft tissue height for single implants and contra-lateral natural teeth.

OBJECTIVE: To compare the interproximal soft tissue dimensions adjacent to single implant restorations in the premolar-molar position with those adjacent to the contra-lateral natural teeth. MATERIAL AND METHODS: Twenty-five patients with a single-tooth implant in premolar-molar position and healthy contra-lateral teeth were enrolled in this retrospective cross-sectional study. The reason for the extraction was periodontitis. Radiographs were used to measure the shortest distance from the tip of the papilla to the crestal bone in single implants and contra-lateral teeth. A Wilcoxon's signed-ranks test was used to examine the differences between the interproximal soft tissue dimensions adjacent to the single-tooth implant restorations (IS-STI) from those of the contra-lateral natural teeth (IS-NT). RESULTS: We found no significant difference between the mesial IS-STI and the mesial IS-NT (3.28+/-0.83/3.31+/-0.62; P=0.861), or between the distal IS-STI and the distal IS-NT (3.09+/-0.72/3.3+/-0.63; P=0.263). CONCLUSIONS: The interproximal soft tissue height adjacent to single-implant-supported restorations in the premolar-molar position is similar to that adjacent to the contra-lateral natural teeth.

Three-dimensional computed tomography evaluation of craniofacial characteristics according to lateral deviation of chin.

BACKGROUND: The relationship between the lateral deviation of chin and the upper and middle facial third asymmetry is still controversial. The purpose of this study is to evaluate the correlation of upper and middle facial third asymmetry with lateral deviation of chin using 3-dimensional computed tomography. The study was conducted on patients who underwent orthognathic surgery from January 2016 to August 2017. A total of 40 patients were included in this retrospective study. A spiral scanner was used to obtain the 3-dimensional computed tomography scans. The landmarks were assigned on the reconstructed 3-dimensional images, and their locations were verified on the axial, midsagittal, and coronal slices. The Pearson correlation analysis was performed to evaluate the correlation between chin deviation and difference between the measurements of distances in paired craniofacial structures. Statistical analysis was performed at a significance level of 5%. RESULTS: In mandible, the degree of chin deviation was correlated with the mandibular length and mandibular body length. Mandibular length and mandibular body length are shorter on the deviated-chin side compared to that on the non-deviated side (mandibular length, r = -0.897, p value < 0.001; mandibular body length, r = -0.318, p value = 0.045). In the upper and middle facial thirds, the degree of chin deviation was correlated with the vertical asymmetry of the glenoid fossa and zygonion. Glenoid fossa and zygonion are superior on the deviated-chin side than on the non-deviated side (glenoid fossa, r = 0.317, p value = 0.046; zygonion, r = 0.357, p value = 0.024). CONCLUSION: Lateral deviation of chin is correlated with upper and middle facial third asymmetry as well as lower facial third asymmetry. As a result, treatment planning in patients with chin deviation should involve a careful evaluation of the asymmetry of the upper and middle facial thirds to ensure complete patient satisfaction.

Modified difficult index adding extremely difficult for fully impacted mandibular third molar extraction.

OBJECTIVES: The aim of this study was to evaluate the validity of the existing classification and difficulty index of impacted mandibular third molars in clinical situations and propose a more practical classification system. MATERIALS AND METHODS: This study included 204 impacted mandibular third molars in 154 patients; panoramic x-ray images were obtained before tooth extraction. Factors including age, sex, and pattern of impaction were investigated. All impacted third molars were classified and scored for spatial relationship (1-5 points), depth (1-4 points), and ramus relationship (1-3 points). All variables were measured twice by the same observer at a minimum interval of one month. Finally, the difficulty index was defined based on the total points scored as slightly difficult (3-4 points), moderately difficult (5-7 points), very difficult (8-10 points), and extremely difficult (11-12 points). RESULTS: The strength of agreement of the total points scored and difficulty index were 0.855 and 0.746, respectively. Most cases were classified as moderately difficult (73.0%). Although only 13 out of 204 cases (6.4%) were classified as extremely difficult, patients classified as extremely difficult were the oldest (P<0.05). CONCLUSION: For difficulty classification, the authors propose one more difficult category beyond the existing three-step difficulty index: the clinician should consider the patient's age in the difficulty index evaluation.

Effect of bisphosphonate on temporomandibular joint in osteopenia-induced rats by botulinum toxin A injection on masticatory muscle: a preliminary study.

BACKGROUND: Botulinum toxin injection on the masticatory muscle induces the osteopenic condition on the ipsilateral condyle. Bisphosphonate suppresses bone resorption and is used to treat osteopenic or osteoporotic condition. This study aimed to evaluate the effect of bisphosphonate administration on prevention of condylar resorption and botulinum toxin A-induced disuse osteopenia in rats. RESULTS: The volume of the condyle and bone volume/tissue volume (BV/TV, %) showed a strong tendency towards statistical significance (p = 0.052 and 0.058). Trabecular thickness (Tb.Th, mm) and trabecular number (Tb.N, 1/mm) were significantly smaller in the Botox group than in the other groups (p < 0.05). The volume of the condyle and BV/TV in the bisphosphonate 100 and bisphosphonate 200 groups showed similar values when compared with the control group. CONCLUSION: Bisphosphonate administration after botulinum toxin A injection in the masticatory muscles appears to prevent condyle resorption and botulinum toxin-induced disuse osteopenia in rats.