LGYSB:Nd─High-Performance Lasing in the Near-Infrared Region.

Three incongruent melting LawNdxGdyYzSc4-w-x-y-z(BO3)4 (LGYSB:Nd) crystals with different Y concentrations (z = 0.15, 0.05, and 0.025) have been grown by the Czochralski method for the first time. The LGYSB:Nd-type crystals exhibit an acentric structure similar to that of the natural mineral huntite CaMg3(CO3)4, with space group R32. The composition of the LGYSB:Nd_3 (z = 0.025) crystal grown from the starting melt composition La0.628Gd0.547Y0.025Nd0.05Sc2.75(BO3)4 was measured by inductively coupled plasma mass spectrometry method, and it was found to be La0.6794Gd0.4105Y0.0178Nd0.0381Sc2.8542(BO3)4. The transversal spatial distribution of the refractive index in the LGYSB:Nd_3 crystal was investigated. Third-order nonlinear optical susceptibility χ(3) of the LGYSB:Nd_3 crystal was determined from third-harmonic generation experiments with ultrashort (fs) laser pulses. The optical transmission spectrum was measured in the range of 200-2000 nm. The absorption cross-section at 808 nm in σ-polarization was determined to be 1.18 × 10-19 cm2 for the LGYSB:Nd_3 crystal. The 10K absorption spectra revealed that the Nd3+ ions occupy only La3+ cationic sites in the LGYSB host matrix. The emission cross-section at 1064 nm in σ-polarization was determined to be σem(σ) = 1.74 × 10-19 cm2 for the LGYSB:Nd_3 crystal. The fluorescence lifetime was found to be τ = 115 µs for all of the LGYSB:Nd crystals. The LGYSB:Nd_3 laser was operated at an emission wavelength of 1062 nm with very high slope efficiencies of ηsa = 0.74 and ηsa = 0.64 in quasi-cw and cw regimes, respectively.

Analysis of thickness influence on refractive index and absorption coefficient of zinc selenide thin films.

Linear optical constants of thermally evaporated Zinc Selenide thin films are computed on the account of only transmittance experimental data. The refractive index and absorption coefficient dispersions of Zinc Selenide layers of small to close-to-bulk (50 nm ÷ 800 nm) thicknesses deposited on transparent quartz substrates are reckoned over a broad wavelength spectrum (300 nm ÷ 2500 nm). To distinct optical thickness classes, distinct analytical approach methods are implemented to compute the refractive index dispersions (Sellmeier equations) and absorption coefficient values, with the substrate's influence accounted for. The implemented methods are exploited to infer the linear optical constants for practically any thin film thickness, with the premise that all considered films are deposited by a same deposition method. Although different deposition methods may lead to different thickness dependencies of the linear optical constants (thin films of the same material having to be regarded accordingly to the deposition process), the implemented approach stays. The study substantiates the possibility and uplifts the importance of prior knowledge on thickness dependent linear optical constants to design thin film structures with particular, custom features for linear and nonlinear photonics applications.

Measuring very low optical powers with a common camera.

We introduce a procedure to calibrate an inexpensive, commercial camera for optical power measurements. This allows the use of the camera as a very sensitive optical power meter that is able to measure powers down to the femtowatt level. A windowing technique, based on the selection of a region of interest from the total sensor area, is used to maintain a good signal-to-noise ratio over a large range of the measured optical powers. The increase of the exposure time of the camera shifts its detection limit to lower powers. Using this calibration procedure and the windowing technique, we measured 25 fW of optical power with a common complementary metal-oxide-semiconductor camera.

Single shot interferometric method for measuring the nonlinear refractive index.

In this paper we are introducing a new single shot method for measuring the nonlinear refractive index of materials in a simple interferometric pump-probe configuration. The theoretical model proposed for extracting the nonlinear refractive index from the experimental fringe pattern and the experimental configuration are presented and discussed. The results obtained by this method are in good agreement with that obtained on the same sample using the conventional Z-scan method.

Use of quasi-local photorefractive response to generated superficial self-written waveguides in lithium niobate.

We report the formation of surface self-written waveguides by means of surface pyrolitons in lithium niobate. By a specific orientation of the crystal axis the quasi-local slow photorefractive response of lithium niobate was used to induce a self-confined beam exactly at the crystal-air interface. The mode profile of the photo-induced waveguide is strongly asymmetric due to the interface presence.

DNA-CTMA Matrix Influence on Rhodamine 610 Light Emission in Thin Films.

Due to the increased application of lasers in different fields (industry, medicine, etc.), there is a growing need for new laser sources with good beam quality and variable emission wavelength. At the same time, for environmental reasons, the obtaining of novel eco-friendly active optical materials, such as those based on the deoxyribonucleic acid (DNA) biopolymer, with optimal light emission properties, is of high interest. The results obtained in this study of the temporal dependence of the transmittance and of the light emission in thin films of DNA-CTMA-Rhodamine 610 (at different Rhodamine concentrations) (DNA-CTMA-Rh610), when they are illuminated with continuous wave laser light at 532 nm (frequently used in the optical pumping of dye lasers), are presented and discussed. The transmittance results obtained for thin film samples are compared to those obtained for the DNA-CTMA-Rh610 solutions in butanol, from which the films have been made, and also with those obtained for Rh610 solutions in butanol with the same concentrations. The investigation was performed in order to assess the influence of the DNA-CTMA and of the green laser light at 532 nm wavelength on relevant chromophore properties such as light transmission and fluorescence emission. The results obtained revealed that the DNA-CTMA matrix has an active influence on the Rhodamine 610 emission, in the whole range of concentrations of the investigated samples.

Influence of continuous wave laser light at 532 nm on transmittance and on photoluminescence of DNA-CTMA-RhB solutions.

Recent results obtained in our experimental investigation on the influence of the illumination with continuous wave (c.w.) laser light at 532 nm on the transmittance at this wavelength and on the photoluminescence of the DNA-CTMA-RhB in butanol compound are reported. The temporal dependence of absorption changes induced by c. w. light at 532 nm in DNA-CTMA-RhB in butanol solution, and, for comparison, in RhB in butanol solution, is investigated experimentally and analyzed in order to assess the effect of DNA-CTMA on this light-induced process. The evolution in time of the peak's amplitude and wavelength of the photoluminescence spectra in solutions of DNA-CTMA-RhB in butanol, during their excitation with laser light at 532 nm wavelength has been also investigated and discussed.

Optical Limiting Properties of DNA Biopolymer Doped with Natural Dyes.

The high-power lasers have important implications for present and future light-based technologies; therefore, the protection measures against their high-intensity radiation are extremely important. Currently, a great deal of interest is directed towards the development of new nonlinear optical materials for passive optical limiters, which are used to protect the human eye and sensitive optical and optoelectronic devices from laser-induced damage. Biopolymers doped with natural dyes are emerging as a new class of optical materials with interesting photosensitive properties. In this paper, the optical limiting capability of deoxyribonucleic acid bio-polymer functionalized with Turmeric natural dye has been demonstrated for the first time, to the best of our knowledge. The experimental investigation of the optical limit has been done by the Intensity-scan method in the NIR spectral domain at the important telecommunication wavelength of 1550 nm, using ultrashort laser pulses (~120 fs). Several optical properties of this natural dye are presented and discussed. The values of the optical transmittance in the linear regime, the saturation intensity of the nonlinear transmittance curves, and the coefficient of the nonlinear absorption have been determined. The influence of the DNA biopolymer and natural dye concentration on the optical limiting properties of the investigated biomaterials is reported and discussed. The photostability and thermal stability of the investigated solutions have also been evaluated by monitoring the temporal decay of the normalized absorption spectra under illumination with UVA light and heating, respectively. Our results evidence the positive influence of the DNA, which embeds Turmeric natural dye, on the optical limiting functionality itself and on the photostability and thermal stability of this novel material. The performed study reveals the potential of the investigated novel biomaterial for applications in nonlinear photonics, in particular in optical limiting.

Ultrafast Third-Order Nonlinear Optical Response Excited by fs Laser Pulses at 1550 nm in GaN Crystals.

The ultrafast third-order optical nonlinearity of c-plane GaN crystal, excited by ultrashort (fs) high-repetition-rate laser pulses at 1550 nm, wavelength important for optical communications, is investigated for the first time by optical third-harmonic generation in non-phase-matching conditions. As the thermo-optic effect that can arise in the sample by cumulative thermal effects induced by high-repetition-rate laser pulses cannot be responsible for the third-harmonic generation, the ultrafast nonlinear optical effect of solely electronic origin is the only one involved in this process. The third-order nonlinear optical susceptibility of GaN crystal responsible for the third-harmonic generation process, an important indicative parameter for the potential use of this material in ultrafast photonic functionalities, is determined.

Graphene Oxide-Based Silico-Phosphate Composite Films for Optical Limiting of Ultrashort Near-Infrared Laser Pulses.

The development of graphene-based materials for optical limiting functionality is an active field of research. Optical limiting for femtosecond laser pulses in the infrared-B (IR-B) (1.4-3 µm) spectral domain has been investigated to a lesser extent than that for nanosecond, picosecond and femtosecond laser pulses at wavelengths up to 1.1 µm. Novel nonlinear optical materials, glassy graphene oxide (GO)-based silico-phosphate composites, were prepared, for the first time to our knowledge, by a convenient and low cost sol-gel method, as described in the paper, using tetraethyl orthosilicate (TEOS), H3PO4 and GO/reduced GO (rGO) as precursors. The characterisation of the GO/rGO silico-phosphate composite films was performed by spectroscopy (Fourier-transform infrared (FTIR), Ultraviolet-Visible-Near Infrared (UV-VIS-NIR) and Raman) and microscopy (atomic force microscopy (AFM) and scanning electron microscope (SEM)) techniques. H3PO4 was found to reduce the rGO dispersed in the precursor's solution with the formation of vertically agglomerated rGO sheets, uniformly distributed on the substrate surface. The capability of these novel graphene oxide-based materials for the optical limiting of femtosecond laser pulses at 1550 nm wavelength was demonstrated by intensity-scan experiments. The GO or rGO presence in the film, their concentrations, the composite films glassy matrix, and the film substrate influence the optical limiting performance of these novel materials and are discussed accordingly.