Pickering Emulsions of Thermotropic Liquid Crystals Stabilized by Amphiphilic Gold Nanoparticles.

We report emulsions of thermotropic liquid crystals (LCs) in water that are stabilized using amphiphilic gold nanoparticles (AuNPs) and retain their ability to respond to aqueous analytes for extended periods (e.g., up to 1 year after preparation). These LC emulsions exhibit exceptional colloidal stability that results from the adsorption of AuNPs that are functionalized with thiol-terminated poly(ethylene glycol) (PEG-thiol) and hexadecanethiol (C16-thiol) to LC droplet interfaces. These stabilized LC emulsions respond to the presence of model anionic (SDS), cationic (C12TAB), and nonionic (C12E4) surfactants in the surrounding aqueous media, as evidenced by ordering transitions in the LC droplets that can be readily observed using polarized light microscopy. Our results reveal significant differences in the sensitivity of the stabilized LC droplets toward each of these analytes. In particular, these stabilized droplets can detect the cationic C12TAB at concentrations that are lower than those required for bare LC droplets under similar experimental conditions (0.5 and 2 mM, respectively). These results demonstrate an enhanced sensitivity of the LC toward C12TAB when the PEG/C16-thiol-coated AuNPs are adsorbed at LC droplet interfaces. In contrast, the concentrations of SDS required to observe optical transformations in the stabilized LC droplets are higher than those required for the bare LC droplets, suggesting that the presence of the PEG/C16-thiol AuNPs reduces the sensitivity of the LC toward this analyte. When combined, our results show that this Pickering stabilization approach using amphiphilic AuNPs as stabilizing agents for LC-in-water emulsions provides a promising platform for developing LC droplet-based optical sensors with long-term colloidal stability as well as opportunities to tune the sensitivity and selectivity of the response to target aqueous analytes.

Environmentally Responsive Emulsions of Thermotropic Liquid Crystals with Exceptional Long-Term Stability and Enhanced Sensitivity to Aqueous Amphiphiles.

We report colloidally stable emulsions of thermotropic liquid crystals (LCs) that can detect the presence of amphiphilic analytes in aqueous environments. Our approach makes use of a Pickering stabilization strategy consisting of surfactant-nanoparticle complexes (SiO2/CnTAB, n = 8, 12, 16) that adsorb to aqueous/LC droplet interfaces. This strategy can stabilize LC emulsions against coalescence for at least 3 months. These stabilized LC emulsions also retain the ability to respond to the presence of model anionic, cationic, and nonionic amphiphiles (e.g., SDS, C12TAB, C12E4) in aqueous solutions by undergoing "bipolar-to-radial" changes in LC droplet configurations that can be readily observed and quantified using polarized light microscopy. Our results reveal these ordering transitions to depend upon the length of the hydrocarbon tail of the CnTAB surfactant used to form the stabilizing complexes. In general, increasing CnTAB surfactant tail length leads to droplets that respond at lower analyte concentrations, demonstrating that this Pickering stabilization strategy can be used to tune the sensitivities of the stabilized LC droplets. Finally, we demonstrate that these colloidally stable LC droplets can report the presence of rhamnolipid, a biosurfactant produced by the bacterial pathogen Pseudomonas aeruginosa. Overall, our results demonstrate that this Pickering stabilization strategy provides a useful tool for the design of LC droplet-based sensors with substantially improved colloidal stability and new strategies to tune their sensitivities. These advances could increase the potential practical utility of these responsive soft materials as platforms for the detection and reporting of chemical and biological analytes.

Spatial and Temporal Drug Usage Patterns in Wastewater Correlate with Socioeconomic and Demographic Indicators in Southern Nevada.

Evaluating drug use within populations in the United States poses significant challenges due to various social, ethical, and legal constraints, often impeding the collection of accurate and timely data. Here, we aimed to overcome these barriers by conducting a comprehensive analysis of drug consumption trends and measuring their association with socioeconomic and demographic factors. From May 2022 to April 2023, we analyzed 208 wastewater samples from eight sampling locations across six wastewater treatment plants in Southern Nevada, covering a population of 2.4 million residents with 50 million annual tourists. Using bi-weekly influent wastewater samples, we employed mass spectrometry to detect 39 analytes, including pharmaceuticals and personal care products (PPCPs) and high risk substances (HRS). Our results revealed a significant increase over time in the level of stimulants such as cocaine (pFDR=1.40×10-10) and opioids, particularly norfentanyl (pFDR =1.66×10-12), while PPCPs exhibited seasonal variation such as peak usage of DEET, an active ingredient in insect repellents, during the summer (pFDR =0.05). Wastewater from socioeconomically disadvantaged or rural areas, as determined by Area Deprivation Index (ADI) and Rural-Urban Commuting Area Codes (RUCA) scores, demonstrated distinct overall usage patterns, such as higher usage/concentration of HRS, including cocaine (p=0.05) and norfentanyl (p=1.64×10-5). Our approach offers a near real-time, comprehensive tool to assess drug consumption and personal care product usage at a community level, linking wastewater patterns to socioeconomic and demographic factors. This approach has the potential to significantly enhance public health monitoring strategies in the United States.

Sources of per- and polyfluoroalkyl substances in an arid, urban, wastewater-dominated watershed.

Per- and polyfluoroalkyl substances (PFAS) enter surface waters from various sources such as wastewater treatment plants, fire-fighting sites, and PFAS-producing and PFAS-using industries. The Las Vegas Wash in Southern Nevada of the United States (U.S.) conveys wastewater effluent from the Las Vegas metropolitan area to Lake Mead, a drinking water source for millions of people in the U.S. Southwest. PFAS have previously been detected in the Las Vegas Wash, but PFAS sources were not identified. In this study, upstream wash tributaries, wastewater treatment effluents, and shallow groundwater wells were sampled in multiple campaigns during dry-weather conditions to investigate possible PFAS sources. Out of 19 PFAS, two short-chain PFAS-perfluoropentanoic acid (48 % of the total molar concentration) and perfluorohexanoic acid (32 %)-comprised the majority of PFAS loading measured in the Las Vegas Wash, followed by perfluorooctanoic acid (9 %). On a mass loading basis, the majority of total measured PFAS (approximately 90 %) and at least 48 % of each specific PFAS in the Las Vegas Wash likely entered via municipal wastewater effluents, of which the main source was likely residential wastewater. One of the drainage areas with a major civilian airport was identified as a potential source of relatively enriched perfluorosulfonic acids to a small wash tributary and shallow groundwater samples. Nonetheless, that tributary contributed at most 15 % of any specific PFAS to the mainstem of the Las Vegas Wash. Total PFAS concentrations were relatively low for the small tributary associated with an urban smaller airport and the lack of flow in the tributary channel immediately downgradient of an Air Force base indicates the smaller airport and base were unlikely significant PFAS sources to the Las Vegas Wash. Overall, this study demonstrated effective PFAS source investigation methodology and the importance of wastewater effluent as a PFAS environmental pathway.

The effects of solids retention time in full-scale activated sludge basins on trace organic contaminant concentrations.

Although pharmaceuticals and personal care products (PPCPs) and endocrine disrupting compounds (EDCs) are largely unregulated, water resource recovery facilities are increasingly using advanced chemical/physical treatment technologies (e.g., advanced oxidation and reverse osmosis) to remove or destroy these trace organic contaminants (TOrCs). This can both reduce potential adverse human health effects in reuse applications and mitigate environmental effects on aquatic ecosystems. Unfortunately, advanced treatment technologies are typically energy intensive and costly to implement, operate, and maintain. The goal of this study was to determine whether optimization of solids retention time (SRT) provided sufficient benefits to warrant such operational strategies for TOrC mitigation. Specifically, SRTs of 5.5, 6, and 15 days were evaluated to determine the effects on several standard wastewater parameters (e.g., nitrite, nitrate, and ammonia concentrations) and the degradation of TOrCs. The experimental SRTs were operated simultaneously in parallel, full-scale activated sludge basins. The results indicate that it can be beneficial to implement biological process optimization strategies using existing infrastructure while reducing reliance on advanced treatment technologies. This study also identified potential operational issues that might arise in activated sludge systems operating at extended SRTs.

Per- and polyfluoroalkyl substances and organofluorine in lakes and waterways of the northwestern Great Basin and Sierra Nevada.

Per- and polyfluoroalkyl substances (PFAS) are anthropogenic chemicals that occur ubiquitously in the environment and have been linked to numerous adverse health effects in humans and aquatic organisms. Although numerous environmental monitoring studies have been conducted, only one has evaluated PFAS in surface waters of the northwestern Great Basin, which features unique topography that results in dozens of endorheic basins and terminal lakes with no natural outlet, where PFAS may accumulate. To close this knowledge gap, we evaluated the occurrence of PFAS in grab samples from 15 lakes (headwater and terminal lakes) and 10 rivers in the Great Basin located in Nevada and California of the United States. PFAS and organofluorine were quantified by liquid chromatography tandem mass spectroscopy (LC-MS/MS) and combustion ion chromatography, respectively. The highest concentrations of PFAS occurred in samples taken near sites with known or suspected prior aqueous film forming foam (AFFF) application (~20 to 4754 ng/L). Samples near wastewater treatment plants and in urban areas also tended to have PFAS concentrations greater than those measured in remote, less anthropogenically influenced areas (~2 to 15 ng/L, <3 ng/L respectively). In limited snapshot sampling events PFAS appeared to accumulate in terminal lakes to some extent; in-lake concentrations were two to five times greater than those of their inflows. Fluorotelomer sulfonates were present downstream of a known AFFF application area likely to have had fluorotelomer-based foams applied to it, and the concentrations decayed in a predictable manner, suggesting they may be used as an indicator of PFAS transport away from an AFFF source. In all but two samples, organofluorine concentrations were greater than the sum of targeted PFAS (on a F basis) (median of 0.6 % of organofluorine identified via LC-MS/MS), although there was considerable variability in organofluorine measured in replicate samples.

Characterizing the chemical and microbial fingerprint of unsheltered homelessness in an urban watershed.

Unsheltered homelessness is rapidly becoming a critical issue in many cities worldwide. The worsening situation not only highlights the socioeconomic plight, but it also raises awareness of ancillary issues such as the potential implications for urban water quality. The objective of this study was to simultaneously leverage diverse source tracking tools to develop a chemical and microbial fingerprint describing the relative contribution of direct human inputs into Las Vegas' tributary washes. By evaluating a wide range of urban water matrices using general water quality parameters, fecal indicator bacteria (FIB), human-associated microbial markers [e.g., HF183, crAssphage, and pepper mild mottle virus (PMMoV)], 16S rRNA gene sequencing data, and concentrations of 52 anthropogenic trace organic compounds (TOrCs), this study was able to differentiate principal sources of these constituents, including contributions from unsheltered homelessness. For example, HF183 (31% vs. 0%), crAssphage (61% vs. 5%), and PMMoV (72% vs. 55%) were more frequently detected in tributary washes with higher homeless census counts vs. 'control' tributary washes. Illicit drugs or their metabolites (e.g., heroin, acetylmorphine, amphetamine, and cocaine) and select TOrCs (e.g., acetaminophen, caffeine, ibuprofen, and naproxen) were also detected more frequently and at higher concentrations in the more anthropogenically-impacted washes. These data can be used to raise awareness of the shared interests between the broader community and those who are experiencing homelessness, notably the importance of protecting environmental health and water quality. Ultimately, this may lead to more rapid adoption of proven strategies for achieving functional zero homelessness, or at least additional resources for unsheltered individuals.

Two new methods of synthesis for the perbromate ion: chemistry and determination by LC-MS/MS.

Historically, the synthesis of perbromate ion through conventional oxidation routes has proven elusive. Herein, we report perbromate ion formation through the reaction of hypobromite and bromate ions in an alkaline sodium hypobromite solution. Formation was established via LC-MS/MS analysis of the bromate and perbromate ions in the reaction solutions over a 13-day period. Furthermore, it was discovered that the perbromate ion was also formed as a result of the electrospray ionization process. Selective reduction of the bromate ion prior to analysis was used to confirm the two formation pathways.

Assessment of PFAS fate, transport, and treatment inhibition associated with a simulated AFFF release within a WASTEWATER treatment plant.

Sequencing batch reactors (SBRs) were operated for 36 days to simulate the potential wastewater treatment impacts as well as fate and transport of per- and polyfluoroalkyl substances (PFAS) that could be associated with a release of alcohol resistant aqueous film forming foam (AR-AFFF) from on-site methanol fire suppression systems. The results of this study indicate that two days of exposure to AFFF were associated with small reductions in mixed liquor solids content and nitrification rates. No impacts on denitrification or biological phosphorus removal were observed. The addition of AFFF was associated with increases in 6:2 fluorotelomer sulfonate (6:2 FTS) in influent, effluent, and solids samples in the SBR. The following biotransformation pathway is proposed: an unidentified fluorotelomer precursor quickly degraded to 6:2 FTS, which then slowly degraded to several identified degradation intermediates and terminal, short-chain perfluorocarboxylic acid products. Data for 6:2 FTS, which was used as a proxy for AFFF-associated PFAS, were extrapolated to estimate that a removal of approximately 70% of AFFF via effluent and solids wasting would occur after 4 days at a full-scale treatment plant. This information can be used to better understand potential impacts on downstream processes, including potable reuse and biosolids production.

[Growth and mortality of the mother-of-pearl Pinctada mazatlanica in natural populations of the east coast of Baja California Sur, Mexico]. / Crecimiento y mortalidad de la madreperla Pinctada mazatlanica en poblaciones naturales del litoral oriental de Baja California Sur, México.

The Mexican Pacific mother-of-pearl Pinctada mazatlanica was placed in forbidden fisheries status for the Mexican Federal Government and considered in extinction danger since 1939. This decree was modified in 1994 to allow the capture of spat for research or marine culture. We estimated the growth and mortality of mother-of-pearl from the eastern littoral of South Baja California wild stock in the periods 1992-93 and 1997-99. We used 38 sample stations at 2 bays and 6 insular complexes. The maximum length was 187.22 mm (179.83-195.81 mm, P > 0.95). Seasonal von Bertalanffy growth (ELEFAN I routine) values are: L(infinity) = 193.31 mm, k = 0.54 year(-1), t(0) = -0.1805 year, C = 0.49 and WP = 0.75. The growth performance index was Phi' = 4.305. The total mortality was calculated from a length-converted catch curve Z = 2.03 año(-1). Length-weight relationship W(i) = 0.0005418 * L(i)(2.7301). The growth parameters were similar to those for Pinctada margaritifera var. cumingi (open ocean wild stocks). The wild stock oysters differ from culture individuals at experimental repopulation conditions in Paz Bay. The total mortality is similar to that for Pinctada radiata in the Red Sea.

[Growth and mortality of the mollusk Pteria sterna in wild banks of Southern Baja California, Mexico]. / Crecimiento y mortalidad de la concha nácar Pteria sterna en bancos silvestres de Baja California Sur, México.

The Gulf of California nacre shell Pteria sterna is an important marine resource in Mexico, and the main species for "half" and round pearl production in the American continent. Wild spat can only be extracted legally for research or culture activities. This study calculates growth and mortality parameters for wild stocks in the eastern coast of Southern Baja California. Height's data (353 dorso-ventral measurements) were taken from 1997 to 1999 at Santa Rosalia, Mulegé and Loreto Bay coast. The maximum length was estimated at 130.35 mm (124.22-136.48 mm, p>0.95). The length frequency data were set in a "virtual year". Seasonal von Bertalanffy growth parameters were calculated in the ELEFAN I routine, the values are: L(infinity) = 156.02 mm, k = 0.48 year(-1), t0 = -0.216 years, C = 0.43, WP = 0.73. and t(s) = 0.5. The growth performance index was phi' = 4.068. The total mortality was calculated from length-converted catch curve Z = 3.34 year(-1). The length-weight relationship was fixed for the equation W = 0.000756 * L(i)(2.7075) (r2 = 0.90, n = 233). The growth parameters values in experimental repopulation conditions are quite different, in contrast with the growth estimated in wild stocks oysters. The value of total mortality is similar to the estimations for Pinctada fucata populations from the Red Sea and P. radiata from the Mediterranean Sea.

Simultaneous ozone and granular activated carbon for advanced treatment of micropollutants in municipal wastewater effluent.

The main objective of this study was to compare the efficacy of ozone (O3) and O3 with granular activated carbon (GAC) (O3/GAC) at pilot-scale for the enhanced removal of micropollutants (MPs) from wastewater effluent. The results revealed enhanced removal of tris (2-carboxylethyl) phosphine (TCEP), sucralose, and meprobamate during the O3/GAC treatment experiments compared to the sum of their removal during isolated ozonation and GAC adsorption experiments. The long-term O3/GAC experiment showed the promotive effect of GAC substantially decreased after 20 h of O3 exposure. This decreased performance correlates with changes to GAC surface properties caused by O3. After 6 h of operation, O3 initially led to an increase in Brunauer-Emmett-Teller (BET) surface area on the GAC improving the elimination level of investigated MPs (except N-nitrosomorpholine (NMOR)). However, after 20 h of exposure, O3 ultimately caused structural damages to the GAC surface, decreased the BET surface area in the final stages of the experiment, and a 4-fold increase in O1s:C1s ratio on the GAC surface was observed due to an increase in surface acidic functional groups caused by O3 treatment.

[Space-time variation of Scleractinia, Gorgonacea, Gastropoda, Bivalvia, Cephalopoda, Asteroidea, Echinoidea and Holothuroidea, from shallow bottom in San Jose Island, Gulf of California]. / Variación espacio-temporal de Seleractinia, Gorgonacea, Gastropoda, Bivalvia, Cephalopoda, Asteroidea, Echinoidea y Holothuroidea, de fondos someros de la isla San José, Golfo de California.

Between the years 1999 and 2000, six expeditions were made to Isla San José, in the Gulf of California. Observations and samples were taken of benthic macroinvertebrates in nine locations. Based on the samples, the specific components of three phyla were determined: Cnidaria (Scleractinia and Gorgonacea), Mollusca (Gastropoda, Bivalvia and Cephalopoda), and Echinodermata (Echinoidea and Holothuroidea). The abundance of conspicuous benthic macroinvertebrates was visually estimated through free dives at a depth of between two and six meters along two transects parallel to the coast. A total of 38 taxa in three groups were determined. The most abundant species are Tripneustes depressus (44.9%), Echinometra vanbruntii (18.3%), Phataria unifascialis (8.9%), Centrostephanus coronatus (8.0%), Diadema mexicanum (5%) y Eucidaris thouarsii (3.6%). No significant differences between diversity (H'), equity (J) and richness of the species (S) during the months and site of study. The similarity analysis identified two groups from locations of the eastern and western coasts.

Removal of perfluoroalkyl and polyfluoroalkyl substances in potable reuse systems.

Perfluoroalkyl and polyfluoroalkyl substances (PFASs) are a group of persistent contaminants that have been identified throughout the aquatic environment. In this study, ten targeted perfluoroalkyl acids (PFAAs), three targeted PFAA precursors, and non-targeted PFAA precursors were monitored in four full- and pilot-scale potable reuse plants at each stage of advanced treatment. Non-targeted PFAA precursors were quantified by applying a total oxidizable precursor assay in which PFAA precursors are oxidized by hydroxyl radicals to targeted PFAAs. Two of the potable reuse systems had membrane-based treatments with reverse osmosis and UV-advanced oxidation (RO-UV/AOP) and two used ozone, biological activated carbon filtration and granular activated carbon adsorption (O3-BAC-GAC). The total targeted PFAAs in the four tertiary effluents, the influent sources for the potable reuse systems, ranged from 52 to 227 ng/L with non-targeted PFAA precursors accounting for 30-67% of total PFASs on a molar basis. The RO-UV/AOP treatment trains reduced PFAAs and PFAA precursors to below their method reporting limits through the barrier provided by RO. The O3-BAC-GAC based treatment trains reduced, but did not completely remove PFAAs or PFAA precursors and the PFASs present in the product water were primarily shorter-chain PFAAs, some of which lack human health guidance values for drinking water. The relative fraction of targeted shorter-chain PFAAs increased after each treatment step indicating that there was preferential removal of the PFAA precursors and longer-chain PFAAs. This study provides new insight on the concentrations and treatment of PFAA precursors through potable reuse treatment systems.

Biotransformation and sorption of trace organic compounds in biological nutrient removal treatment systems.

This study determined biotransformation rates (kbio) and sorption-distribution coefficients (Kd) for a select group of trace organic compounds (TOrCs) in anaerobic, anoxic, and aerobic activated sludge collected from two different biological nutrient removal (BNR) treatment systems located in Nevada (NV) and Ohio (OH) in the United States (US). The NV and OH facilities operated at solids retention times (SRTs) of 8 and 23 days, respectively. Using microwave-assisted extraction, the biotransformation rates of the chosen TOrCs were measured in the total mixed liquor. Sulfamethoxazole, trimethoprim, and atenolol biotransformed in all three redox regimes irrespective of the activated sludge source. The biotransformation of N, N-diethyl-3-methylbenzamide (DEET), triclosan, and benzotriazole was observed in aerobic activated sludge from both treatment plants; however, anoxic biotransformation of these three compounds was seen only in anoxic activated sludge from NV. Carbamazepine was recalcitrant in all three redox regimes and both sources of activated sludge. Atenolol and DEET had greater biotransformation rates in activated sludge with a higher SRT (23 days), while trimethoprim had a higher biotransformation rate in activated sludge with a lower SRT (8 days). The remaining compounds did not show any dependence on SRT. Lyophilized, heat inactivated sludge solids were used to determine the sorption-distribution coefficients. Triclosan was the most sorptive compound followed by carbamazepine, sulfamethoxazole, DEET, and benzotriazole. The sorption-distribution coefficients were similar across redox conditions and sludge sources. The biotransformation rates and sorption-distribution coefficients determined in this study can be used to improve fate prediction of the target TOrCs in BNR treatment systems.

Perchlorate assessment of the Nakdong and Yeongsan watersheds, Republic of Korea.

The objective of the present study was to conduct a preliminary assessment for perchlorate in surface water, drinking water, and wastewater treatment plant effluent samples obtained from the Nakdong and Yeongsan watersheds in the Republic of Korea. Samples were analyzed for perchlorate using ion chromatography with suppressed conductivity detection (IC-CD) and/or liquid chromatography with tandem mass spectrometry detection (LC-MS/MS). Method reporting limits were 5.0 microg/L for IC-CD and 0.05 microg/L for LC-MS/MS analysis. At perchlorate levels above 5.0 microg/L, IC-CD and LC-MS/MS provided comparable results. The levels of perchlorate detected in the samples procured from the Yeongsan watershed were < 5.0 microg/L in each case. However, Nakdong watershed samples contained perchlorate at levels up to 60 microg/L. The highest concentrations of perchlorate were found in surface water samples, although drinking water contained perchlorate at concentrations up to 35 microg/L. In a subset of samples analyzed by LC-MS/MS, chlorate and bromate also were detected at concentrations ranging from < 0.10 to 44 microg/L and < 0.10 to 2.6 microg/L, respectively. To the best of the authors' knowledge, this is the first perchlorate assessment reported for water sources in the Republic of Korea.

Analysis of bromate and bromide in blood.

Bromate is a regulated disinfection byproduct primarily associated with the ozonation of water containing bromide, but also is a byproduct of hypochlorite used to disinfect water. To study the pharmacokinetics of bromate, it is necessary to develop a robust and sensitive analytical method for the identification and quantitation of bromate in blood. A critical issue is the extent to which bromate is degraded presystemically and in blood at low (environmentally relevant) doses of ingested bromate as it is delivered to target tissue. A simple isolation procedure was developed using blood plasma spiked with various levels of bromate and bromide. Blood proteins and lipids were precipitated from plasma using acetonitrile. The resulting extracts were analyzed by ion-chromatography with inductively-coupled plasma mass spectrometry (IC-ICP/MS), with a method reporting limit of 5 ng/mL plasma for both bromate and bromide. Plasma samples purchased commercially were spiked with bromate and stored up to 7 days. Over the 7 day storage period, bromate decay remained under 20% for two spike doses. Decay studies in plasma samples from spiked blood drawn from live rats showed significant bromate decay within short periods of time preceding sample freezing, although samples which were spiked, centrifuged and frozen immediately after drawing yielded excellent analytical recoveries.

Population structure and accompanying biota of the snail Turbo (Callopoma) funiculosus (Gastropoda: Turbinidae), on Socorro Island, Revillagigedo Archipelago, Mexico.

The porcelain snail, Turbo funiculosus, is a potential fishery resource that almost has not been studied or used commercially. In March of 1992, we sampled T. funiculosus in Bahia Binners and Bahia Blanca, Socorro Island, Revillagigedo Archipelago, using 25 m2 quadrants. We found that total length varies between 3.0 and 85 mm, proportional weight between 3.0 and 228 g, and density between 6.21 and 9.87 ind/m2. The largest organisms (over 50 mm) contain 30.6% of soft parts. Porcelain snail populations remain unexploited on Revillagedo Archipelago and could be a potential resource under an adequate management strategy.

Treatment of poly- and perfluoroalkyl substances in U.S. full-scale water treatment systems.

The near ubiquitous presence of poly- and perfluoroalkyl substances (PFASs) in humans has raised concerns about potential human health effects from these chemicals, some of which are both extremely persistent and bioaccumulative. Because some of these chemicals are highly water soluble, one major pathway for human exposure is the consumption of contaminated drinking water. This study measured concentrations of PFASs in 18 raw drinking water sources and 2 treated wastewater effluents and evaluated 15 full-scale treatment systems for the attenuation of PFASs in water treatment utilities throughout the U.S. A liquid-chromatography tandem mass-spectrometry method was used to enable measurement of a suite of 23 PFASs, including perfluorocarboxylic acids (PFCAs) and perfluorosulfonic acids (PFSAs). Despite the differences in reporting levels, the PFASs that were detected in >70% of the source water samples (n = 39) included PFSAs, perfluorobutane sulfonic acid (74%), perfluorohexane sulfonic acid (79%), and perfluorooctane sulfonic acid (84%), and PFCAs, perfluoropentanoic acid (74%), perfluorohexanoic acid (79%), perfluoroheptanoic acid (74%), and perfluorooctanoic acid (74%). More importantly, water treatment techniques such as ferric or alum coagulation, granular/micro-/ultra- filtration, aeration, oxidation (i.e., permanganate, ultraviolet/hydrogen peroxide), and disinfection (i.e., ozonation, chlorine dioxide, chlorination, and chloramination) were mostly ineffective in removing PFASs. However, anion exchange and granular activated carbon treatment preferably removed longer-chain PFASs and the PFSAs compared to the PFCAs, and reverse osmosis demonstrated significant removal for all the PFASs, including the smallest PFAS, perfluorobutanoic acid.

Titanium distribution in swimming pool water is dominated by dissolved species.

The increased use of titanium dioxide nanoparticles (nano-TiO2) in consumer products such as sunscreen has raised concerns about their possible risk to human and environmental health. In this work, we report the occurrence, size fractionation and behavior of titanium (Ti) in a children's swimming pool. Size-fractionated samples were analyzed for Ti using ICP-MS. Total titanium concentrations ([Ti]) in the pool water ranged between 21 µg/L and 60 µg/L and increased throughout the 101-day sampling period while [Ti] in tap water remained relatively constant. The majority of [Ti] was found in the dissolved phase (<1 kDa), with only a minor fraction of total [Ti] being considered either particulate or microparticulate. Simple models suggest that evaporation may account for the observed variation in [Ti], while sunscreen may be a relevant source of particulate and microparticule Ti. Compared to diet, incidental ingestion of nano-Ti from swimming pool water is minimal.