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In recent years, a new class of highly crystalline advanced permeable materials covalent-organic frameworks (COFs) have garnered a great deal of attention thanks to their remarkable properties, such as their large surface area, highly ordered pores and channels, and controllable crystalline structures. The lower physical stability and electrical conductivity, however, prevent them from being widely used in applications like photocatalytic activities and innovative energy storage and conversion devices. For this reason, many studies have focused on finding ways to improve upon these interesting materials while also minimizing their drawbacks. This review article begins with a brief introduction to the history and major milestones of COFs development before moving on to a comprehensive exploration of the various synthesis methods and recent successes and signposts of their potential applications in carbon dioxide (CO2 ) sequestration, supercapacitors (SCs), lithium-ion batteries (LIBs), and hydrogen production (H2 -energy). In conclusion, the difficulties and potential of future developing with highly efficient COFs ideas for photocatalytic as well as electrochemical energy storage applications are highlighted.
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Nanotechnology is gaining enormous attention as the most dynamic research area in science and technology. It involves the synthesis and applications of nanomaterials in diverse fields including medical, agriculture, textiles, food technology, cosmetics, aerospace, electronics, etc. Silver nanoparticles (AgNPs) have been extensively used in such applications due to their excellent physicochemical, antibacterial, and biological properties. The use of plant extract as a biological reactor is one of the most promising solutions for the synthesis of AgNPs because this process overcomes the drawbacks of physical and chemical methods. This review article summarizes the plant-mediated synthesis process, the probable reaction mechanism, and the colorimetric sensing applications of AgNPs. Plant-mediated synthesis parameters largely affect the surface plasmon resonance (SPR) characteristic due to the changes in the size and shape of AgNPs. These changes in the size and shape of plant-mediated AgNPs are elaborately discussed here by analyzing the surface plasmon resonance characteristics. Furthermore, this article also highlights the promising applications of plant-mediated AgNPs in sensing applications regarding the detection of mercury, hydrogen peroxide, lead, and glucose. Finally, it describes the future perspective of plant-mediated AgNPs for the development of green chemistry.
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Nanopartículas Metálicas , Ressonância de Plasmônio de Superfície , Prata/química , Colorimetria/métodos , Nanopartículas Metálicas/química , Antibacterianos/química , Extratos Vegetais/química , Química VerdeRESUMO
Execution of natural thickener (wild taro corm) over pretreated cotton woven fabric with reactive dye has been explored in this research work. Taro root was collected from Sherpur in Bangladesh and made into a fine powder using a grinder. Thickener pastes were prepared by using different concentrations of taro powder, then their viscosity was measured to find out the difference with sodium alginate thickener, which is traditionally used for reactive printing. A suitable thickener stock paste concentration was selected from a number of trials and depending on the result of visual sharpness of the printed samples. A suitable reactive printing method was selected between all in (1 step) and 2 step methods of reactive printing and finally the amount of thickener on the printing recipe was optimized. The color fastness to wash, color fastness to rubbing, bending length, K/S value, levelness, penetration%, print paste adds on and visual sharpness were measured to assess the printing quality. The findings indicate that when Taro corm powder is combined with boiled water, it produces a solution with higher viscosity. Additionally, a mixture of 15 % taro and boiled water yields the most distinct print outline. Comparatively, the 2-step reactive printing method offers a superior outline compared to the 1-step (all in one) method. Moreover, using 50 to 60 gm of taro corm thickening paste for every 100 g of print paste results in a higher K/S value. The results revealed that the wild taro corm could be used successfully as thickener for reactive printing. Finally, the cost was also calculated, and it was found economical as well compared to sodium alginate.
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The increasing depletion of reserves of natural resources has led to a growing worldwide focus on the exploitation of available waste in new domains. The presence of weedy plants is pervasive on a global scale and has detrimental effects on several aspects of the environment, agriculture, and people's health. Therefore, repurposing these Agri-weed plants for beneficial purposes would be a significant achievement. Furthermore, since raw materials constitute a substantial portion of manufacturing costs, using weeds as a feasible substitute for raw materials might potentially provide considerable advantages for manufacturers. In this study, an endeavor has been made to the utilization of agricultural waste "Urena Lobata", for the purpose of paper production. In the interim, the utilization of Urena Lobata as an alternative and sustainable raw material for pulp and paper industry could potentially offer a beneficial approach to mitigation of deforestation. The effective production of handsheets with weights of 70 g/m2 and 80 g/m2 was achieved using Urena Lobata fiber, Bleached Urena Lobata Fiber, and hardwood kraft pulp. Mechanical characteristics of handsheet's were comprehensively examined by the bursting index, tensile strength, tear index, brightness percentage and scanning electron microscope for handsheet's morphology. The results show that the handsheets produced by Urena Lobata fiber exhibit a much lower brightness percentage, high tensile strength and bursting index. Alongside, handsheets by bleached Urena Lobata fiber indicate higher brightness percentage, satisfactory values for tensile strength, bursting index, and tear index. The prepared materials are suitable for a broad spectrum of prospective applications, encompassing newsprint, tissue paper, filtration paper as well as high-quality writing and printing paper.
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Jute is an inherent lignocellulosic fiber, consisting of hemicellulose, α-cellulose, and lignin. Industrial ventilation, automotive composites, upholstery, carpets, military uniforms, hospital furnishings, and curtains necessitate the integration of flame-retardance properties into jute fibers. In this investigation, seven weave-structured jute fabrics were treated using an organophosphorus-based flame-retardant (FR) chemical (ITOFLAM CPN) and a crosslinking agent (KNITTEX CHN) by the pad-dry-cure method. The thermal stability, degradation and pyrolysis behavior of jute was measured using a thermogravimetric analyzer (TGA). Surface morphology and element distribution were scrutinized utilizing a scanning electron microscope (SEM) and an energy-dispersive spectrometer (EDS). The ATR-FTIR (Attenuated Total Reflection-Fourier Transform Infrared Spectrometer) technique has been employed for analyzing the composition of chemicals in the jute fabrics. According to the protocols specified in ISO 14184-1, free formaldehyde detection was carried out on the jute fabrics. The flame-retardance property was significantly improved on all of the jute fabrics after FR treatment. FTIR and SEM-EDS studies revealed the presence of FR chemical deposition on the surface of the jute fabrics. TGA analysis indicated that the fabrics treated with FR exhibited premature degradation, leading to the generation of more char compared to untreated samples. The jute fabrics specifically demonstrated a notable enhancement in residual mass, exceeding 50% after FR treatment. However, it is noteworthy that the FR-treated fabrics exhibited an elevated level of free formaldehyde content, surpassing the permissible limit of formaldehyde in textiles intended for direct skin contact. The residual mass loss percentage after ten washes of FR-treated fabrics remained in a range from 32% to 36%. Twill weave designed fabrics (FRD4 and FRD5) clearly showed a lower thermal degradation temperature than the other weaves used in this study.
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In recent years, consumer preferences have begun to turn back to natural dyes, whereas synthetic dyes have been pushed into the background over the previous 60 years. This is a result of increased knowledge of the potential hazards associated with the creation of synthetic dyes, which use raw materials derived from petrochemicals and involve intense chemical interactions. Such dyes need a lot of energy to produce, and their negative effects on the environment increase pollution. It has been discovered that several of these dyes, particularly the azo-based ones are carcinogenic. On the contrary, natural dyes are getting more attention from scientists and researchers as a result of their several advantages like being eco-friendly, biodegradable and renewable, sustainable, available in nature, having no disposal problems, minimizing the consumption of fossil fuel, anti-bacterial, insect repellent, and anti-allergic, anti-ultraviolet, intensify dyeing and finishing process efficiency, less expensive, and no adverse effects on human health and environment. However, there are also some drawbacks, like poor fastness properties, natural dye printing for bulk production, difficulties in reproducibility of shades, and so forth. Despite all these limitations, the demand for natural dyes is increasing significantly in textile industries because they offer far more safety than synthetic dyes. This study provides an overall concept of the natural dyes in textile printing. It illustrates parameters of printing performance, methods, and techniques of extraction of natural dyes, printing methods, and printing of natural and synthetic fibers. Finally, this study describes the challenges and future prospects of natural dyes in textile printing.
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Corantes , Têxteis , Corantes/química , Impressão , Indústria TêxtilRESUMO
Today, textile-based wearable electronic devices (textronics) have been developed by taking advantage of nanotechnology and textile substrates. Textile substrates offer flexibility, air permeability, breathability, and wearability, whereas, using nanomaterials offers numerous functional properties, like electrical conductivity, hydrophobicity, touch sensitivity, self-healing properties, joule heating properties, and many more. For these reasons, textronics have been extensively used in many applications. Recently, new emerging two-dimensional (2D) transition metal carbide and nitride, known as MXene, nanomaterials have been highly considered for developing textronics because the surface functional groups and hydrophilicity of MXene nanoflakes allow the facile fabrication of MXene-based textronics. In addition, MXene nanosheets possess excellent electroconductivity and mechanical properties as well as large surface area, which also give numerous opportunities to develop novel functional MXene/textile-based wearable electronic devices. Therefore, this review summarizes the recent advancements in the architectural design of MXene-based textronics, like fiber, yarn, and fabric. Regarding the fabrication of MXene/textile composites, numerous factors affect the functional properties (e.g. fabric structure, MXene size, etc.). All the crucial affecting parameters, which should be chosen carefully during the fabrication process, are critically discussed here. Next, the recent applications of MXene-based textronics in supercapacitors, thermotherapy, and sensors are elaborately delineated. Finally, the existing challenges and future scopes associated with the development of MXene-based textronics are presented.
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A quest was carried out to print on light weight lyocell knitted fabric with two mono-functional reactive dyes using pure guar gum (GG) or substituted guar gum (SGG) in combination with sodium alginate (Al) at different ratios. For each dyestuff, the print paste was prepared using mixed thickeners, namely GG/Al or SGA/Al at five different ratios. All samples were compared with the recipe containing pure sodium alginate. The empirical data show that the rheological behaviorisms of print paste-like viscosity and its other physical characteristics, such as paste add-on percentage (%) and penetration percentage (%), were dependent on the percentage of GG or SGG present in the thickener combination prepared with sodium Alginate. The combination of thickeners of these types also creates an impact on the final excellence of printed fabric, such as the colour yield, sharpness, stiffness of the fabric and the fastness of the colour. However, a few qualities are also dye dependent. The SGG/A combination gives a superior result when combining all the data with GG/A. Alginate with the small addition of SGG viz. the 80/20 or 60/40 mixture shows an excellent result in terms of printing characteristics. The thickener had no influential effect on the colour fastness rating.
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The rapid growth of population and industrialization have intensified the problem of water pollution globally. To meet the challenge of industrialization, the use of synthetic dyes in the textile industry, dyeing and printing industry, tannery and paint industry, paper and pulp industry, cosmetic and food industry, dye manufacturing industry, and pharmaceutical industry has increased exponentially. Among these industries, the textile industry is prominent for the water pollution due to the hefty consumption of water and discharge of coloring materials in the effluent. The discharge of this effluent into the aquatic reservoir affects its biochemical oxygen demand (BOD), chemical oxygen demand (COD), total dissolved solids (TDS), total suspended solids (TSS), and pH. The release of the effluents without any remedial treatment will generate a gigantic peril to the aquatic ecosystem and human health. The ecological-friendly treatment of the dye-containing wastewater to minimize the detrimental effect on human health and the environment is the need of the hour. The purpose of this review is to evaluate the catastrophic effects of textile dyes on human health and the environment. This review provides a comprehensive insight into the dyes and chemicals used in the textile industry, focusing on the typical treatment processes for their removal from industrial wastewaters, including chemical, biological, physical, and hybrid techniques.
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Poluentes Químicos da Água , Humanos , Poluentes Químicos da Água/análise , Ecossistema , Águas Residuárias , Corantes/química , Têxteis , Indústria Têxtil , Resíduos Industriais/análiseRESUMO
Bioactive textile materials are a promising field in the development of functional textiles. The integration of bioactive compounds, such as natural dyes, into textiles offers a range of benefits, including UV protection, anti-microbial properties, and insect repellency. Natural dyes have been shown to have bioactivity, and their integration into textiles has been extensively studied. The application of natural dyes on textile substrates will be an advantage for their inherent functional properties along with their non-toxic and eco-friendly nature. This review addresses the effect of natural dyes on surface modification of most used natural and synthetic fibers and its subsequent effects on their anti-microbial, UV protection and insect repellent properties with natural dyes. Natural dyes have proved to be environmentally friendly in an attempt to improve bioactive functions in textile materials. This review provides a clear view of sustainable resources for the dyeing and finishing of textiles to develop a cleaner pathway of bioactive textiles using natural dyes. Furthermore, the dye source, advantages and disadvantages of natural dye, main dye component, and chemical structure are listed. However, there is still a need for interdisciplinary research to further optimize the integration of natural dyes into textiles and to improve their bioactivity, biocompatibility, and sustainability. The development of bioactive textile materials using natural dyes has the potential to revolutionize the textile industry and to provide a range of benefits to consumers and society.
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Corantes , Têxteis , Corantes/química , Indústria TêxtilRESUMO
This experiment presents a study carried out on the electric charge passing textiles for heat production in compression weft-knitted composite fabrics used for medical purposes. The aim was to flourish compression support of knitted structure with integrated highly sensitive metal (silver) coated polyamide multifilament yarns and to evaluate its heat origination attributes after stretching in different levels as well as changes of the temperature during the time. A flat double needle-bed knitting machine was utilized to fabricate the selected specimens together with elastomeric inlay-yarn incorporated into the structure for compression generation and silver coated polyamide yarn laid as ground yarn in a plated structure for heat generation. Six different variants depending on the metal coated yarn amount used and the fabric structure along with two types of the conductive yarn linear density were fabricated for this research work. Scanning electron microscope (SEM) images were preoccupied to show the morphology of conductive yarn and thermal pictures were captured to study the evenness of the heat over the surface of composite fabrics depending on conductive yarn distribution in the pattern repeat. The temperature profile of fabricated composite fabrics and comparison of the heat generation by specimens after stretching in different levels was studied.
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This work investigated the effect of superheated steam (SHS) jute fiber and poly (lactic acid) (PLA) having a weight proportion of 30:70 which were synthesized using the melt blending method. The goal of this treatment was to boost up the fiber-polymer interfacial linkage. The action was conducted in a superheated steam oven at various times (30-120 min) and temperatures (170-220 °C). The biocomposites were assessed in terms of mechanical characteristics, dimensional stability and morphological properties. Compared to different treatment temperatures, the results showed that treatment at 210 °C for 60 min offered the best tensile characteristics. Because of the presence of SHS-Jute, the tensile, impact, bending and dimensional stability of the bio-composites have been improved. The FTIR and SEM study revealed progress in the interfacial linkage between SHS-Jute and PLA. This interfacial link improves the bending strength of SHS-Jute-PLA biocomposites by about 15.64%. X-ray diffraction (XRD) investigation also showed an elevation in the crystalline structure with the incorporation of SHS-Jute. The degradation tests of the biocomposite were carried out in deionized water. SHS treatment reduces hemicellulose contents in jute fiber which causes water uptake% reduction is 54% in SHS-Jute-PLA. The SHS-Jute-PLA biocomposite appeared with promising characteristics for utilization as a green and ecological substitute particle board material.
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A huge amount of waste was generated from the apparel industries. This study aims to develop the process of producing recycled yarn from apparel waste. The apparel leftover fabric was converted to fiber, and the fiber was mixed with virgin cotton in different ratios to produce sustainable 6/1 Ne rotor yarn. The produced yarn qualities viz. count strength product (CSP), elongation percentage, total quality index (TQI) and tenacity were decreased linearly, and opposite scenario observed for thick and thin places, neps, imperfection index (IPI) and hairiness (H) attributes with increasing the amount of waste addition with virgin cotton. The leftover fabric (LOF) can be utilized to develop a sustainable yarn and to zero waste management.
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Intelligent textiles are predicted to see a 'surprising' development in the future. The consequence of this revived interest has been the growth of industrial goods and the improvement of innovative methods for the incorporation of electrical features into textiles materials. Conductive textiles comprise conductive fibres, yarns, fabrics, and finished goods produced using them. Present perspectives to manufacture electrically conductive threads containing conductive substrates, metal wires, metallic yarns, and intrinsically conductive polymers. This analysis concentrates on the latest developments of electro-conductivity in the area of smart textiles and heeds especially to materials and their assembling processes. The aim of this work is to illustrate a potential trade-off between versatility, ergonomics, low energy utilization, integration, and heating properties.
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Textile-based heaters have opened new opportunities for next-generation smart heating devices. This experiment presents electrically conductive textiles for heat generation in orthopaedic compression supports. The main goal was to investigate the influence of frequent washing and stretching on heat generation durability of constructed compression knitted structures. The silver coated polyamide yarns were used to knit a half-Milano rib structure containing elastomeric inlay-yarn. Dimensional stability of the knitted fabric and morphological changes of the silver coated electro-conductive yarns were investigated during every wash cycle. The results revealed that temperature becomes stable within two minutes for all investigated fabrics. The heat generation was found to be dependent on the stretching, mostly due to the changing surface area; and it should be considered during the development of heated compression knits. Washing negatively influences the heat-generating capacity on the fabric due to the surface damage caused by the mechanical and chemical interaction during washing. The higher number of silver-coated filaments in the electro-conductive yarn and the knitted structure, protecting the electro-conductive yarn from mechanical abrasion, may ensure higher durability of heating characteristics.
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This study aimed to investigate the effect of extensibility on cotton blended polyester-spandex core-spun yarn in the weft direction of 3/1 right-handed Z-twill denim. For the preparation of samples, 100% ring spun cotton yarn of 42 tex (14s/1 Ne) was used as warp, and 70:30, 30:70, 60:40, and 40:60 cotton-polyester core-spun yarn of 30 tex (20s/1) was used in the weft direction. Four categories of denim fabric were fabricated by using the air-jet weaving machine. Spandex yarn was used as a core material of weft with a percentage of 2%, 2.5%, 1.9%, and 1.8% respectively. Different physio-mechanical characteristics namely tensile and tearing strength, GSM, growth and recovery percentage, initial modulus, bending length, drape co-efficiency, abrasion resistance, flexural rigidity were evaluated to justify the quality of fabricated pieces of denim. Water wicking and breathability were taken into consideration when determining comfort. Higher cotton containing specimens exhibited lower tensile and tearing strength. Additionally, the produced denim fabrics showed balanced drapability and good breathability.
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Water is the ultimate and mostly used media during textile materials processing, especially in colouration. This study investigated the possibilities of using seawater for cotton and polyester fabrics dyeing. Single jersey fabrics made of 100 percent cotton and polyester were dyed using a standard recipe and two separate water source as dyeing mediums. It has been focused on the assessment of colour fastness to wash, perspiration, saliva, rubbing, water, light and colour difference value due to compare the efficiency of dyeing media. The results revealed that the cotton fabric dyed with seawater showed lighter shade than that of ground water sample. But for polyester fabric darker shade was obtained compared to ground water. The cotton sample dyed with sea water carried about 15% higher colour strength than ground water dyed sample but for polyester it was very negligible, only 3%. Moreover, the results of colour fastness to wash, perspiration, saliva, rubbing, water and light for seawater dyed samples of cotton and polyester were shown satisfactory outcomes having the grading of 4-5 in most of the cases. This exploration established that commercial dyeing processes were robust and can be practically transferable into the seawater medium for cotton and polyester fabrics.
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This research aims to study the spinnability of pristine PALF and PALF blended cotton using the existing spinning machines. Apron draft ring spinning frame and flyer jute spinning frame were used to produce 100% PALF yarn and the yarns count were found 121 tex and 138 tex separately. Besides, 90:10 and 80:20 cotton-PALF blended 30 tex yarn spun in a cotton spinning system with different twist factors. With both yarns, two samples; 1/1 plain and 3/1 twill fabrics, were fabricated through equal density. For plain and twill fabric, PALF yarn of 121 tex and 138 tex were used in the warp way, respectively and PALF blended cotton yarn of 60 tex was used in the weft way. Through the study, physio-mechanical properties of the samples were explored and FTIR & XRD patterns were analyzed to perform the task for diversified use as an ultimate fiber in industrial and domestic purposes.