Occurrence, Distribution, and Potential Sources of Organophosphate Esters in Urban and Rural Surface Water in Shanghai, China.

In this study, the occurrence and distribution patterns of eight organophosphate esters (OPEs) were investigated in urban and rural surface water in a typical cosmopolitan city: Shanghai, China. In addition, concentration levels and removal efficiencies of seven sewage treatment plants were analyzed. The OPEs concentrations detected in urban rivers were significantly higher than those detected in rural rivers. Total OPEs ranged from 185.4 to 321 ng L-1 in rural surface water and from 340 to 1688.7 ng L-1 in urban, with an average of 221.8 ng L-1 and 850.2 ng L-1, respectively. Compared with other studies published in the world, the OPEs contamination in surface river water in Shanghai was at a moderate level. Furthermore, the potential sources of OPEs in urban surface water were investigated, and the results indicated that OPEs in urban surface water mainly came from three potential sources. In rural surface water, the OPE concentrations were uniformly distributed, so OPEs in rural surface water may came from nonpoint source pollution. Last, a preliminary environmental risk assessment and health risk assessment were conducted. The results showed low environmental risks at all sampling sites (except for sampling point R7: medium risk for algae) for the three aquatic organisms (algae, daphnia, and fish). Health risk assessment indicated a noncarcinogenic risk for diverse human groups for Æ©OPEs.

Fano resonances in cone-shaped inwall capillary based microsphere resonator.

In this paper, we demonstrate a cone-shaped inwall coupler for excitation of the whispering-gallery modes (WGMs) of a microsphere resonator. The coupler is composed of a single mode fiber (SMF) and a capillary with an inner diameter of 5 µm. After immersing the capillary front end vertically into Hydrofluoric acid to obtain a cone inside the capillary, light in the SMF couples into the capillary efficiently while the hollow core is wide enough for a microsphere to be inserted. Because the front end face of the capillary acts as a reflector, a Fano resonance with an asymmetric line shape and a Q-factor of 2.57 × 104 is observed in the reflection spectrum using a barium titanite glass microsphere with a diameter of 45 µm. The integrated resonator structure has the advantages such as the reflective type, alignment-free and mechanically robust, making it have great potential in sensing applications and optical switching.

Investigation into the characteristics of electron beam-aged microplastics and adsorption behavior of dibutyl phthalate.

Microplastics are increasingly prevalent in the environment, and their ability to adsorb various organic additives, posing harm to organisms, has attracted growing attention. Currently, there are no effective methods to age microplastics, and there is limited discussion on the subsequent treatment of aged microplastics. This study focuses on micro polyethylene (PE) and employs electron beam technology for aging treatment, investigating the adsorption and leaching behavior between PE and dibutyl phthalate (DBP) before and after aging. Experimental results indicate that with increasing doses of electron beam irradiation, the surface microstructure of PE worsens, inducing the generation of oxygen-containing functional groups on the surface of polyethylene. Comparative evaluations between electron beam aging and existing methods show that electron beam technology surpasses existing aging methods, achieving a level of aging exceeding 0.7 within an extremely short period of 1 min at doses exceeding 350 kGy. Adsorption experiments demonstrate that the adsorption between PE and DBP conforms to pseudo-second-order kinetics and the Freundlich model both before and after aging. The adsorption capacity of microplastics for DBP increases from 76.8 mg g-1 to 167.0 mg g-1 after treatment, exceeding that of conventional DBP adsorbents. Electron beam irradiation causes aging of microplastics mainly through the generation of ·OH, which lead to the formation of oxygen-containing functional groups on the microplastics' surface, thereby enhancing their adsorption capacity for DBP. This provides a new perspective for the degradation of aged microplastics and composite pollutants.

Investigation of the adsorption behavior and adsorption mechanism of pollutants onto electron beam-aged microplastics.

Microplastics, as an emerging pollutant, are widely distributed worldwide. Extensive research has been conducted to address the issue of microplastic pollution; however, effective methods for microplastic treatment are still lacking. This study innovatively utilizes electron beam technology to age and degrade microplastics. Compared to other treatment methods, electron beam technology can effectively promote the aging and degradation of microplastics. The Oxygen - carbon ratio of aged microplastics reached 0.071, with a mass loss of 48 % and a carbonyl index value of 0.69, making it the most effective method for short-term aging treatment in current research efforts. Theoretical calculations and experimental results demonstrate that a large number of oxygen-containing functional groups are generated on the surface of microplastics after electron beam irradiation, changing their adsorption performance for pollutants. Theoretical calculations show that an increase in oxygen-containing functional groups on the surface leads to a gradual decrease in hydrophobic pollutant adsorption capacity while increasing hydrophilic pollutant adsorption capacity for aged microplastics. Experimental studies were conducted to investigate the adsorption behavior and process of typical pollutants by aged microplastics which conform to pseudo-second-order kinetics and Henry model during the adsorption process, and the adsorption results are consistent with theoretical calculations. The results show that the degradation of microplastics is mainly due to hydroxyl radicals generated by electron beam irradiation, which can break the carbon chain of microplastics and gradually degrade them into small molecular esters and alcohols. Furthermore, studies have shown that microplastics can desorb pollutants in pure water and simulated gastric fluid. Overall, electron beam irradiation is currently the most effective method for degrading microplastics. These results also clearly elucidate the characteristics and mechanisms of the interaction between aged microplastics and organic pollutants, providing further insights for assessing microplastic pollution in real-world environments.

Revealing the role of interlayer spacing in radioactive-ion sieving of functionalized graphene membranes.

Functionalization of graphene enables precise control over interlayer spacing during film formation, thereby enhancing the separation efficiency of radioactive ions in graphene membranes. However, the systematic impact of interlayer spacing of graphene membranes on radioactive-ion separation remains unexplored. This study aims to elucidate how interlayer spacing in functionalized graphene membranes affects the separation of radioactive ions. Utilizing polyamidoxime (PAO) to modify graphene oxide, we controlled the interlayer spacing of graphene membranes. Experimental results indicate that tuning interlayer spacing enables control of the permeation flux of radioactive ions (UO22+ 1.01 × 10-5-8.32 × 10-5 mol/m2·h, and K+ remains stable at 3.60 × 10-4 mol/m2·h), and the K+/UO22+ separation factors up to 36.2 at an interlayer spacing of 8.8 Å. Using density functional theory and molecular dynamics simulations, we discovered that the effective separation is mainly determined via interlayer spacing and the quantity of introduced functional groups, explaining the anomalous high permeation flux of target ions at low interlayer spacing (4.3 Å). This study deepens our comprehension of interlayer spacing within nanoconfined spaces for ion separation and recovery via graphene membranes, offering valuable insights for the design and synthesis of high-performance nanomembrane materials.

Constructing amidoxime adsorption sites on the core-shell structured natural silk protein for uranium capture.

Amidoxime-based fiber adsorbents hold significant promise for uranium extraction. However, a notable issue is that these adsorbents primarily originate from synthetic polymer materials, which, aside from providing good mechanical support, have no other functions. In recent study, we shifted our focus to silk fiber (SF), a natural protein fiber known for its unique core-shell structure and rich amino acids. The shell layer, due to its abundant functional groups, makes it easily modifiable, while the core layer provides excellent mechanical strength. Leveraging these inherent properties, an amidoxime-based fiber adsorbent was developed. This adsorbent utilizes amino and carboxyl groups for enhanced performance synergistically. This method involves establishing uranium affinity sites on the outer sericin layer of SF via chemical initiation of graft polymerization (CIGP) and amidoximation (SF-g-PAO). The water absorption ratio of SF-g-PAO is as high as 601.16 % (DG = 97.17 %). Besides, SF-g-PAO demonstrates an exceptional adsorption capacity of 15.69 mg/g in simulated seawater, achieving a remarkable removal rate of uranyl ions at 95.06 %. It can withstand a minimum of five adsorption-elution cycles. Over a 4-week period in natural seawater, SF-g-PAO displayed an adsorption capacity of 4.95 mg/g. Furthermore, SF-g-PAO also exhibits impressive uranium removal efficiency in real nuclear wastewater, with a removal rate of 63 % in just 15 min and a final removal rate of 90 %. It is hoped that this SF-g-PAO, prepared through this straightforward method and characterized by the synergistic action of amino and carboxyl groups, can offer innovative insights into the development of uranium extraction adsorbents.

Electron beam degradation of the cardiovascular drug salbutamol: Mechanisms and degradation pathways.

With the increasing incidence and mortality of cardiovascular diseases, high consumption of the cardiovascular drug salbutamol (SAL) has made this compound an emerging pollutant in natural water and a challenge for traditional wastewater treatment. In this paper, an efficient advanced oxidation process was used to degrade SAL by electron beam (EB) irradiation. The results revealed that 100 mg L-1 of SAL could be nearly completely removed (95.1%) at 10 kGy and the degradation kinetic well followed pseudo first-order kinetic model. Different factors, including pH, inorganic ions and water matrix, had varying effects on the degradation of SAL owing to their important influence on the formation of reactive species in the aqueous solution. And it was found that eaq- played a major role in the degradation of SAL parent. Moreover, the addition of K2S2O8 (20 mM) increased the SAL mineralization rate from 2.9% to 64.2%, suggesting that oxidation free radicals could greatly improve the mineralization rate of SAL. Combining with the theoretical calculations and determined degradation by-products, four possible degradation pathways of SAL by EB irradiation were proposed, including H•, •OH and eaq- all participated in the degradation of SAL. Finally, toxicity evaluation suggested that the toxicity of SAL aqueous solution reduced after EB irradiation, indicating that it is an effective method to degrade SAL.

Enhanced decomplexation of Cu-EDTA and simultaneous removal of Cu(II) by electron beam irradiation accompanied with autocatalytic fenton-like reaction: Synergistic performance and mechanism.

Widely existing heavy metal complexes with high stability and poor biodegradability are intractable to be eliminated by conventional methods. In this study, electron beam (EB) irradiation characterized by rapidly producing strong oxidizing radicals was employed to effectively decompose Cu-ethylenediaminetetraacetic acid (Cu-EDTA) with almost complete elimination at 5 kGy. In terms of heavy metal removal, EB irradiation at relatively low doses was insufficient to remove copper ions, which was only 17.2% under 15 kGy. However, with the extra addition of 8 mM H2O2, such an irradiation dose could result in 99.0% copper ions removal. Mechanism analysis indicated that EB irradiation combined with spontaneously induced Fenton-like reactions were responsible for its excellent performance. The prime function of EB irradiation was to destroy the structure of Cu-EDTA with in-situ produced ·OH, and the subsequent released Cu-based intermediates could activate H2O2 to initiate autocatalytic chain reactions, correspondingly accelerating the degradation of complexes and the liberation of metal ions. Highly oxidative ·OH and O2·- were demonstrated as main active species acted on different positions of Cu-EDTA to realize gradual decarboxylation, synchronously generating low molecular weight compounds. XRD and XPS analysis showed that the released copper ions were mainly precipitated in the form of CuO, Cu(OH)2 and Cu2(OH)2CO3. In general, EB/H2O2 was an adoptable strategy for the disposal of such refractory heavy metal complexes.

Degradation of hexavalent chromium and naphthalene by electron beam irradiation: Degradation efficiency, mechanisms, and degradation pathway.

Heavy metals (HMs) and polycyclic aromatic hydrocarbons (PAHs) in industrial wastewater have attracted much attention due to their damage to the environment and the human body. Studies have shown that there may be interactions between PAHs and HMs, leading to enhanced toxicity of both pollutants. It has been shown that traditional methods are difficult to treat a combination of PAHs and HMs simultaneously. This paper presented an innovative method for treating PAHs and HMs compound pollutants by electron beam irradiation and achieved the removal of the compound pollutants using a single means. Experiments showed that the absorbed dose at 15 kGy could achieve 100% degradation of NAP and 90% reduction of Cr (Ⅵ). This article investigated the effects of electron beam removal of PAHs and HMs complex contaminants in various water environmental matrices. The experimental results showed that the degradation of NAP followed the pseudo-first-order dynamics, and the degradation of NAP was more favorable under neutral conditions. Inorganic ions and water quality had little effect on NAP degradation. For electron beam reduction of Cr (Ⅵ), alkaline conditions were more conducive to reducing Cr (Ⅵ). Especially, adding K2S2O8 or HCOOH achieved 99% reduction of Cr (Ⅵ). Experiments showed that •OH achieve the degradation of NAP, and eaq- achieve the reduction of Cr (Ⅵ). The results showed that the degradation of NAP was mainly achieved by benzene ring opening, carboxylation and aldehyde, which proved that the degradation of NAP was mainly caused by •OH attack. The toxicity analysis results showed that the electron beam could significantly reduce the toxicity of NAP, and the toxicity of the final product was much lower than NAP, realizing the harmless treatment of NAP. The experimental results showed that electron beam irradiation has faster degradation rates and higher degradation efficiency for NAP and Cr (Ⅵ) compared to other reported treatment methods.

The performance and pathway of benzothiazole degradation by electron beam irradiation.

Benzothiazole (BTH) is a typical refractory heterocyclic compound that can be used as a photosensitive material in organic synthesis and conditional plant resource research. The extensive use of BTH has led to high BTH concentrations in natural environment, such as in tap water and urine, which tend to inhibit animal hormone synthesis and induce genotoxicity. Traditional wastewater treatment processes cannot effectively remove BTH. Therefore, we aimed to use the electron beam method, an emerging method for pollutant degradation, to degrade BTH in water. Experiments showed that BTH can be effectively degraded (up to 90%) when the electron beam reaches 5 kGy and irradiation conformed perfectly to the pseudo first-order kinetics model. Experimental results showed that acidic conditions are more favorable for electron beam degradation of BTH, while the degradation of most other inorganic ions is inhibited (except SO42-). Hydroxyl radicals (•OH) was confirmed to play a major role in degradation by the experiment, and the mineralization rate was greatly increased by the addition of H2O2 and K2S2O8. In addition, our experimental and theoretical calculations showed that the degradation of BTH occurred mainly through the opening of the benzene ring. Theoretical calculations showed that the toxicity of BTH decreased significantly after electron beam degradation, making it an effective way to degrade BTH.

Electron beam induced degradation of indomethacin in aqueous solution: kinetics, degradation mechanism, and toxicity assessment.

Pharmaceutical compounds were emerging contaminants, and the accumulation of pharmaceutical compounds in the environment increased the risk to humans and ecosystems. In this study, electron beam irradiation was applied to degrade indomethacin (IDM) in aqueous solution. IDM degradation followed pseudo-first-order kinetics and 300 µM IDM could be completely degraded at only 2 kGy. According to the quenching experiment, the dose constant ratios of oxidative radicals (•OH) and reductive radicals (e-aq and •H) could be calculated as k•OH: ke aq and •H=4.79:1. As the concentration of H2O2 increased from 0 to 10 mM, the dose constant increased from 1.883 to 2.582 kGy-1. However, degradation effect would be restrained in the existence of NO-3, NO-2, CO2-3, HCO-3, SO2-, and humic acid due to their competition for the active species. Theoretical calculation revealed the radical attacking sites of IDM molecule and the most probable pathways were proposed with identification of intermediates. The attack of •OH mainly resulted in the cleavage of amide bond, indole ring opening, demethoxylation, and •OH addition. Dechlorination and the reduction of the carbonyl group occurred on IDM molecular through the reduction of e-aq and •H. The intermediates could continue to be degraded to small molecule acid, such as formic acid, acetic acid, and oxalic acid. Furthermore, highly toxic IDM transformed into less toxic products during the irradiation process.

Degradation of anticorrosive agent benzotriazole by electron beam irradiation: Mechanisms, degradation pathway and toxicological analysis.

Benzotriazole (BTA), which is extensively served as household and engineering agent, is one of the emerging and persistent contaminants. Despite the spirit to remove BTA is willing, the traditional wastewater treatments are weak. Therefore, the degradation of BTA via electron beam was systematically explored in this study. It turned out that after 5.0 kGy irradiation, even 87.5 mg L-1 BTA could be completely removed, and the irradiation conformed perfectly to the pseudo first-order kinetics model. The effects of solution pH, inorganic anions (CO32-, HCO3-, NO3-, NO2-, SO42-, SO32-, Cl-), and gas atmosphere were all explored. And results indicated that oxidative hydroxyl radicals played critical role in BTA irradiation. Additionally, presence of H2O2 and K2S2O8 promoted significantly not only degradation extent but also mineralization efficiency of BTA due to they both augmented the generation of oxidative free radicals. Moreover, by combining theoretical calculations with experimental results, it could be inferred that degradation of BTA was mainly carried out by the benzene ring-opening. Further toxicity evaluation proved that as irradiation proceeded, the toxicity alleviated. Taken together, there were various indications that BTA could be effectively eliminated by electron beam irradiation in aquatic environments.

Typical antibiotics in the receiving rivers of direct-discharge sources of sewage across Shanghai: occurrence and source analysis.

In Shanghai, the antibiotics in the receiving rivers of direct-discharge sources of sewage (aquaculture farms, cattle farms and wastewater treatment plants) were investigated. Water and sediment samples from the receiving rivers of these sources were collected, and were screened for 19 typical antibiotics. The concentration of the antibiotics in the water and sediment ranged from not detected (ND) to 530.05 ng L-1 and ND to 1039.53 ng g-1, respectively, and sulfonamides and fluoroquinolones were identified as the main antibiotics in the water and sediment, respectively. According to principal component analysis with multiple linear regression (PCA-MLR), source contributions were estimated: wastewater treatment plants (66.8%) > aquaculture farms and cattle farms (21.2%), indicating that the contribution of human antibiotics was higher than veterinary antibiotics. Based on the risk quotients, ciprofloxacin was identified as the main antibiotic that causes medium risk in the aquatic ecosystem. This work systematically reflected the profile and source apportionment of antibiotics in Shanghai, which is helpful for antibiotic contamination control and environmental management.

Determination of OCPs, OPPs, and 21 SVOCs in water and sediment samples in five rivers of Shenzhen, China, during the period of 2017 and 2018.

One hundred two semivolatile organic compounds (SVOCs), including 20 organochlorine pesticides (OCPs) and 12 organophosphorus pesticides (OPPs), were determined in the main rivers of Shenzhen, China. As a result, p,p'-dichlorodiphenyldichloroethane (DDD), aldrin, and benzoepin sulfate were the main OCPs detected in surface water, and p,p'-DDD, heptachlor, and endrin aldehyde were the main compounds in sediment. In addition, diazinon was the most frequent OPP detected in both water and sediment. At most sites, SVOCs were at similar concentration levels in 2017 and 2018. Compared with other areas, diazinon and malathion had comparative high concentrations in Maozhou River in this study. Analyzed from the SVOCs concentrations in water and sediment, p,p'-DDD was from the quick degradation of p,p'-dichlorodiphenyltrichloroethane (DDT), and no recent DDT was input around the investigated area. Besides, the interrelationships among these pollutants were calculated, revealing that OPPs were mainly from the chronically cumulative content, rather than the directly transferring from surface water to sediment. According to the risk assessment, the occurrence of p,p'-DDD and p,p'-DDT affected the aquatic community. All in all, further investigations on the occurrence and source of these pollutants are still needed to avoid the potential risk for human beings living around the contaminated environment.

Radiolytic degradation of anticancer drug capecitabine in aqueous solution: kinetics, reaction mechanism, and toxicity evaluation.

The occurrence of anticancer drugs in the environment has attracted wide attention due to its potential environmental risks. The aim of this study was to investigate degradation characteristics and mechanism of anticancer drug capecitabine (CPC) by electron beam (EB) irradiation. The results showed that EB was an efficient water treatment process for CPC. The degradation followed pseudo-first-order kinetics with dose constants ranged from 1.27 to 3.94 kGy-1. Removal efficiencies in natural water filtered or unfiltered were lower than pure water due to the effect of water matrix components. The degradation was restrained by the presence of NO2-, NO3- and CO32-, and fulvic acid due to competition of reactive radical •OH. It demonstrated that oxidizing radical played important role in irradiation process. The appropriate addition of H2O2 and K2S2O8 providing with oxidizing agents •OH and •SO4- was favorable to improve degradation efficiency of CPC. The possible transformation pathways of CPC including cleavage of the ribofuranose sugar and defluorination were proposed based on intermediate products and were consistent with the theoretical calculation of charge and electron density distribution. Toxicity of CPC and intermediate products were estimated by ECOSAR program. It was found that CPC was transformed to low toxicity products with EB.

Pollution characteristics and underlying ecological risks of primary semi-volatile organic compounds (SVOCs) in urban watersheds of Shanghai, China.

We investigated the pollution characteristics of ninety semi-volatile organic compounds (SVOCs) in the rivers and lakes of Shanghai. Total concentrations of Σ90SVOCs in water and sediment samples from 30 sites ranged from 1.47 to 19.5 µg/L and 2.38 to 9.48 mg/kg, respectively. PAEs and PAHs were the major contaminant compounds found in all samples. OCPs accounted for less than 3% of the total concentrations of Σ90SVOCs and other SVOCs were either not detected or only detected in trace amounts. Our results indicated that domestic swage, industrial wastewater, petroleum products, and other human activities were the pollutant sources to the water and sediment. It is noteworthy that products that contain the banned chemicals HCH and DDT are still under use within the studied areas. Ecological and health risk assessment results showed that dieldrin and BBP have the potential to cause adverse effects on the environment, while B(a)p and DBP have high carcinogenic risks to humans.

Bioaccumulation of short-chain chlorinated paraffins in chicken (Gallus domesticus): Comparison to fish.

Short chain chlorinated paraffins (SCCPs) are a complex group of chlorinated organic pollutants that have raised an increasing public attention. However, limited information is currently available on the bioaccumulation of SCCPs in terrestrial birds which are abundant and widely distributed around the world. In the present study, chicken (Gallus domesticus) was used as a model organism to provide significant implications for other avian species. We investigated the transfer of SCCPs from dietary sources (feed and topsoil) to chicken and their tissue distribution behavior. SCCPs were detected in chicken feed (54-170 ng/g, dry weight), topsoil (170-860 ng/g, dry weight), and adult chicken tissues (460-13000 ng/g, lipid weight). Adult chicken tended to accumulate SCCP congeners with lower n-octanol-water partition coefficients (KOW) and octanol-air partition coefficients (KOA). The accumulation ratio values for SCCPs of the chicken were more influenced by KOA than by KOW, which was contrary to those for aquatic fish. Levels and homologue profiles of SCCPs varied among chicken tissues. SCCP levels in the livers were significantly lower than those in the other tissues (p < 0.05). The accumulation potential for SCCP congeners with higher KOW increased in the order of muscle < liver < fat.

Immunotoxicity of bisphenol S and F are similar to that of bisphenol A during zebrafish early development.

Bisphenol S (BPS) and bisphenol F (BPF) have been increasingly used as alternatives to bisphenol A (BPA) owing to health concerns. The present study aims to evaluate the impact of these two BPA analogs on oxidative stress and the immune system during zebrafish embryonic and larval development. Environmentally relevant levels of BPS and BPF exposure could increase reactive oxygen species (ROS) content, nitric oxide (NO) content, nitric oxide synthase (NOS) activity, and the expression of immunity-related genes in concentration dependent manners during the early developmental stages in zebrafish. At a concentration of 100 µg/L, BPS and BPF showed similar effects on the immune toxicity of zebrafish as that of BPA. Moreover, BPS and BPF induced both erα and nf-κb expression, and antagonists of estrogen receptor and NF-κB blocked the effects on immunity-related gene expression, providing evidence that the two pathways mediate the actions of BPS and BPF on fish immune response and functions. Thus we conclude that the presence of BPS and BPF in the environment, similar to BPA, may also pose risks to ecosystem and human health and cannot be widely used without limitations and precautions.

Electron beam irradiation induced degradation of antidepressant drug fluoxetine in water matrices.

With the development of psychiatric disorder in the current society, abuse of antidepressant drug fluoxetine (FLX) has made such compound an emerging contaminant in natural waters, and causes endocrine systems disturbance on some aquatic species. Herein, an efficient advanced oxidation process (AOP), electron beam irradiation was carried out to investigate the decomposition characteristics of such novel environmental pollutant, including the effects of initial concentration, pH, radical scavengers and anions. The results showed that FLX degradation followed pseudo-first-order kinetics. The degradation rate and dose constant decreased with increasing initial FLX concentration; and G-values elevated with the increase of initial concentration but reduced with increase of absorbed dose. Acidic condition was more conducive to FLX destruction than neutral and alkaline. The radical scavenger experiments indicated OH was the main reactive species for the decomposition of FLX, while the reductive species e-aq and H played an adjuvant role. The presence of anions slightly decreased or even no impact on FLX degradation rate. Various water matrices influenced degradation processes of FLX. Experimental results suggested radiolytic degradation showed the best performance in pure water rather than natural water no matter with filtration or not. Moreover, with the occurrence of defluorination and dealkylation during degradation process, some organic and inorganic intermediates were detected, and the possible degradation mechanisms and pathways of FLX were proposed.

Hexabromocyclododecane and tetrabromobisphenol A in tree bark from different functional areas of Shanghai, China: levels and spatial distributions.

The concentrations and spatial distributions of hexabromocyclododecane (HBCDD) and tetrabromobisphenol A (TBBPA) were measured in tree bark from different functional areas of Shanghai. ΣHBCDD (sum of α-, ß-, and γ-HBCDD) concentrations ranged from 1.2 × 102 to 6.6 × 103 ng g-1 lw (median 5.7 × 102 ng g-1 lw) and TBBPA concentrations ranged from 48 to 7.2 × 104 ng g-1 lw (median 2.8 × 102 ng g-1 lw). The concentrations of ΣHBCDD and TBBPA all followed the order of industrial areas > commercial areas > residential areas. The mean percentage of α-HBCDD in bark samples (44%) from Shanghai was higher than that in technical HBCDD products, but comparable with that in air. The concentrations of TBBPA and individual HBCDD diastereoisomers between industrial areas and commercial areas were correlated. Based on the concentrations of HBCDD in the bark, the corresponding atmospheric HBCDD concentrations were estimated. Compared with the published data for HBCDD in urban air, the estimated atmospheric HBCDD concentrations in Shanghai had a relatively high level, and more attention should be paid to the pollution status of HBCDD in Shanghai.