RESUMO
In the title mol-ecule, C20H16O2, the dihedral angle between the phenyl rings of the diphenyl-methyl group is 68.3â (2)°. The benzoate group is essentially planar, with a maximum deviation of 0.017â (2)â Å for the carbonyl O atom, and the two phenyl rings are twisted by 27.5â (4) and 85.6â (9)° from this plane. In the crystal, weak C-Hâ¯O hydrogen bonds link mol-ecules along [100].
RESUMO
In the title compound, C(10)H(10)O(2), all the non-H atoms except the methyl C atoms lie on a crystallographic mirror plane. In the crystal, C-Hâ¯O hydrogen bonds link the mol-ecules into zigzag chains running parallel to [100]. Weak π-π stacking inter-actions between the benzene rings [centroid-centroid distance = 3.9817â (5)â Å] link the chains in the [010] direction.
RESUMO
In the title mol-ecular salt [systematic name: 3-(5H-di-benzo[a,d]cyclo-hepten-5-yl-idene)-N,N-dimethyl-1-propanaminium 2-hy-droxy-benzoate], C(20)H(22)N(+)·C(7)H(5)O(3) (-), the benzene rings of the cyclo-benzaprinium cation are inclined with a dihedral angle of 61.66â (7)°. An intra-molecular O-Hâ¯O hydrogen bond occurs within the salicylate anion, generating an S(6) ring. In the crystal, the cation and anion are linked by an N-Hâ¯O inter-action.
RESUMO
IN THE TITLE COMPOUND (SYSTEMATIC NAME: 2-{4-[3-(5H-dibenz[b,f]azepin-5-yl)prop-yl]piperazin-1-yl}ethanol), C(23)H(29)N(3)O, the 5H-dibenz[b,f]azepine and piperazine rings adopt boat and chair conformations, respectively, and the overall shape of the fused ring part of the molecule is a butterfly. In the crystal, O-Hâ¯N and C-Hâ¯O hydrogen bonds link the mol-ecules into a layer parallel to the bc plane.
RESUMO
In the title compound, C(14)H(11)N, the dihedral angle between the mean planes of the two benzene rings is 44.6â (7)°. The crystal packing is stabilized by weak inter-molecular π-π stacking inter-actions, the centroid-centroid distances being 3.8172â (12) and 3.9349â (12)â Å.
RESUMO
In the title compound, C(14)H(11)NO(3)S, the six-membered thia-zine ring fused to two benzene rings adopts a distorted boat conformation. The dihedral angle between the mean planes of the two benzene rings is 45.8â (1)°. The crystal packing is stabilized by weak inter-molecular C-Hâ¯O inter-actions.
RESUMO
IN THE TITLE COMPOUND [SYSTEMATIC NAME: 3-(10,10-dimethyl-anthracen-9-yl-idene)-N,N,N-trimethyl-propanaminium chlor-ide], C(21)H(26)N(+)·Cl(-), the cyclo-hexane ring adopts a chair conformation. The dihedral angle between the terminal benzene rings is 40.43â (12)°. In the crystal, ions are linked through inter-molecular N-Hâ¯Cl and C-Hâ¯Cl hydrogen bonds, forming supra-molecular layers parallel to the bc plane.
RESUMO
In the title compound, C(21)H(26)N(2)O, the dihedral angle between the mean planes of the two benzene rings is 81.1â (9)°. The piperidine ring is in a chair conformation. The crystal packing is stabilized by N-Hâ¯N and N-Hâ¯O hydrogen bonds and weak inter-molecular C-Hâ¯O inter-actions.
RESUMO
In the title mol-ecular salt [systematic name: 3-(5H-dibenzo[a,d]cyclo-hepten-5-yl-idene)-N,N-dimethyl-propan-aminium chloride], C(20)H(22)N(+)·Cl(-), two cation-anion pairs make up the asymmetric unit. The dihedral angles between the mean planes of the two fused benzene rings of the cation are 49.5â (1) and 50.9â (1)°. The cystal packing is stabilized by N-Hâ¯Cl hydrogen bonds and weak C-Hâ¯Cl inter-actions.
RESUMO
IN THE TITLE COMPOUND [SYSTEMATIC NAME: 3-(5,5-dioxo-phen-othia-zin-10-yl)-N,N,2-trimethyl-propanaminium chloride], C(18)H(23)N(2)O(2)S(+)·Cl(-), the dihedral angle between the two outer aromatic rings of the phenothia-zine unit is 30.5â (2)°. In the crystal, the components are linked by N-Hâ¯Cl and C-Hâ¯Cl hydrogen bonds and C-Hâ¯π inter-actions.
RESUMO
In the title compound, C(19)H(20)F(3)NOS, the dihedral angle between the mean planes of the two benzene rings attached to the thioxanthene ring is 41.8â (7)°; the latter has a slightly distorted boat conformation. The F atoms are disordered over three sets of sites [occupancy ratio = 0.564â (10):0.287â (10):0.148â (5)] and the methyl groups are disordered over two sets of sites [occupancy ratio = 0.72â (4):0.28â (4)]. The crystal packing is stabilized by O-Hâ¯N and C-Hâ¯S hydrogen bonds and weak C-Hâ¯Cg inter-actions.
RESUMO
In the title compound, C(14)H(13)NO, which has two mol-ecules in the asymmetric unit, the dihedral angles between the mean planes of the benzene rings are 84.6â (7) and 85.0â (6)°. N-Hâ¯O hydrogen bonds [forming R(2) (2)(8) ring motifs] and C-Hâ¯O hydrogen bonds dominate the crystal packing, forming zigzag chains parallel to the a axis. In addition, weak inter-molecular C-Hâ¯π inter-actions are observed.
RESUMO
In the title compound, C(15)H(12)O(4), the dihedral angle between the benzene rings is 64.0â (6)°. In the crystal, mol-ecules are linked by O-Hâ¯O hydrogen bonds, forming C(8) chains propagating in [10[Formula: see text]] and the packing is reinforced by weak C-Hâ¯O inter-actions.
RESUMO
In the title salt, C(23)H(27)F(3)N(2)OS(+)·2C(4)H(3)O(4) (-), a non-merohedral twin [ratio of the twin components = 0.402â (1):0.598â (1)], the -CF(3) group is disordered over two sets of sites with occupancy factors in the ratio 0.873â (2):0.127â (2). The dihedral angle between the two outer aromatic rings of the 9H-thioxanthene unit, whose thio-pyran ring has a screw-boat conformation, is 33.01â (9)°. The diprotonated piperazine ring adopts a chair conformation. In the crystal, inter-molecular O-Hâ¯O, N-Hâ¯O and C-Hâ¯O hydrogen bonds between neighboring mol-ecules form zigzag chains along the a axis and contribute to the stabilization of the packing.
RESUMO
In the title compound, C(23)H(27)F(3)N(2)OS(+)·2Cl(-), the piperazinediium ring adopts a chair conformation. The dihedral angle between the two outer aromatic rings of the 9H-thioxanthene unit is 40.35â (18)°. The F atoms in the trifluoro-methyl group are disordered over two sets of sites with occupancies of 0.803â (6) and 0.197â (6). In the crystal, mol-ecules are connected by N-Hâ¯Cl, O-Hâ¯Cl C-Hâ¯O and C-Hâ¯Cl hydrogen bonds, forming chains propagating along [001]. There are also C-Hâ¯π inter-actions present in the crystal structure.
RESUMO
In the crystal structure of the title salt {systematic name: 4-[3-(5H-dibenz[b,f]azepin-5-yl)prop-yl]-1-(2-hy-droxy-eth-yl)piperazin-1-ium (2Z)-3-carb-oxy-prop-2-enoate}, C(23)H(30)N(3)O(+)·C(4)H(3)O(4) (-), the piperazine group in the opipramol cation is protonated at only one of the N atoms. In the cation, the dihedral angle between the two benzene rings is 53.5â (6)°. An extensive array of inter-molecular O-Hâ¯O, O-Hâ¯N and N-Hâ¯O hydrogen bonds and weak inter-molecular N-Hâ¯O, C-Hâ¯O and C-Hâ¯π inter-actions dominate the crystal packing.
RESUMO
In the cation of the title salt, C(20)H(24)NO(+)·C(4)H(3)O(4) (-), the N atom in the dimethyl-ammonium group is protonated. The dihedral angle between the mean planes of the two six-membered rings fused to the cyclo-hepten-5-yl ring is 54.4â (1)°. An intra-molecular O-Hâ¯O hydrogen bond occurs in the anion. The crystal packing is stabilized by inter-molecular O-Hâ¯O and N-Hâ¯(O,O) hydrogen bonds and weak C-Hâ¯O inter-actions, forming a two-dimensional network.
RESUMO
There is one cation-anion pair in the asymmetric unit of the title compound [systematic name: 4-(3-carb-oxy-6-fluoro-4-oxo-1,4-dihydroquinolin-7-yl)-1-ethyl-piperazin-1-ium 2,4,6-tri-nitro-phenolate], C(19)H(23)FN(3)O(3) (+)·C(6)H(2)N(3)O(7) (-). The six-membered piperazine group in the cation adopts a slightly distorted chair conformation and contains a protonated N atom. The dihedral angles between the mean planes of the cyclo-propyl and piperazine rings in the cation with the 10-atom ring system of the quinolone group are 48.1â (1) and 69.9â (5)°, respectively. The picrate anion inter-acts with the protonated N atom of an adjacent cation through a bifurcated N-Hâ¯O three-center hydrogen bond, forming an R(1) (2)(6) ring motif. Furthermore, there is an intra-molecular O-Hâ¯O hydrogen bond. The dihedral angle between the mean planes of the anion benzene and cation piperizine, quinoline and cyclo-propyl rings are 61.3â (6), 31.1â (4) and 70.4â (9)°, respectively. The mean planes of the two o-NO(2) and single p-NO(2) groups in the picrate anion are twisted by 6.7â (6), 38.3â (9) and 12.8â (7)° with respect to the mean plane of the benzene ring. Strong N-Hâ¯O and weak inter-molecular C-Hâ¯O hydrogen bonds in concert with weak π-π stacking inter-actions [centroid-centroid distances = 3.5785â (13), 3.7451â (12) and 3.6587â (13)â Å] dominate the crystal packing.
RESUMO
IN THE CATION OF THE TITLE COMPOUND [SYSTEMATIC NAME: (RS)-4-(3-carb-oxy-1-ethyl-6,8-difluoro-4-oxo-1,4-dihydro-quinolin-7-yl)-2-methyl-piperazin-1-ium 2,4,6-trinitro-phenolate], C(17)H(20)F(2)N(3)O(3) (+)·C(6)H(2)N(3)O(7) (-), the piper-azine ring adopts a slightly distorted chair conformation and contains a protonated N atom. An intra-molecular O-Hâ¯O hydrogen bond occurs in the cation. The dihedral angles between the mean planes of the six-atom piperazine ring and the 10-atom fused ring system is 43.3â (5)°. The picrate anion inter-acts with the protonated N atom of an adjacent cation through a bifurcated N-Hâ¯(O,O) three-center hydrogen bond. Strong N-Hâ¯O hydrogen bonds in concert with weak π-π stacking inter-actions [centroid-centroid distance = 3.6460â (14)â Å] dominate the crystal packing, creating a two-dimensional network structure along [011].
RESUMO
In the cinnarizinium dication of the title compound {systematic name: 1-diphenyl-methyl-4-[(2E)-3-phenyl-prop-2-en-1-yl]piperazine-1,4-diium bis-(2,4,6-trinitro-phenolate)}, C(26)H(30)N(2) (2+)·2C(6)H(2)N(3)O(7) (-), the piperazine group is protonated at both N atoms and adopts a slightly distorted chair conformation. Strong N-Hâ¯O(hy-droxy) cation-anion hydrogen bonds link the dication and two anions. In the cation, the (2E)-3-phenyl-prop-2-en-1-yl fragment is disordered over two positions in a ratio of 0.586â (4): 0.414â (4). Two nitro groups in one anion and three in the other one demonstrate rotational disorder. The crystal packing is stabilized by weak inter-molecular π-π [centroid-centroid distances = 3.844â (7), 3.677â (9), 3.825â (5), 3.634â (2) and 3.729â (7)â Å], C-Hâ¯π and C-Hâ¯O inter-actions.