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1.
Tetrahedron ; 69(29): 5829-5840, 2013 Jul 22.
Artigo em Inglês | MEDLINE | ID: mdl-23894213

RESUMO

The preparation of an indole appended vinamidinium salt, an indole appended vinylogous amide and an indole appended chloroenal are described. The subsequent regiospecific conversion of these indole containing building blocks to functionalized pyrazoles and pyrroles is detailed.

2.
Tetrahedron ; 66(44): 8485-8493, 2010 Oct 30.
Artigo em Inglês | MEDLINE | ID: mdl-21113324

RESUMO

Studies directed at the amine exchange reaction of vinamidinium salts followed by sodium borohydride reduction to secondary and tertiary allylic amines are described. The tertiary allylic amines were alkylated and subjected to base mediated rearrangement to yield a variety of highly functionalized tertiary homoallylic amines.

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