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1.
Micromachines (Basel) ; 15(3)2024 Feb 24.
Artigo em Inglês | MEDLINE | ID: mdl-38542562

RESUMO

Granite edge finishing through grinding is a common process in the granite processing industry, crucial for achieving the final desired shape and edge quality of products. This study focuses on the granite industry, specifically delving into the significance of grinding and polishing for improving aesthetics and extending material longevity. The experimental design entails a comprehensive factorial experiment plan involving two workpiece materials (white and black granite samples) and two cutting tool edge shapes (chamfer and concave), each with two grit sizes: G150 and G600. The cutting conditions varied and consisted of variations in spindle speeds (1500, 2500, 3500 rpm), feed rates (500, 1000, 1500 mm/min), and lubrication modes (wet/dry). The results uncover intricate relationships among these parameters and part quality, underscoring the pivotal role of tool geometry in achieving superior surface finishes and in controlling the cutting forces. These findings contribute to a nuanced understanding of the dynamic interplay between tool characteristics, material properties, and machining conditions within the granite industry.

2.
Materials (Basel) ; 17(18)2024 Sep 23.
Artigo em Inglês | MEDLINE | ID: mdl-39336417

RESUMO

The present work was aimed at quantifying the effects of Ni addition in the range of 0-4% together with 0.3%Zr on the hardness and the tensile properties, volume fraction of intermetallics, and changes in size and distribution of phase precipitation in Sr-modified Al-9%Si-2%Cu-0.6%Mg cast alloys. The study was mainly carried out using high-resolution FESEM and TEM microscopes equipped with EDS facilities. Samples were solidified at the rate of ~3 °C/s and examined at different aging conditions. The investigations are supported by thermal analysis carried out at a solidification rate of ~0.8 °C/s. The results revealed that the main compositions of the Ni-based phases are close to Al3(Ni,Cu), Al3CuNi, and Al3Ni. An Al3Ni2Cu2 phase was also detected in the 4%Ni alloy. The Cu-Ni phases were observed to precipitate, covering the surfaces of pre-existing primary Al3Zr particles. The TEM analysis indicated the magnitude of the reduction in both size and density of the precipitated Al2Cu phase particles as the Ni content reached 4%, coupled with a delay in the transition from coherent to incoherency of the Al2Cu precipitates.

3.
Nanomedicine ; 9(1): 22-4, 2013 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-22960193

RESUMO

Interactions between nanoparticles (NP), humans and the environment are not fully understood yet. Moreover, frameworks aiming at protecting human health have not been adapted to NP but are nonetheless applied to NP-related activities. Consequently, business organizations currently have to deal with NP-related risks despite the lack of a proven effective method of risk-management. To respond to these concerns and fulfill the needs of populations and industries, ÉquiNanos was created as a largely interdisciplinary provincial research team in Canada. ÉquiNanos consists of eight platforms with different areas of action, from adaptive decision-aid tool to public and legal governance, while including biological monitoring. ÉquiNanos resources aim at responding to the concerns of the Quebec nanotechnology industry and public health authorities. Our mandate is to understand the impact of NP on human health in order to protect the population against all potential risks emerging from these high-priority and rapidly expanding innovative technologies. FROM THE CLINICAL EDITOR: In this paper by Canadian authors an important framework is discussed with the goal of acquiring more detailed information and establishing an infrastructure to evaluate the interaction between nanoparticles and living organisms, with the ultimate goal of safety and risk management of the rapidly growing fields of nanotechnology-based biological applications.


Assuntos
Nanopartículas , Gestão de Riscos
4.
Materials (Basel) ; 16(19)2023 Sep 30.
Artigo em Inglês | MEDLINE | ID: mdl-37834639

RESUMO

In this study, the effects of heat treatment on the microstructure and strength (micro-hardness) of an aluminum-lithium (Al-Li) base alloy containing copper (Cu) and scandium (Sc) were investigated, with a view to enhancing the alloy performance for aerospace applications. The heat treatment conditions were investigated to understand the precipitation behavior and the mechanisms involved in strengthening. Aging was carried out at temperatures of 130 °C and 150 °C for aging times of 1 h, 2.5 h, 5 h, 10 h, 15 h, 25 h, 35 h, and 45 h at each temperature for Al-Li alloy and at 160 °C, 180 °C, and 200 °C for aging times of 5 h, 10 h, 15 h, 20 h, 25 h, and 30 h at each temperature for Al-Li-Cu and Al-Li-Cu-Sc alloys. The investigation revealed that both solution heat treatment and artificial aging had a notable impact on strengthening the hardness of the alloy. This effect was attributed to the characteristics of the precipitates, including their type, size, number density, and distribution. The addition of copper (Cu) and scandium (Sc) was observed to have an impact on grain size refinement, while Cu addition specifically affected the precipitation behavior of the alloy. It led to remarkable changes in the number density, size, and distribution of T1 (Al2CuLi) and θ' (Al2Cu) phases. As a result, the hardness of the alloy was significantly improved after the addition of Cu and Sc, in comparison with the base Al-Li alloy. The best heat treatment process was determined as: 580 °C/1 h solution treatment +150 °C/45 h artificial aging for Al-Li alloy and 505 °C/5 h solution treatment +180 °C/20 h artificial aging for Al-Li-Cu and Al-Li-Cu-Sc alloys.

5.
Materials (Basel) ; 16(16)2023 Aug 15.
Artigo em Inglês | MEDLINE | ID: mdl-37629930

RESUMO

The present analysis addresses the solidification and thermodynamic parameters involved during the solidification of aluminum (Al)-based alloys as presented in the literature using different systems viz., binary aluminum-boron (Al-B) and aluminum-titanium (Al-Ti) systems, ternary aluminum-titanium-boron (Al-Ti-B) and aluminum-titanium-carbon (Al-Ti-C) systems, as well as taking into consideration the silicon-titanium-aluminide (Si-TiAl3) interaction in Al-based alloys containing Si. The analysis is supported by recent metallographic evidence obtained by the authors on A356.2 alloys. The sections on thermodynamic aspects cover the different models proposed concerning nucleation and growth on a newly formed Al grain. The value of the recalescence parameter reduces gradually with the increase in the Ti added. At a level of 0.20 wt%, this parameter becomes zero. If the concentration of grain refiner exceeds a certain amount, the grain size becomes minimal. Another parameter to be considered is the interaction between the grain refiner and traces of other metals in the base alloy. For example, Al-4%B can react with traces of Ti that may exist in the base alloy, leading to the reaction between boron and titanium to form titanium diboride (TiB2). Grain refinement is achieved primarily with TiB2 rather than aluminum diboride (AlB2), or both, depending on the Ti content in the given alloy.

6.
Materials (Basel) ; 16(23)2023 Nov 27.
Artigo em Inglês | MEDLINE | ID: mdl-38068119

RESUMO

The present study was performed on three versions of 7075 alloy to which Sc or Sc + Li was added. The alloys were subjected to various aging treatments. The microhardness results show that the highest value of hardness was achieved when the alloy containing Li + Sc was aged at 120 °C for 24 h whereas the minimum level was exhibited by the base alloy aged at 280 °C. The results were interpreted in terms of the size and distribution of the main hardening phase (η'(MgZn2)), and the role of the presence of Al and Cu in the used alloy. Precipitation of Al3(Sc, Zr, Ti) phase particles during solidification of the Sc-containing ingots was also discussed. The coarsening and spheroidi-zation of η-phase particles take place through the Ostwald ripening mechanism while smaller par-ticles in solution dissolve and deposit on larger particles. In Sc-containing alloys, star phase particle consists of different layers. The change in the brightness from layer to layer indicates that the Zr and Sc concentrations are varied within the star phase, since the atomic number of Zr (40) is higher than the atomic number of Sc (21). The addition of Sc, as well, leads to marked decrease in the grain size of the as-cast alloys i.e., 300 µm and 45 µm, respectively. The interaction between Li and Sc would reduce the effectiveness of the grain refining effect of Sc. The results of the refining effect of Sc were confirmed using the EBSD technique.

7.
Materials (Basel) ; 16(4)2023 Feb 07.
Artigo em Inglês | MEDLINE | ID: mdl-36837030

RESUMO

The present work was performed on three versions of a newly developed alloy coded T200 containing 6.5% Cu, 0.1% Fe, 0.45% Mg, and 0.18% Zr in addition to A319 and A356 alloys (grain refined and Sr-modified). Tensile bars were subjected to 13 different heat treatments prior to testing at either 25 °C or 250 °C. The tensile data were analyzed using the quality index method. The results obtained showed that, due to the high copper content in the T200 alloy coupled with proper grain refining, the alloy possesses the highest quality as well as improved resistance to softening when tested at 250 °C among the five alloys. The results also demonstrate the best heat treatment condition to maximize the use of the T200 alloy for automotive applications. Grain-refined alloy B, treated in the T6 temper and tested at 250 °C, exhibited the best combination of the four tensile parameters, i.e., UTS, YS, %El, and Q-values: 308 MPa, 304 MPa, 2.3%, and 352 MPa, respectively, which are comparable with those obtained from the 356 alloy: 309 MPa, 305 MPa, 2.8%, and 375 MPa in the same order.

8.
Materials (Basel) ; 16(7)2023 Apr 04.
Artigo em Inglês | MEDLINE | ID: mdl-37049162

RESUMO

The present article addresses solidification parameters, and includes analyses of the macrostructure and microstructure in the light of the results obtained from the thermal analysis, from which it is possible to conclude that undercooling (TS) and recalescence (TR) temperatures increase with the initial increase in titanium (Ti) concentration. If the concentration reaches approximately 0.25%, a rapid decrease in these temperatures is observed. Thereafter, the temperatures increase again with the further increase in Ti concentration, and eventually become constant. These temperatures also vary depending on the superheating and casting temperature. The ∆T parameter (i.e., TS - TR) decreases with the Ti concentration and, from a concentration of around 0.20% Ti, this parameter becomes zero. The grain size decreases with the Ti concentration. If the concentration exceeds about 0.20%, the grain size becomes the minimum. Another parameter to be considered is the interaction between the grain refiner and the traces of other metals in the base Al alloy. For example, Al-4%B can react with traces of Ti that may exist in the base alloy, leading to the reaction between boron (B) and Ti to form TiB2. Grain refinement is achieved primarily with TiB2 rather than AlB2, or both, depending on the Ti content in the given alloy.

9.
Materials (Basel) ; 16(5)2023 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-36903162

RESUMO

The main objective of this review is to analyze the equations proposed for expressing the effect of various parameters on porosity formation in aluminum-based alloys. These parameters include alloying elements, solidification rate, grain refining, modification, hydrogen content, as well as the applied pressure on porosity formation in such alloys. They are used to establish as precisely as possible a statistical model to describe the resulting porosity characteristics such as the percentage porosity and pore characteristics, as controlled by the chemical composition of the alloy, modification, grain refining, and the casting conditions. The measured parameters of percentage porosity, maximum pore area, average pore area, maximum pore length, and average pore length, which were obtained from statistical analysis, are discussed, and they are supported using optical micrographs, electron microscopic images of fractured tensile bars, as well as radiography. In addition, an analysis of the statistical data is presented. It should be noted that all alloys described were well degassed and filtered prior to casting.

10.
Materials (Basel) ; 15(11)2022 Jun 02.
Artigo em Inglês | MEDLINE | ID: mdl-35683263

RESUMO

Particles emitted during manufacturing processes such as polishing can represent a serious danger for the environment and for occupational safety. The formation mechanisms responsible for these dust emissions include chip formation, friction at the tool/workpiece and chip/tool interfaces, shearing and cutting. These mechanisms thus depend on workpiece and tool properties, as well as the polishing conditions. In the case of granite polishing, particle emissions during polishing can contain chemical compounds such as silica, which represent harmful health risks for the worker. It is therefore important to characterize the particles emitted and to search for possible interactions between the particles (size and composition) and the machining conditions in order to find ways of reducing emissions at the source. In this study, an investigation was undertaken to characterize the particles emitted during granite polishing as a function of polishing conditions, type of granite, and abrasive grit sizes used. Scanning electron microscopy (SEM) was employed for particle morphology characterization and particle grain size and chemical composition were evaluated using X-ray diffraction (XRD) and energy dispersive X-ray (EDX) techniques, respectively. Results show that the influence of polishing speed and feed rate on particle emission depends mainly on the granite type used, providing useful information for controlling the polishing procedure, and thereby dust emission.

11.
Micromachines (Basel) ; 13(10)2022 Oct 11.
Artigo em Inglês | MEDLINE | ID: mdl-36296067

RESUMO

Edge-finishing of granites by grinding is a process frequently used in the granite processing industry to generate the final desired shape and edge quality of products. However, this process releases significant amounts of fine and ultrafine particles (FPs and UFPs) containing crystalline silica. When inhaled, this dust can cause silicosis disease and threaten the health and safety of workers. The purpose of this study is to optimize the process by decreasing the concentrations of dust generated while also maintaining the required surface finish. Experimental tests were planned and performed on granite samples using a full factorial design. Two cutting tool edge shapes were studied (chamfer and concave) using G150 and G600 grit size tools, at various spindle speeds (1500, 2500, 3500 rpm), feed rates (500, 1000, 1500 mm/min) and lubrication flow rates (20, 40, 60 mL/min). The findings show that the particle emissions as well as the surface finish depend on the tool shape, its grit size, and the machining and lubrication parameters used. Higher MQL flow rates led to better finished surface quality and lower concentrations of fine dust. Polishing with flood lubrication reduces the maximum number concentration of FPs corresponding to particles smaller than 1 µm diameter by about 85% as compared to dry polishing and produced the best surface finish. Polishing with lubrication in MQL mode at 60 mL/min led to the production of part with Ra-value comparable with that obtained in flood lubrication condition.

12.
Materials (Basel) ; 15(4)2022 Feb 18.
Artigo em Inglês | MEDLINE | ID: mdl-35208090

RESUMO

In recent years and due to advanced fabrication techniques of composites, many of these functional materials have been brought to the forefront with more benefits. Amongst composites, special attention has been paid to metal matrix composites (MMCs). Reinforced aluminum MMCs with nanoparticles are among the new MMCs with a wide range of industry applications. The combination of aluminum as a soft, lightweight, and low-strength material with silicon carbide (SiC), bismuth (Bi), and tin (Sn) particles, which are hard and high-strength materials, may lead to the generation of high-strength and lightweight material, which can be classified as difficult to cut material. According to literature, limited studies have been reported on the effects of various reinforcing elements on the machinability of Al-MMC, in principle tool wear morphology and size and surface quality. According to statistical analysis, the effect of cutting parameters and reinforcing particles on the surface quality attributes is not statistically significant. In contrast, the effect of cutting parameters and reinforcing particles on the tool flank wear is significant and reliable. In addition, it is observed that the reinforcing particles and cutting speed have the most significant effects, and the lubrication mode has a minor impact on the tool flank wear.

13.
Materials (Basel) ; 15(9)2022 May 04.
Artigo em Inglês | MEDLINE | ID: mdl-35591632

RESUMO

In the present study, the statistical design of experiments (DOE) method was applied to study and control the properties of near-eutectic Al-11%Si alloys. In this study, we developed regression equations between response variables, including hardness, yield stress, ultimate tensile stress, elongation, total cutting force, cutting power, and tool life, and varying factors which included the percentage of the alloying element in the composition and the modification level. These equations may be analyzed quantitatively to acquire an understating of the effects of the main variables and their interactions on the mechanical behavior and the machinability of the alloy under investigation. Analysis of variance (ANOVA) was performed to verify the fit and adequacy of the developed mathematical models. The results show that increasing the levels of Cu and Fe results in an increase in hardness, yield stress and ultimate tensile strength in both modified and non-modified alloys. On the other hand, both Cu and Fe appear to affect the elongation adversely, whereas the Sr level shows a positive effect on the elongation percentage. We found that the Sr level had the most significant effect on the cutting forces and cutting power, followed by Fe and Cu contents.

14.
Materials (Basel) ; 15(9)2022 May 08.
Artigo em Inglês | MEDLINE | ID: mdl-35591703

RESUMO

This paper presents the development of a numerical model for predicting and studying the effects of tool nose geometries and its interactions with cutting parameters during orthogonal cutting of AISI 1045 steel. The process performance characteristics studied were cutting temperature, effective stress, cutting forces and tool wear. The cutting simulations were done using the commercial DEFORM-2D R V 11.3 software, based on the finite element method (FEM). The cutting tool used had a round nose with various nose radii (0.01-0.9 mm), while the machining parameters tested were the feed rate (0.1-0.3 mm/rev), the cutting speed (100-500 m/min) and the rake angle (-5° to +10°). The interactions between the tool nose radius and the cutting parameters (speed, feed) were found to affect mostly the cutting stress and, slightly, the tool wear rate. These interactions did not much influence the cutting temperature, that was found to be high when the tool nose radius and/or the cutting speed were high. The maximum temperature was found to occur at the middle of the tool-chip contact length and at the interaction of nose radius and flank face of the tool. Except for some fluctuations, there was no significant difference in tool wear rate between small and large nose radius scales.

15.
Materials (Basel) ; 15(13)2022 Jun 27.
Artigo em Inglês | MEDLINE | ID: mdl-35806637

RESUMO

The present work investigated the effect of aging treatment on the microstructure and tensile properties of an Al-2%Cu base alloy containing various additions of Zr and other alloying elements. Aging was carried out at temperatures of 180-300 °C for different aging times at each temperature. The tensile properties indicated that Zr additions improved the strength of the base alloy, especially at high Zr levels at 180 °C. At the 220 °C aging temperature, however, while Zr addition did not have a beneficial effect on the alloy strength, the ductility was found to improve. Zr-Ti combined additions had a significant effect on the microstructure of the base alloy, as the morphology of the α-Al grains transformed into a non-dendritic morphology, and the grain size decreased sharply. These effects were at their maximum at 180 °C and 0.5 wt% Zr addition. Moreover, the Zr-containing alloys aged at higher temperatures, such as 220 °C and 240 °C, maintained a noticeably higher level of strength over the base alloy aged at the same temperatures. Quality index charts based on the tensile test data also reflected an improvement in alloy quality and strength with Zr-Ti combined additions.

16.
Materials (Basel) ; 15(8)2022 Apr 12.
Artigo em Inglês | MEDLINE | ID: mdl-35454522

RESUMO

Al-Si-Cu-Mg cast (354) alloys are used in the automotive sector owing to their remarkable properties which are achievable after applying appropriate thermal treatments. Zirconium, Nickel, and Manganese were added to this category of Al-alloys to preserve good mechanical properties while being exposed to elevated temperatures for long times. The ultimate and yield strength values obtained at room temperature for the stabilized (thermally-exposed) T5-treated condition were comparable to those of the stabilized T6-treated condition, whereas the same properties for T5-treated alloys were higher than those of T6-treated ones for elevated-temperature tensile testing. Interestingly, the results showed that the addition of 0.75 wt.% Mn was competitive with the addition of 2 and 4 wt.% Ni with respect to the elevated-temperature and ambient temperature strength values, respectively. In addition, the Mn-containing alloy M3S exhibited improved ductility values at ambient temperature and at 250 °C, compared to the Ni-containing alloys. Examination of the fracture surface of tested samples revealed the advantageous role of sludge particles in enhancing the performance of Mn-containing alloys through their resistance to the propagation of cracks that developed in many intermetallic phases. This finding is considered to be economically significant in view of the lower price of manganese compared to that of nickel.

17.
Materials (Basel) ; 15(19)2022 Oct 05.
Artigo em Inglês | MEDLINE | ID: mdl-36234242

RESUMO

The effect of tramp elements, mainly Bi and Ca, on the thermal characteristics of Sr-modified Al-Si-Cu and Al-Si-Cu-Mg alloys has been investigated using thermal analysis, X-ray radiography, and field emission scanning electron microscopy (FESEM) techniques. The high affinity of Bi to interact with Sr results in an increase in the Al-Si eutectic temperature, and hence an increase in the size of eutectic silicon particles. In contrast, the Ca-Sr interaction seems to have no significant effect on the alloy thermal behavior. The effect of these interactions on porosity formation has been discussed. Hot zones may be formed in thin cavities, in particular, near the bottom of the mold, leading to formation of unexpected coarse porosity, mostly shrinkage type. The study also highlights the significance of other parameters on porosity formation, such as no melt degassing, SrO, Al2O3 (strings or bifilms), as well as the presence of iron-based intermetallics.

18.
Materials (Basel) ; 15(1)2022 Jan 05.
Artigo em Inglês | MEDLINE | ID: mdl-35009525

RESUMO

This study was undertaken to emphasize the influence of Sn and Bi addition on the machinability of Sr-modified, grain-refined, and heat-treated Al-Si B319 and 396 alloys. Drilling and tapping tests were conducted to examine the cutting forces, tool life, tool wear, built-up edge evolution, and chip shape. Microstructures were examined using optical and electron microscopy. Drilling test results show that the B319.2 alloy with 0.15%Sn yields the longest drill life, i.e., twice that of the B319.2 alloy containing 0.5%Bi, and one-and-a-half times that of the B319.2 alloy containing 0.15%Sn + 0.5%Bi. The presence of 0.5%Bi in the B319.2 alloy causes a deterioration of drill life (cf., 1101 holes with 2100 holes drilled in the B319.2 alloy containing 0.15%Sn). The α-Fe phase in the 396 alloy produces the highest number of holes drilled compared with alloys containing sludge or ß-Fe. The presence of sludge decreases the drill life by 50%. Built-up edge (BUE) measurements and optical photographs show little change in the BUE width for different numbers of holes except for the B319.2 alloy containing 0.5%Bi, which shows a slightly lower width (0.166 mm) compared with that containing 0.15% Sn (0.184 mm) or 0.15%Sn + 0.5%Bi (0.170 mm).

19.
Materials (Basel) ; 15(3)2022 Jan 25.
Artigo em Inglês | MEDLINE | ID: mdl-35160862

RESUMO

The present study was conducted on the machinability of 396 alloy (containing approximately 11% Si) and B319.2 alloy mainly to emphasize the effects of Fe-intermetallics, i.e., α-Fe, ß-Fe, and sludge. The results demonstrate that the presence of sludge in the form of hard spots has a significant effect on cutting forces and tool life, in that it decreases drill life by 50% compared to the base alloy. The formation of the α-Fe phase in the M1 base alloy has a beneficial effect on tool life in that this alloy produces the highest number of holes drilled compared to alloys containing sludge or ß-Fe; this result may be explained by the fact that the formation of the α-Fe intermetallic, with its rounded Chinese script morphology and its presence within α-Al dendrites, is expected to improve matrix homogeneity via hardening of the soft α-Al dendrites. Increasing the Fe-content from 0.5% to 1% in the 396-T6 alloy containing 0.5% Mn produces a distinct improvement in alloy machinability in terms of cutting force and tool life. The addition of Fe and/or Mn appears to have no discernible effect on the build-up edge area (BUE) and chip shape.

20.
Materials (Basel) ; 14(15)2021 Jul 31.
Artigo em Inglês | MEDLINE | ID: mdl-34361485

RESUMO

The present research work aimed to study the effects of cutting environments and conditions on tool wear and residual stresses induced by orthogonal cutting of AA6061-T6. Cutting environments included dry- and flood-coolant modes and cutting conditions consisted of cutting speed and feed rate. A 2D finite element (FE) model was developed to predict tool wear and residual stresses and was validated by experimental measurements including machining forces, tool wear, and residual stresses. This was obtained by exploring various magnitudes of the shear friction factor and heat transfer coefficient and choosing proper coefficients using the calibration of the predicted results with the measured ones. The experimental results showed that the effect of cutting environment including dry and flood-coolant modes was negligible on machining forces. The experimental investigation also demonstrated that increasing feed rate raised machining forces, tool wear and residual stresses in both cutting environments. Low Speed Cutting (LSC) led to the highest value of tool wear and High Speed Cutting (HSC) provided the lowest values of resultant machining forces and residual stresses in both modes. Flood-coolant mode reduced tool wear and slightly decreased tensile residual stresses in comparison with dry mode. As a result, low feed rate and high-speed cutting under flood-coolant mode were proposed in order to improve tool wear and residual stress in orthogonal cutting of AA6061-T6.

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