RESUMO
In the title compound, C(35)H(29)N(3)O, the quinoxaline and indene systems are essentially planar, with maximum deviations of 0.047â (2) and 0.032â (2)â Å for C atoms, respectively. The quinoxaline system forms a dihedral angle of 4.75â (3)° with the indene system. The pyrrolizine system is folded. The substituted five-membered ring adopts an envelope conformation. In the other five-membered ring, one C atom is disordered with a site-occupancy ratio of 0.676â (12):0.324â (12). In the crystal, mol-ecules are linked via C-Hâ¯O hydrogen bonds involving the bifurcated carbonyl O atom.
RESUMO
In the title compound, C(25)H(20)Cl(2)N(2)O(2), the pyrrolidine ring adopts an envelope conformation and the best plane through the five ring atoms makes a dihedral angle of 87.03â (8)° with the indoline ring. Mol-ecules are connected by pairs of N-Hâ¯O hydrogen bonds into centrosymmetric dimers with an R(2) (2)(8) graph-set ring motif. C-Hâ¯O hydrogen bonds stabilize the crystal structure.
RESUMO
In the title compound, C(14)H(9)BrN(2)O, the quinazoline unit is essentially planar, with a mean deviation of 0.058â (2)â Å from the least-squares plane defined by the ten constituent ring atoms. The dihedral angle between the mean plane of the quinazoline ring system and the 4-bromo-phenyl ring is 47.6â (1)°. In the crystal, mol-ecules are linked by inter-molecular C-Hâ¯N and C-Hâ¯O hydrogen bonds, forming infinite chains of alternating R(2) (2)(6) dimers and R(2) (2)(14) ring motifs.