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1.
Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 8): o2469, 2012 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-22904912

RESUMO

In the title compound, C(35)H(29)N(3)O, the quinoxaline and indene systems are essentially planar, with maximum deviations of 0.047 (2) and 0.032 (2) Šfor C atoms, respectively. The quinoxaline system forms a dihedral angle of 4.75 (3)° with the indene system. The pyrrolizine system is folded. The substituted five-membered ring adopts an envelope conformation. In the other five-membered ring, one C atom is disordered with a site-occupancy ratio of 0.676 (12):0.324 (12). In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds involving the bifurcated carbonyl O atom.

2.
Acta Crystallogr Sect E Struct Rep Online ; 67(Pt 11): o3128, 2011 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-22220130

RESUMO

In the title compound, C(25)H(20)Cl(2)N(2)O(2), the pyrrolidine ring adopts an envelope conformation and the best plane through the five ring atoms makes a dihedral angle of 87.03 (8)° with the indoline ring. Mol-ecules are connected by pairs of N-H⋯O hydrogen bonds into centrosymmetric dimers with an R(2) (2)(8) graph-set ring motif. C-H⋯O hydrogen bonds stabilize the crystal structure.

3.
Acta Crystallogr Sect E Struct Rep Online ; 67(Pt 11): o2928, 2011 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-22219959

RESUMO

In the title compound, C(14)H(9)BrN(2)O, the quinazoline unit is essentially planar, with a mean deviation of 0.058 (2) Šfrom the least-squares plane defined by the ten constituent ring atoms. The dihedral angle between the mean plane of the quinazoline ring system and the 4-bromo-phenyl ring is 47.6 (1)°. In the crystal, mol-ecules are linked by inter-molecular C-H⋯N and C-H⋯O hydrogen bonds, forming infinite chains of alternating R(2) (2)(6) dimers and R(2) (2)(14) ring motifs.

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